Introductory Chemistry: Concepts and Critical Thinking (8th Edition)
Introductory Chemistry: Concepts and Critical Thinking (8th Edition)
8th Edition
ISBN: 9780134421377
Author: Charles H Corwin
Publisher: PEARSON
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Chapter 16, Problem 19E
Interpretation Introduction

Interpretation:

The value of equilibrium constant, Keq for the reaction, 2SO2(g)+O2(g)2SO3(g), is to be calculated.

Concept introduction:

Chemical equilibrium is a state in which forward rate of reaction is equal to reverse rate of reaction at a given temperature. Law of chemical equilibrium states that at a given temperature ratio of molar concentration of products, each raised to a power equal to its coefficient, to the molar concentration of reactants, each raised to their coefficient, is constant.

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AG/F-2° V 3. Before proceeding with this problem you may want to glance at p. 466 of your textbook where various oxo-phosphorus derivatives and their oxidation states are summarized. Shown below are Latimer diagrams for phosphorus at pH values at 0 and 14: -0.93 +0.38 -0.50 -0.51 -0.06 H3PO4 →H4P206 →H3PO3 →→H3PO₂ → P → PH3 Acidic solution Basic solution -0.28 -0.50 3--1.12 -1.57 -2.05 -0.89 PO HPO H₂PO₂ →P → PH3 -1.73 a) Under acidic conditions, H3PO4 can be reduced into H3PO3 directly (-0.28V), or via the formation and reduction of H4P206 (-0.93/+0.38V). Calculate the values of AG's for both processes; comment. (3 points) 0.5 PH P 0.0 -0.5 -1.0- -1.5- -2.0 H.PO, -2.3+ -3 -2 -1 1 2 3 2 H,PO, b) Frost diagram for phosphorus under acidic conditions is shown. Identify possible disproportionation and comproportionation processes; write out chemical equations describing them. (2 points) H,PO 4 S Oxidation stale, N
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Introductory Chemistry: Concepts and Critical Thinking (8th Edition)

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