Condensed structural formula for acetyl chloride has to be drawn. Concept Introduction: General structure of acid chloride can be represented as shown below, The structure of the acid chloride can be derived from the IUPAC name or common name. “R” group present in the above structure is a part of the parent carboxylic acid from which the acid chloride is obtained. Name of the acid chloride is obtained by replacing “-oic acid” in the parent carboxylic acid name with “-oyl chloride”.

Question

Draw the structure of ,-diethyl--propylthiopentane. With explanation

Answer 1

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 16, Problem 16.146EP

(a)

Interpretation Introduction

Interpretation:

Condensed structural formula for acetyl chloride has to be drawn.

Concept Introduction:

General structure of acid chloride can be represented as shown below,

The structure of the acid chloride can be derived from the IUPAC name or common name. “R” group present in the above structure is a part of the parent carboxylic acid from which the acid chloride is obtained. Name of the acid chloride is obtained by replacing “-oic acid” in the parent carboxylic acid name with “-oyl chloride”.

(b)

Interpretation Introduction

Interpretation:

Condensed structural formula for 2-methylbutanoyl chloride has to be drawn.

Concept Introduction:

General structure of acid chloride can be represented as shown below,

The structure of the acid chloride can be derived from the IUPAC name or common name. “R” group present in the above structure is a part of the parent carboxylic acid from which the acid chloride is obtained. Name of the acid chloride is obtained by replacing “-oic acid” in the parent carboxylic acid name with “-oyl chloride”.

(c)

Interpretation Introduction

Interpretation:

Condensed structural formula for propionic anhydride has to be drawn.

Concept Introduction:

General structure of acid anhydride can be represented as shown below,

The structure of the acid anhydride can be derived from the IUPAC name or common name. “R, R₁” group present in the above structure is a part of the parent carboxylic acid from which the acid anhydride is obtained. If the acid anhydride is a symmetric one, then the name of acid anhydride is given by replacing the acid in the parent carboxylic acid name with anhydride. If the acid anhydride is an asymmetric one, then the name of acid anhydride is given by using the name of individual carboxylic acid in an alphabetical order followed by anhydride.

(d)

Interpretation Introduction

Interpretation:

Condensed structural formula for ethanoic methanoic anhydride has to be drawn.

Concept Introduction:

General structure of acid anhydride can be represented as shown below,

The structure of the acid anhydride can be derived from the IUPAC name or common name. “R, R₁” group present in the above structure is a part of the parent carboxylic acid from which the acid anhydride is obtained. If the acid anhydride is a symmetric one, then the name of acid anhydride is given by replacing the acid in the parent carboxylic acid name with anhydride. If the acid anhydride is an mixed one, then the name of acid anhydride is given by using the name of individual carboxylic acid in an alphabetical order followed by anhydride.

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Draw the structure of ,-diethyl--propylthiopentane. With explanation

A. Provide a stepwise mechanism for the formation of nerolidyl pyrophosphate fromfarnesylpyrophosphate B. Provide a stepwise mechanism for the formation of carbocation 1 from nerolidylpyrophosphate. Number the backbone carbons of nerolidyl pyrophosphate from 1 to 11 as shown, andinclude the carbon numbering in your structure of 1 C. Following from B, give an arrow-pushing mechanism to convert 1 to 2 and 2 to 3. Use thebackbone carbon numbering from 1 to indicate where carbon atoms ended up in 2 and 3 D. In addition to forming epi-cedrol, carbocation 3 gives three minor byproducts: a diastereomericalcohol and two alkenes. Draw mechanisms that could give rise to these three products

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Answer 2

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 16, Problem 16.146EP

(a)

Interpretation Introduction

Interpretation:

Condensed structural formula for acetyl chloride has to be drawn.

Concept Introduction:

General structure of acid chloride can be represented as shown below,

The structure of the acid chloride can be derived from the IUPAC name or common name. “R” group present in the above structure is a part of the parent carboxylic acid from which the acid chloride is obtained. Name of the acid chloride is obtained by replacing “-oic acid” in the parent carboxylic acid name with “-oyl chloride”.

(b)

Interpretation Introduction

Interpretation:

Condensed structural formula for 2-methylbutanoyl chloride has to be drawn.

Concept Introduction:

General structure of acid chloride can be represented as shown below,

The structure of the acid chloride can be derived from the IUPAC name or common name. “R” group present in the above structure is a part of the parent carboxylic acid from which the acid chloride is obtained. Name of the acid chloride is obtained by replacing “-oic acid” in the parent carboxylic acid name with “-oyl chloride”.

