
Chemistry: Atoms First
2nd Edition
ISBN: 9780073511184
Author: Julia Burdge, Jason Overby Professor
Publisher: McGraw-Hill Education
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Question
Chapter 16.10, Problem 20PPB
(a)
Interpretation Introduction
Interpretation:
Two salts that will dissolve to give
- (a) An acidic solution
- (b) A basic solution
- (c) A neutral solution has to be given.
Concept Information:
- Salt hydrolysis is a reaction in which the ion of salt reacts with water and produce either hydronium ion or hydroxide ion.
- Based on salt hydrolysis, the salt can be classified as,
- Acidic
- Basic
- Neutral
Two salts giving neutral solution are:
To Give: Two salts that gives acidic solution
(b)
Interpretation Introduction
Interpretation:
Two salts that will dissolve to give
- (d) An acidic solution
- (e) A basic solution
- (f) A neutral solution has to be given.
Concept Information:
- Salt hydrolysis is a reaction in which the ion of salt reacts with water and produce either hydronium ion or hydroxide ion.
- Based on salt hydrolysis, the salt can be classified as,
- Acidic
- Basic
- Neutral
To Give: Two salts that gives basic solution
(c)
Interpretation Introduction
Interpretation:
Two salts that will dissolve to give
- (g) An acidic solution
- (h) A basic solution
- (i) A neutral solution has to be given.
Concept Information:
- Salt hydrolysis is a reaction in which the ion of salt reacts with water and produce either hydronium ion or hydroxide ion.
- Based on salt hydrolysis, the salt can be classified as,
- Acidic
- Basic
- Neutral
To Give: Two salts giving neutral solution are:
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Using the conditions of spontaneity to deduce the signs of AH and AS
Use the observations about each chemical reaction in the table below to decide the sign (positive or negative) of the reaction enthalpy AH and reaction entropy
AS.
Note: if you have not been given enough information to decide a sign, select the "unknown" option.
reaction
observations
conclusions
A
This reaction is always spontaneous, but
proceeds slower at temperatures above
120. °C.
ΔΗ is
(pick one)
AS is
(pick one)
ΔΗ is
(pick one)
B
This reaction is spontaneous except above
117. °C.
AS is
(pick one)
ΔΗ is
(pick one)
This reaction is slower below 20. °C than
C
above.
AS is
|(pick one)
?
18
Ar
1
Calculating the pH at equivalence of a titration
Try Again
Your answer is incorrect.
0/5
a
A chemist titrates 70.0 mL of a 0.7089 M hydrocyanic acid (HCN) solution with 0.4574M KOH solution at 25 °C. Calculate the pH at equivalence. The pK of
hydrocyanic acid is 9.21.
Round your answer to 2 decimal places.
Note for advanced students: you may assume the total volume of the solution equals the initial volume plus the volume of KOH solution added.
pH
=
11.43]
G
00.
