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Concept explainers
(a)
Interpretation:
Condensed structural formula has to be drawn for the given
Concept Introduction:
The structural representation of organic compound can be done in 2D and 3D. In two-dimensional representation, there are four types of representation in which an organic compound can be drawn. They are,
- Expanded structural formula
- Condensed structural formula
- Skeletal structural formula
- Line-angle structural formula
Structural formula which shows all the atoms in a molecule along with all the bonds that is connecting the atoms present in the molecule is known as Expanded structural formula.
Structural formula in which grouping of atoms are done and in which the central atoms along with the other atoms are connected to them are treated as group is known as Condensed structural formula.
Structural formula that shows the bonding between carbon atoms alone in the molecule ignoring the hydrogen atoms being shown explicitly is known as Skeletal structural formula.
Structural formula where a line represent carbon‑carbon bond and the carbon atom is considered to be present in each point and the end of lines is known as Line-angle structural formula.
(a)
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Answer to Problem 16.22EP
The condensed structural formula is,
Explanation of Solution
Given name of carboxylic acid is 2,3-dichlorohexanoic acid.
From the name it is identified that the parent carbon chain is hexane and the substituent present in the chain are two chlorine atoms, each on second and third carbon atom. The first carbon atom is from the carboxyl group. The structure can be drawn as,
The condensed structural formula for the given carboxylic acid is drawn as shown above.
The condensed structural formula for the given carboxylic acid is drawn.
(b)
Interpretation:
Condensed structural formula has to be drawn for the given carboxylic acid.
Concept Introduction:
The structural representation of organic compound can be done in 2D and 3D. In two-dimensional representation, there are four types of representation in which an organic compound can be drawn. They are,
- Expanded structural formula
- Condensed structural formula
- Skeletal structural formula
- Line-angle structural formula
Structural formula which shows all the atoms in a molecule along with all the bonds that is connecting the atoms present in the molecule is known as Expanded structural formula.
Structural formula in which grouping of atoms are done and in which the central atoms along with the other atoms are connected to them are treated as group is known as Condensed structural formula.
Structural formula that shows the bonding between carbon atoms alone in the molecule ignoring the hydrogen atoms being shown explicitly is known as Skeletal structural formula.
Structural formula where a line represent carbon‑carbon bond and the carbon atom is considered to be present in each point and the end of lines is known as Line-angle structural formula.
(b)
![Check Mark](/static/check-mark.png)
Answer to Problem 16.22EP
The condensed structural formula is,
Explanation of Solution
Given name of carboxylic acid is 2,3-dichlorohexanedioic acid.
From the name it is identified that the parent carbon chain is hexane and the substituent present in the chain are two chlorine atoms, each on second and third carbon atom. In the given name suffix “-dioic acid” is present. Therefore, this compound should have two carboxyl groups in it. The first carbon atom and sixth carbon is from the two carboxyl groups. The structure can be drawn as,
The condensed structural formula for the given carboxylic acid is drawn as shown above.
The condensed structural formula for the given carboxylic acid is drawn.
(c)
Interpretation:
Condensed structural formula has to be drawn for the given carboxylic acid.
Concept Introduction:
The structural representation of organic compound can be done in 2D and 3D. In two-dimensional representation, there are four types of representation in which an organic compound can be drawn. They are,
- Expanded structural formula
- Condensed structural formula
- Skeletal structural formula
- Line-angle structural formula
Structural formula which shows all the atoms in a molecule along with all the bonds that is connecting the atoms present in the molecule is known as Expanded structural formula.
Structural formula in which grouping of atoms are done and in which the central atoms along with the other atoms are connected to them are treated as group is known as Condensed structural formula.
Structural formula that shows the bonding between carbon atoms alone in the molecule ignoring the hydrogen atoms being shown explicitly is known as Skeletal structural formula.
Structural formula where a line represent carbon‑carbon bond and the carbon atom is considered to be present in each point and the end of lines is known as Line-angle structural formula.
(c)
![Check Mark](/static/check-mark.png)
Answer to Problem 16.22EP
The condensed structural formula is,
Explanation of Solution
Given name of carboxylic acid is 2,3-dichlorocyclopentanecarboxylic acid.