(c)

Interpretation Introduction

Interpretation:

Condensed structural formula for propionic anhydride has to be drawn.

Concept Introduction:

General structure of acid anhydride can be represented as shown below,

The structure of the acid anhydride can be derived from the IUPAC name or common name. “R, R₁” group present in the above structure is a part of the parent carboxylic acid from which the acid anhydride is obtained. If the acid anhydride is a symmetric one, then the name of acid anhydride is given by replacing the acid in the parent carboxylic acid name with anhydride. If the acid anhydride is an asymmetric one, then the name of acid anhydride is given by using the name of individual carboxylic acid in an alphabetical order followed by anhydride.

(d)

Interpretation Introduction

Interpretation:

Condensed structural formula for ethanoic methanoic anhydride has to be drawn.

Concept Introduction:

General structure of acid anhydride can be represented as shown below,

The structure of the acid anhydride can be derived from the IUPAC name or common name. “R, R₁” group present in the above structure is a part of the parent carboxylic acid from which the acid anhydride is obtained. If the acid anhydride is a symmetric one, then the name of acid anhydride is given by replacing the acid in the parent carboxylic acid name with anhydride. If the acid anhydride is an mixed one, then the name of acid anhydride is given by using the name of individual carboxylic acid in an alphabetical order followed by anhydride.

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Answer 3

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 16, Problem 16.146EP

(a)

Interpretation Introduction

Interpretation:

Condensed structural formula for acetyl chloride has to be drawn.

Concept Introduction:

General structure of acid chloride can be represented as shown below,

The structure of the acid chloride can be derived from the IUPAC name or common name. “R” group present in the above structure is a part of the parent carboxylic acid from which the acid chloride is obtained. Name of the acid chloride is obtained by replacing “-oic acid” in the parent carboxylic acid name with “-oyl chloride”.

(b)

Interpretation Introduction

Interpretation:

Condensed structural formula for 2-methylbutanoyl chloride has to be drawn.

Concept Introduction:

General structure of acid chloride can be represented as shown below,

The structure of the acid chloride can be derived from the IUPAC name or common name. “R” group present in the above structure is a part of the parent carboxylic acid from which the acid chloride is obtained. Name of the acid chloride is obtained by replacing “-oic acid” in the parent carboxylic acid name with “-oyl chloride”.

(c)

Interpretation Introduction

Interpretation:

Condensed structural formula for propionic anhydride has to be drawn.

Concept Introduction:

General structure of acid anhydride can be represented as shown below,

The structure of the acid anhydride can be derived from the IUPAC name or common name. “R, R₁” group present in the above structure is a part of the parent carboxylic acid from which the acid anhydride is obtained. If the acid anhydride is a symmetric one, then the name of acid anhydride is given by replacing the acid in the parent carboxylic acid name with anhydride. If the acid anhydride is an asymmetric one, then the name of acid anhydride is given by using the name of individual carboxylic acid in an alphabetical order followed by anhydride.

(d)

Interpretation Introduction

Interpretation:

Condensed structural formula for ethanoic methanoic anhydride has to be drawn.

Concept Introduction:

General structure of acid anhydride can be represented as shown below,

The structure of the acid anhydride can be derived from the IUPAC name or common name. “R, R₁” group present in the above structure is a part of the parent carboxylic acid from which the acid anhydride is obtained. If the acid anhydride is a symmetric one, then the name of acid anhydride is given by replacing the acid in the parent carboxylic acid name with anhydride. If the acid anhydride is an mixed one, then the name of acid anhydride is given by using the name of individual carboxylic acid in an alphabetical order followed by anhydride.

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Answer 4

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 16, Problem 16.146EP

(a)

Interpretation Introduction

Interpretation:

Condensed structural formula for acetyl chloride has to be drawn.

Concept Introduction:

General structure of acid chloride can be represented as shown below,

The structure of the acid chloride can be derived from the IUPAC name or common name. “R” group present in the above structure is a part of the parent carboxylic acid from which the acid chloride is obtained. Name of the acid chloride is obtained by replacing “-oic acid” in the parent carboxylic acid name with “-oyl chloride”.

(b)

Interpretation Introduction

Interpretation:

Condensed structural formula for 2-methylbutanoyl chloride has to be drawn.

Concept Introduction:

General structure of acid chloride can be represented as shown below,

The structure of the acid chloride can be derived from the IUPAC name or common name. “R” group present in the above structure is a part of the parent carboxylic acid from which the acid chloride is obtained. Name of the acid chloride is obtained by replacing “-oic acid” in the parent carboxylic acid name with “-oyl chloride”.