18
Ar
B•
Chapter 16 Solutions
Chemistry: Atoms First
Ch. 16.1 - What is (a) the conjugate base of HNO3, (b) the...Ch. 16.1 - What is (a) the conjugate acid of ClO4, (b) the...Ch. 16.1 - HSO3 is the conjugate acid of what species? HSO3...Ch. 16.1 - Which of the models represents a species that has...Ch. 16.1 - Prob. 16.2WECh. 16.1 - Identify and label the species in each reaction....Ch. 16.1 - Prob. 2PPBCh. 16.1 - Write the formula and charge for each species in...Ch. 16.1 - Prob. 16.1.1SRCh. 16.1 - Prob. 16.1.2SR
Ch. 16.2 - Predict the relative strengths of the oxoacids in...Ch. 16.2 - Prob. 3PPACh. 16.2 - Based on the information in this section, which is...Ch. 16.2 - Prob. 3PPCCh. 16.2 - Prob. 16.2.1SRCh. 16.2 - Prob. 16.2.2SRCh. 16.2 - Prob. 16.2.3SRCh. 16.3 - Prob. 16.4WECh. 16.3 - The concentration of hydroxide ions in the antacid...Ch. 16.3 - The value of Kw at normal body temperature (37C)...Ch. 16.3 - Prob. 4PPCCh. 16.3 - Prob. 16.3.1SRCh. 16.3 - Prob. 16.3.2SRCh. 16.4 - Determine the pOH of a solution at 25C in which...Ch. 16.4 - Determine the pOH of a solution at 25C in which...Ch. 16.4 - Determine the pOH of a solution at 25C in which...Ch. 16.4 - Prob. 5PPCCh. 16.4 - Calculate the hydroxide ion concentration in a...Ch. 16.4 - Prob. 6PPACh. 16.4 - Prob. 6PPBCh. 16.4 - Prob. 6PPCCh. 16.4 - Prob. 16.4.1SRCh. 16.4 - Prob. 16.4.2SRCh. 16.4 - Prob. 16.4.3SRCh. 16.4 - Prob. 16.4.4SRCh. 16.5 - Calculate the pH of an aqueous solution at 25C...Ch. 16.5 - Prob. 7PPACh. 16.5 - Prob. 7PPBCh. 16.5 - Prob. 7PPCCh. 16.5 - Prob. 16.8WECh. 16.5 - Calculate the concentration of HNO3 in a solution...Ch. 16.5 - Prob. 8PPBCh. 16.5 - Which of the plots [(i)(iv)] best approximates the...Ch. 16.5 - Prob. 16.9WECh. 16.5 - Prob. 9PPACh. 16.5 - Prob. 9PPBCh. 16.5 - Prob. 9PPCCh. 16.5 - Prob. 16.10WECh. 16.5 - Prob. 10PPACh. 16.5 - Prob. 10PPBCh. 16.5 - Prob. 10PPCCh. 16.5 - Prob. 16.5.1SRCh. 16.5 - Prob. 16.5.2SRCh. 16.5 - Prob. 16.5.3SRCh. 16.5 - Prob. 16.5.4SRCh. 16.5 - Prob. 16.5.5SRCh. 16.5 - Prob. 16.5.6SRCh. 16.5 - Prob. 16.5.7SRCh. 16.6 - The Ka of hypochlorous acid (HClO) is 3.5 108....Ch. 16.6 - Calculate the pH at 25C of a 0.18-M solution of a...Ch. 16.6 - Prob. 11PPBCh. 16.6 - The diagrams show solutions of four different weak...Ch. 16.6 - Determine the pH and percent ionization for acetic...Ch. 16.6 - Determine the pH and percent ionization for...Ch. 16.6 - At what concentration does hydrocyanic acid...Ch. 16.6 - Prob. 12PPCCh. 16.6 - Aspirin (acetylsalicylie acid, HC9H7O4) is a weak...Ch. 16.6 - Prob. 13PPACh. 16.6 - Prob. 13PPBCh. 16.6 - Calculate Ka values (to two significant figures)...Ch. 16.6 - Prob. 16.6.1SRCh. 16.6 - Prob. 16.6.2SRCh. 16.6 - Prob. 16.6.3SRCh. 16.7 - Prob. 16.14WECh. 16.7 - Calculate the pH at 25C of a 0.0028-M solution of...Ch. 16.7 - Prob. 14PPBCh. 