From the name it is identified that the parent carbon chain is cyclopentane and the substituent present in the chain are two chlorine atoms, each on second carbon atom and third carbon atom. In the given name suffix “-carboxylic acid” is present. Therefore, this compound should have a carboxyl group attached to the cyclopentane ring. The carbon atom in the ring where the carboxyl group is attached is the first carbon atom. The structure can be drawn as,
The condensed structural formula for the given carboxylic acid is drawn as shown above.
The condensed structural formula for the given carboxylic acid is drawn.
(d)
Interpretation:
Condensed structural formula has to be drawn for the given carboxylic acid.
Concept Introduction:
The structural representation of organic compound can be done in 2D and 3D. In two-dimensional representation, there are four types of representation in which an organic compound can be drawn. They are,
- Expanded structural formula
- Condensed structural formula
- Skeletal structural formula
- Line-angle structural formula
Structural formula which shows all the atoms in a molecule along with all the bonds that is connecting the atoms present in the molecule is known as Expanded structural formula.
Structural formula in which grouping of atoms are done and in which the central atoms along with the other atoms are connected to them are treated as group is known as Condensed structural formula.
Structural formula that shows the bonding between carbon atoms alone in the molecule ignoring the hydrogen atoms being shown explicitly is known as Skeletal structural formula.
Structural formula where a line represent carbon‑carbon bond and the carbon atom is considered to be present in each point and the end of lines is known as Line-angle structural formula.
(d)
![Check Mark](/static/check-mark.png)
Answer to Problem 16.22EP
The condensed structural formula is,
Explanation of Solution
Given name of carboxylic acid is 3,5-dichlorobenzenecarboxylic acid.
From the name it is identified that the parent carbon chain is benzene and the substituent present in the chain are two chlorine atoms, each on third carbon atom and fifth carbon atom. In the given name suffix “-carboxylic acid” is present. Therefore, this compound should have a carboxyl group attached to the benzene ring. The carbon atom in the ring where the carboxyl group is attached is the first carbon atom. The structure can be drawn as,
The condensed structural formula for the given carboxylic acid is drawn as shown above.
The condensed structural formula for the given carboxylic acid is drawn.
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Chapter 16 Solutions
General, Organic, And Biological Chemistry, Hybrid (with Owlv2 Quick Prep For General Chemistry Printed Access Card)
- (6 pts - 2 pts each part) Although we focused our discussion on hydrogen light emission, all elements have distinctive emission spectra. Sodium (Na) is famous for its spectrum being dominated by two yellow emission lines at 589.0 and 589.6 nm, respectively. These lines result from electrons relaxing to the 3s subshell. a. What is the photon energy (in J) for one of these emission lines? Show your work. b. To what electronic transition in hydrogen is this photon energy closest to? Justify your answer-you shouldn't need to do numerical calculations. c. Consider the 3s subshell energy for Na - use 0 eV as the reference point for n=∞. What is the energy of the subshell that the electron relaxes from? Choose the same emission line that you did for part (a) and show your work.arrow_forwardNonearrow_forward(9 Pts) In one of the two Rare Earth element rows of the periodic table, identify an exception to the general ionization energy (IE) trend. For the two elements involved, answer the following questions. Be sure to cite sources for all physical data that you use. a. (2 pts) Identify the two elements and write their electronic configurations. b. (2 pts) Based on their configurations, propose a reason for the IE trend exception. c. (5 pts) Calculate effective nuclear charges for the last electron in each element and the Allred-Rochow electronegativity values for the two elements. Can any of these values explain the IE trend exception? Explain how (not) - include a description of how IE relates to electronegativity.arrow_forward
- Please explain thoroughly and provide steps to draw.arrow_forwardAs you can see in the picture, the instrument uses a Xe source. Given that the instrument is capable of measuring from 200-800nm, if Xe was not used, what other source(s) could be used? Refer to figure 7-3. How many monochrometers does this instrument have? Why? Trace the light as it goes from the Xenon lamp all the way to the circle just slightly to the right and a little bit down from S4. What do you think that circle is? In class we talked about many types of these, which kind do you think this one is for a fluorimeter? Why? Explain. What is/are some strategy(ies) that this instrument has for dealing with noise that you see present in the optics diagram? Why does a fluorescence cuvette have to be clear on four sides?arrow_forwardProvide steps and thoroughly solve.arrow_forward
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