(c)

Interpretation Introduction

Interpretation:

Condensed structural formula for propionic anhydride has to be drawn.

Concept Introduction:

General structure of acid anhydride can be represented as shown below,

The structure of the acid anhydride can be derived from the IUPAC name or common name. “R, R₁” group present in the above structure is a part of the parent carboxylic acid from which the acid anhydride is obtained. If the acid anhydride is a symmetric one, then the name of acid anhydride is given by replacing the acid in the parent carboxylic acid name with anhydride. If the acid anhydride is an asymmetric one, then the name of acid anhydride is given by using the name of individual carboxylic acid in an alphabetical order followed by anhydride.

(d)

Interpretation Introduction

Interpretation:

Condensed structural formula for ethanoic methanoic anhydride has to be drawn.

Concept Introduction:

General structure of acid anhydride can be represented as shown below,

The structure of the acid anhydride can be derived from the IUPAC name or common name. “R, R₁” group present in the above structure is a part of the parent carboxylic acid from which the acid anhydride is obtained. If the acid anhydride is a symmetric one, then the name of acid anhydride is given by replacing the acid in the parent carboxylic acid name with anhydride. If the acid anhydride is an mixed one, then the name of acid anhydride is given by using the name of individual carboxylic acid in an alphabetical order followed by anhydride.

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Answer 5

Chapter 16, Problem 16.146EP

(a)

Interpretation Introduction

Interpretation:

Condensed structural formula for acetyl chloride has to be drawn.

Concept Introduction:

General structure of acid chloride can be represented as shown below,

The structure of the acid chloride can be derived from the IUPAC name or common name. “R” group present in the above structure is a part of the parent carboxylic acid from which the acid chloride is obtained. Name of the acid chloride is obtained by replacing “-oic acid” in the parent carboxylic acid name with “-oyl chloride”.

(b)

Interpretation Introduction

Interpretation:

Condensed structural formula for 2-methylbutanoyl chloride has to be drawn.

Concept Introduction:

General structure of acid chloride can be represented as shown below,

The structure of the acid chloride can be derived from the IUPAC name or common name. “R” group present in the above structure is a part of the parent carboxylic acid from which the acid chloride is obtained. Name of the acid chloride is obtained by replacing “-oic acid” in the parent carboxylic acid name with “-oyl chloride”.

(c)

Interpretation Introduction

Interpretation:

Condensed structural formula for propionic anhydride has to be drawn.

Concept Introduction:

General structure of acid anhydride can be represented as shown below,

The structure of the acid anhydride can be derived from the IUPAC name or common name. “R, R₁” group present in the above structure is a part of the parent carboxylic acid from which the acid anhydride is obtained. If the acid anhydride is a symmetric one, then the name of acid anhydride is given by replacing the acid in the parent carboxylic acid name with anhydride. If the acid anhydride is an asymmetric one, then the name of acid anhydride is given by using the name of individual carboxylic acid in an alphabetical order followed by anhydride.

(d)

Interpretation Introduction

Interpretation:

Condensed structural formula for ethanoic methanoic anhydride has to be drawn.

Concept Introduction:

General structure of acid anhydride can be represented as shown below,

The structure of the acid anhydride can be derived from the IUPAC name or common name. “R, R₁” group present in the above structure is a part of the parent carboxylic acid from which the acid anhydride is obtained. If the acid anhydride is a symmetric one, then the name of acid anhydride is given by replacing the acid in the parent carboxylic acid name with anhydride. If the acid anhydride is an mixed one, then the name of acid anhydride is given by using the name of individual carboxylic acid in an alphabetical order followed by anhydride.

Answer 6

Chapter 16, Problem 16.146EP

(a)

Interpretation Introduction

Interpretation:

Condensed structural formula for acetyl chloride has to be drawn.

Concept Introduction:

General structure of acid chloride can be represented as shown below,

The structure of the acid chloride can be derived from the IUPAC name or common name. “R” group present in the above structure is a part of the parent carboxylic acid from which the acid chloride is obtained. Name of the acid chloride is obtained by replacing “-oic acid” in the parent carboxylic acid name with “-oyl chloride”.

Answer 7

Chapter 16, Problem 16.146EP

(a)

Interpretation Introduction

Interpretation:

Condensed structural formula for acetyl chloride has to be drawn.