16.7 - The diagrams represent solutions of three...Ch. 16.7 - Caffeine, the stimulant in coffee and tea, is a...Ch. 16.7 - Prob. 15PPACh. 16.7 - Prob. 15PPBCh. 16.7 - Prob. 15PPCCh. 16.7 - Prob. 16.7.1SRCh. 16.7 - Prob. 16.7.2SRCh. 16.7 - Prob. 16.7.3SRCh. 16.8 - Prob. 16.16WECh. 16.8 - Prob. 16PPACh. 16.8 - Prob. 16PPBCh. 16.8 - Prob. 16PPCCh. 16.8 - Prob. 16.8.1SRCh. 16.8 - Prob. 16.8.2SRCh. 16.8 - Prob. 16.8.3SRCh. 16.9 - Oxalic acid (H2C2O4) is a poisonous substance used...Ch. 16.9 - Calculate the concentrations of H2C2O4, HC2O4,...Ch. 16.9 - Calculate the concentrations of H2SO4, HSO4, SO42,...Ch. 16.9 - Prob. 17PPCCh. 16.9 - Prob. 16.9.1SRCh. 16.9 - Prob. 16.9.2SRCh. 16.9 - Prob. 16.9.3SRCh. 16.10 - Prob. 16.18WECh. 16.10 - Determine the pH of a 0.15-M solution of sodium...Ch. 16.10 - Prob. 18PPBCh. 16.10 - Winch of the graphs [(i)(iv)] best represents the...Ch. 16.10 - Calculate the pH of a 0.10-M solution of ammonium...Ch. 16.10 - Determine the pH of a 0.25-M solution of...Ch. 16.10 - Prob. 19PPBCh. 16.10 - Prob. 19PPCCh. 16.10 - Predict whether a 0.10-M solution of each of the...Ch. 16.10 - Predict whether a 0.10-M solution of each of the...Ch. 16.10 - Prob. 20PPBCh. 16.10 - Prob. 20PPCCh. 16.10 - Prob. 16.10.1SRCh. 16.10 - Prob. 16.10.2SRCh. 16.10 - Prob. 16.10.3SRCh. 16.10 - Prob. 16.10.4SRCh. 16.10 - Prob. 16.10.5SRCh. 16.12 - Identify the Lewis acid and Lewis base in each of...Ch. 16.12 - Prob. 21PPACh. 16.12 - Prob. 21PPBCh. 16.12 - Which of the diagrams best depicts the combination...Ch. 16.12 - Prob. 16.12.1SRCh. 16.12 - Prob. 16.12.2SRCh. 16 - F or a species to act as a Brnsted base, an atom...Ch. 16 - Identify the acid-base conjugate pairs in each of...Ch. 16 - Prob. 16.3QPCh. 16 - Prob. 16.4QPCh. 16 - Write the formulas of the conjugate bases of the...Ch. 16 - Prob. 16.6QPCh. 16 - Prob. 16.7QPCh. 16 - List four factors that affect the strength of an...Ch. 16 - Prob. 16.9QPCh. 16 - Prob. 16.10QPCh. 16 - Prob. 16.11QPCh. 16 - Prob. 16.12QPCh. 16 - Prob. 16.13QPCh. 16 - Write the equilibrium expression for the...Ch. 16 - Write an equation relating [H+] and [OH] in...Ch. 16 - Write an equation relating [H+] and [OH] in...Ch. 16 - Prob. 16.17QPCh. 16 - Prob. 16.18QPCh. 16 - Prob. 16.19QPCh. 16 - Prob. 16.20QPCh. 16 - Prob. 16.21QPCh. 16 - Prob. 16.22QPCh. 16 - Prob. 16.23QPCh. 16 - Calculate the concentration of H+ ions in a 0.62 M...Ch. 16 - Calculate the concentration of OH ions in a 1.4 ...Ch. 16 - Calculate the pH of each of the following...Ch. 16 - Calculate the pH of each of the following...Ch. 16 - Prob. 16.28QPCh. 16 - Prob. 16.29QPCh. 16 - Prob. 16.30QPCh. 16 - How much NaOH (in grams) is needed to prepare 546...Ch. 16 - Prob. 16.32QPCh. 16 - Why are ionizations of strong acids and strong...Ch. 16 - Prob. 16.34QPCh. 16 - Prob. 16.35QPCh. 16 - Prob. 16.36QPCh. 16 - Prob. 16.37QPCh. 16 - Prob. 16.38QPCh. 16 - Prob. 16.39QPCh. 16 - Prob. 16.40QPCh. 16 - Prob. 16.41QPCh. 16 - Prob. 16.42QPCh. 16 - Prob. 16.43QPCh. 16 - Prob. 16.1VCCh. 16 - Prob. 16.2VCCh. 16 - Prob. 16.3VCCh. 16 - Prob. 16.4VCCh. 16 - Prob. 16.44QPCh. 16 - Prob. 16.45QPCh. 16 - Prob. 16.46QPCh. 16 - Why do we normally not quote Ka values for strong...Ch. 16 - Why is it necessary to specify temperature when...Ch. 16 - Which of the following solutions has the highest...Ch. 16 - Prob. 16.50QPCh. 16 - The Ka for benzoic acid is 6.5 105. Calculate the...Ch. 16 - Calculate the pH of an aqueous solution at 25C...Ch. 16 - Calculate the pH of an aqueous solution at 25C...Ch. 16 - Determine the percent ionization of the following...Ch. 16 - Determine the percent ionization of the following...Ch. 16 - Prob. 16.56QPCh. 16 - A 0.015-M solution of a monoprotic acid is 0.92%...Ch. 16 - Prob. 16.58QPCh. 16 - Prob. 16.59QPCh. 16 - Prob. 16.60QPCh. 16 - Prob. 16.61QPCh. 16 - Prob. 16.62QPCh. 16 - In biological and medical applications, it is...Ch. 16 - Classify each of the following species as a weak...Ch. 16 - Prob. 16.65QPCh. 16 - Prob. 16.66QPCh. 16 - Prob. 16.67QPCh. 16 - Which of the following has a higher pH: (a) 1.0 M...Ch. 16 - Prob. 16.69QPCh. 16 - Prob. 16.70QPCh. 16 - Prob. 16.71QPCh. 16 - What is the original molarity of an aqueous...Ch. 16 - Prob. 16.73QPCh. 16 - Prob. 16.74QPCh. 16 - Prob. 16.75QPCh. 16 - Prob. 16.76QPCh. 16 - Prob. 16.77QPCh. 16 - Calculate Ka for each of the following ions: NH4+,...Ch. 16 - The following diagrams represent aqueous solutions...Ch. 16 - Prob. 16.80QPCh. 16 - Write all the species (except water) that are...Ch. 16 - Write the Ka1 and Ka2 expressions for sulfurous...Ch. 16 - Prob. 16.83QPCh. 16 - Prob. 16.84QPCh. 16 - Prob. 16.85QPCh. 16 - Prob. 16.86QPCh. 16 - Calculate the pH at 25C of a 0.25-M aqueous...Ch. 16 - The first and second ionization constants of a...Ch. 16 - Prob. 16.89QPCh. 16 - Prob. 16.90QPCh. 16 - Explain why small, highly charged metal ions are...Ch. 16 - Prob. 16.92QPCh. 16 - Specify which of the following salts will undergo...Ch. 16 - Prob. 16.94QPCh. 16 - Calculate the pH of a 0.42 M NH4Cl solution. (Kb...Ch. 16 - Calculate the pH of a 0.082 M NaF solution. (Ka...Ch. 16 - Calculate the pH of a 0.91 M C2H5NH3I solution....Ch. 16 - Prob. 16.98QPCh. 16 - Predict whether the following solutions are...Ch. 16 - Prob. 16.100QPCh. 16 - In a certain experiment, a student finds that the...Ch. 16 - Prob. 16.102QPCh. 16 - Prob. 16.103QPCh. 16 - Classify the following oxides as acidic, basic,...Ch. 16 - Prob. 16.105QPCh. 16 - Explain why metal oxides tend to be basic if the...Ch. 16 - Arrange the oxides in each of the following groups...Ch. 16 - Prob. 16.108QPCh. 16 - Prob. 16.109QPCh. 16 - Prob. 16.110QPCh. 16 - Prob. 16.111QPCh. 16 - Prob. 16.112QPCh. 16 - In terms of orbitals and electron arrangements,...Ch. 16 - Prob. 16.114QPCh. 16 - Prob. 16.115QPCh. 16 - Which