Introductory Chemistry: Concepts and Critical Thinking (8th Edition)
8th Edition
ISBN: 9780134421377
Author: Charles H Corwin
Publisher: PEARSON
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Question
Chapter 16, Problem 9E
Interpretation Introduction
Interpretation:
The energy profile diagram for the reaction involving phosphorous pentachloride used in the manufacturing of computer chips is to be drawn.
Concept introduction:
Reaction profile diagram shows the change in energy as the reaction progress. The transition state is the topmost point on the reaction profile diagram where bond breaking and new bonds formation takes place. Activation energy is the amount of energy required to convert reactants into transition state. In an endothermic reaction, heat is absorbed. In an exothermic reaction, heat is evolved.
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When an unknown amine reacts with an unknown acid chloride, an amide with a molecular mass of 163 g/mol (M* = 163 m/z)
is formed. In the infrared spectrum, important absorptions appear at 1661, 750 and 690 cm. The 13C NMR and DEPT spectra
are provided. Draw the structure of the product as the resonance contributor lacking any formal charges.
13C NMR
DEPT 90
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DEPT 135
T
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Draw the unknown amide.
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Chapter 16 Solutions
Introductory Chemistry: Concepts and Critical Thinking (8th Edition)
Ch. 16 - Prob. 1CECh. 16 - Prob. 2CECh. 16 - Prob. 3CECh. 16 - Prob. 4CECh. 16 - Prob. 5CECh. 16 - Prob. 6CECh. 16 - Prob. 7CECh. 16 - Prob. 8CECh. 16 - Prob. 9CECh. 16 - Prob. 10CE
Ch. 16 - Prob. 1KTCh. 16 - Prob. 2KTCh. 16 - Prob. 3KTCh. 16 - Prob. 4KTCh. 16 - Prob. 5KTCh. 16 - Prob. 6KTCh. 16 - Prob. 7KTCh. 16 - Prob. 8KTCh. 16 - Prob. 9KTCh. 16 - Prob. 10KTCh. 16 - Prob. 11KTCh. 16 - Prob. 12KTCh. 16 - Prob. 13KTCh. 16 - Prob. 14KTCh. 16 - Prob. 15KTCh. 16 - Prob. 16KTCh. 16 - Prob. 17KTCh. 16 - Prob. 18KTCh. 16 - Prob. 1ECh. 16 - Prob. 2ECh. 16 - Prob. 3ECh. 16 - Prob. 4ECh. 16 - Prob. 5ECh. 16 - Prob. 6ECh. 16 - Prob. 7ECh. 16 - Prob. 8ECh. 16 - Prob. 9ECh. 16 - Prob. 10ECh. 16 - Prob. 11ECh. 16 - Prob. 12ECh. 16 - Prob. 13ECh. 16 - Prob. 14ECh. 16 - Prob. 15ECh. 16 - Prob. 16ECh. 16 - Prob. 17ECh. 16 - Prob. 18ECh. 16 - Prob. 19ECh. 16 - Prob. 20ECh. 16 - Prob. 21ECh. 16 - Prob. 22ECh. 16 - Prob. 23ECh. 16 - Prob. 24ECh. 16 - Prob. 25ECh. 16 - Prob. 26ECh. 16 - Prob. 27ECh. 16 - Prob. 28ECh. 16 - Prob. 29ECh. 16 - Prob. 30ECh. 16 - Prob. 31ECh. 16 - Prob. 32ECh. 16 - Prob. 33ECh. 16 - Prob. 34ECh. 16 - Prob. 35ECh. 16 - Prob. 36ECh. 16 - Prob. 37ECh. 16 - Prob. 38ECh. 16 - Prob. 39ECh. 16 - Prob. 40ECh. 16 - Prob. 41ECh. 16 - Prob. 42ECh. 16 - Prob. 43ECh. 16 - Prob. 44ECh. 16 - Prob. 45ECh. 16 - Prob. 46ECh. 16 - Prob. 47ECh. 16 - Prob. 48ECh. 16 - Prob. 1STCh. 16 - Prob. 2STCh. 16 - Prob. 3STCh. 16 - Prob. 4STCh. 16 - Prob. 5STCh. 16 - Prob. 6STCh. 16 - Prob. 7STCh. 16 - Prob. 8STCh. 16 - Prob. 9STCh. 16 - Prob. 10STCh. 16 - Prob. 11STCh. 16 - Prob. 12STCh. 16 - Prob. 13STCh. 16 - Prob. 14STCh. 16 - Prob. 15ST
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