Concept Introduction:

General structure of acid chloride can be represented as shown below,

The structure of the acid chloride can be derived from the IUPAC name or common name. “R” group present in the above structure is a part of the parent carboxylic acid from which the acid chloride is obtained. Name of the acid chloride is obtained by replacing “-oic acid” in the parent carboxylic acid name with “-oyl chloride”.

Answer 8

(b)

Interpretation Introduction

Interpretation:

Condensed structural formula for 2-methylbutanoyl chloride has to be drawn.

Concept Introduction:

General structure of acid chloride can be represented as shown below,

The structure of the acid chloride can be derived from the IUPAC name or common name. “R” group present in the above structure is a part of the parent carboxylic acid from which the acid chloride is obtained. Name of the acid chloride is obtained by replacing “-oic acid” in the parent carboxylic acid name with “-oyl chloride”.

Answer 9

(b)

Interpretation Introduction

Interpretation:

Condensed structural formula for 2-methylbutanoyl chloride has to be drawn.

Concept Introduction:

General structure of acid chloride can be represented as shown below,

The structure of the acid chloride can be derived from the IUPAC name or common name. “R” group present in the above structure is a part of the parent carboxylic acid from which the acid chloride is obtained. Name of the acid chloride is obtained by replacing “-oic acid” in the parent carboxylic acid name with “-oyl chloride”.

Answer 10

(c)

Interpretation Introduction

Interpretation:

Condensed structural formula for propionic anhydride has to be drawn.

Concept Introduction:

General structure of acid anhydride can be represented as shown below,

The structure of the acid anhydride can be derived from the IUPAC name or common name. “R, R₁” group present in the above structure is a part of the parent carboxylic acid from which the acid anhydride is obtained. If the acid anhydride is a symmetric one, then the name of acid anhydride is given by replacing the acid in the parent carboxylic acid name with anhydride. If the acid anhydride is an asymmetric one, then the name of acid anhydride is given by using the name of individual carboxylic acid in an alphabetical order followed by anhydride.

Answer 11

(c)

Interpretation Introduction

Interpretation:

Condensed structural formula for propionic anhydride has to be drawn.

Concept Introduction:

General structure of acid anhydride can be represented as shown below,

The structure of the acid anhydride can be derived from the IUPAC name or common name. “R, R₁” group present in the above structure is a part of the parent carboxylic acid from which the acid anhydride is obtained. If the acid anhydride is a symmetric one, then the name of acid anhydride is given by replacing the acid in the parent carboxylic acid name with anhydride. If the acid anhydride is an asymmetric one, then the name of acid anhydride is given by using the name of individual carboxylic acid in an alphabetical order followed by anhydride.

Answer 12

(d)

Interpretation Introduction

Interpretation:

Condensed structural formula for ethanoic methanoic anhydride has to be drawn.

Concept Introduction:

General structure of acid anhydride can be represented as shown below,

The structure of the acid anhydride can be derived from the IUPAC name or common name. “R, R₁” group present in the above structure is a part of the parent carboxylic acid from which the acid anhydride is obtained. If the acid anhydride is a symmetric one, then the name of acid anhydride is given by replacing the acid in the parent carboxylic acid name with anhydride. If the acid anhydride is an mixed one, then the name of acid anhydride is given by using the name of individual carboxylic acid in an alphabetical order followed by anhydride.

Answer 13

(d)

Interpretation Introduction

Interpretation:

Condensed structural formula for ethanoic methanoic anhydride has to be drawn.

Concept Introduction:

General structure of acid anhydride can be represented as shown below,

The structure of the acid anhydride can be derived from the IUPAC name or common name. “R, R₁” group present in the above structure is a part of the parent carboxylic acid from which the acid anhydride is obtained. If the acid anhydride is a symmetric one, then the name of acid anhydride is given by replacing the acid in the parent carboxylic acid name with anhydride. If the acid anhydride is an mixed one, then the name of acid anhydride is given by using the name of individual carboxylic acid in an alphabetical order followed by anhydride.

Answer 14

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Answer 15

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Answer 25

Ch. 16.1 - Prob. 1QQ Ch. 16.1 - Prob. 2QQ Ch. 16.1 - Prob. 3QQ Ch. 16.1 - Prob. 4QQ Ch. 16.1 - Prob. 5QQ Ch. 16.2 - Prob. 1QQ Ch. 16.2 - Prob. 2QQ Ch. 16.2 - Prob. 3QQ Ch. 16.2 - Prob. 4QQ Ch. 16.2 - Prob. 5QQ

Solution Summary: The author explains that the structure of the acid chloride can be derived from the IUPAC name or common name.

Chapter 16 Solutions