would be considered a stronger Lewis acid:...Ch. 16 - Prob. 16.117QPCh. 16 - Identify the Lewis acid and the Lewis base in the...Ch. 16 - Identify the Lewis acid and the Lewis base in the...Ch. 16 - Prob. 16.120QPCh. 16 - Prob. 16.121QPCh. 16 - Prob. 16.122QPCh. 16 - Prob. 16.123QPCh. 16 - Prob. 16.124QPCh. 16 - Calculate the pH and percent ionization of a 0.88...Ch. 16 - Prob. 16.126QPCh. 16 - Prob. 16.127QPCh. 16 - The pH of a 0.0642-M solution of a monoprotic acid...Ch. 16 - Prob. 16.129QPCh. 16 - HA and HB are both weak acids although HB is the...Ch. 16 - Prob. 16.131QPCh. 16 - Prob. 16.132QPCh. 16 - Use the data in Table 16.5 to calculate the...Ch. 16 - Prob. 16.134QPCh. 16 - Most of the hydrides of Group 1A and Group 2 A...Ch. 16 - Prob. 16.136QPCh. 16 - Novocaine, used as a local anesthetic by dentists,...Ch. 16 - Which of the following is the stronger base: NF3...Ch. 16 - Prob. 16.139QPCh. 16 - The ion product of D20 is 1.35 1015 at 25C. (a)...Ch. 16 - Prob. 16.141QPCh. 16 - Prob. 16.142QPCh. 16 - Prob. 16.143QPCh. 16 - Prob. 16.144QPCh. 16 - Prob. 16.145QPCh. 16 - When the concentration of a strong acid is not...Ch. 16 - Calculate the pH of a 2.00 M NH4CN solution.Ch. 16 - Prob. 16.148QPCh. 16 - Prob. 16.149QPCh. 16 - Prob. 16.150QPCh. 16 - Prob. 16.151QPCh. 16 - Hydrocyanic acid (HCN) is a weak acid and a deadly...Ch. 16 - How many grams of NaCN would you need to dissolve...Ch. 16 - Prob. 16.154QPCh. 16 - Calculate the pH of a 1-L solution containing...Ch. 16 - Prob. 16.156QPCh. 16 - You are given two beakers, one containing an...Ch. 16 - Use Le Chteliers principle to predict the effect...Ch. 16 - A 0.400 M formic acid (HCOOH) solution freezes at...Ch. 16 - The disagreeable odor of fish is mainly due to...Ch. 16 - Prob. 16.161QPCh. 16 - Prob. 16.162QPCh. 16 - Both the amide ion (NH2) and the nitride ion (N3)...Ch. 16 - When carbon dioxide is bubbled through a clear...Ch. 16 - Explain the action of smelling salt, which is...Ch. 16 - About half of the hydrochloric acid produced...Ch. 16 - Which of the following does not represent a Lewis...Ch. 16 - Determine whether each of the following statements...Ch. 16 - How many milliliters of a strong monoprotic acid...Ch. 16 - Hemoglobin (Hb) is a blood protein that is...Ch. 16 - Prob. 16.171QPCh. 16 - Calculate the pH of a solution that is 1.00 M HCN...Ch. 16 - Tooth enamel is largely hydroxyapatite...Ch. 16 - Prob. 16.174QPCh. 16 - Prob. 16.175QPCh. 16 - Prob. 16.176QPCh. 16 - Sulfuric acid (H2SO4) accounts for as much as 80...Ch. 16 - A 1-87-g sample of Mg reacts with 80.0 mL of a HCl...Ch. 16 - Calculate the pH of a solution that is 0.22 M in...Ch. 16 - Determine pH at the equivalence point in the...Ch. 16 - Calculate the pH of a solution that is 0.22 M in...Ch. 16 - Determine pH at the equivalence point in the...
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