The reaction of Al ( OH ) 3 with a base is to be written, and the type of reaction is to be identified. Concept introduction: Metals and transition metals combine with hydroxide ions to form metal hydroxides. Nature of all alkali and alkaline earth metal hydroxides is basic. Transition metal hydroxides show basic as well as acidic behavior. Thus, they are amphoteric in nature. Lewis acids are those species that can accept a lone pair of electrons. They need not have a hydrogen atom to be removed as a proton, but they are required to have an empty orbital to accommodate a lone pair of electrons. Lewis bases are those species that can donate a pair of electrons. They may not accept a proton, but they need to have a lone pair of electrons to be donated for bond formation.
The reaction of Al ( OH ) 3 with a base is to be written, and the type of reaction is to be identified. Concept introduction: Metals and transition metals combine with hydroxide ions to form metal hydroxides. Nature of all alkali and alkaline earth metal hydroxides is basic. Transition metal hydroxides show basic as well as acidic behavior. Thus, they are amphoteric in nature. Lewis acids are those species that can accept a lone pair of electrons. They need not have a hydrogen atom to be removed as a proton, but they are required to have an empty orbital to accommodate a lone pair of electrons. Lewis bases are those species that can donate a pair of electrons. They may not accept a proton, but they need to have a lone pair of electrons to be donated for bond formation.
Solution Summary: The author explains that the reaction of Al( OH)_3 with a base is to be written.
Definition Definition Elements containing partially filled d-subshell in their ground state configuration. Elements in the d-block of the periodic table receive the last or valence electron in the d-orbital. The groups from IIIB to VIIIB and IB to IIB comprise the d-block elements.
Chapter 16, Problem 113QP
Interpretation Introduction
Interpretation:
The reaction of Al(OH)3 with a base is to be written, and the type of reaction is to be identified.
Concept introduction:
Metals and transition metals combine with hydroxide ions to form metal hydroxides.
Nature of all alkali and alkaline earth metal hydroxides is basic.
Transition metal hydroxides show basic as well as acidic behavior. Thus, they are amphoteric in nature.
Lewis acids are those species that can accept a lone pair of electrons. They need not have a hydrogen atom to be removed as a proton, but they are required to have an empty orbital to accommodate a lone pair of electrons.
Lewis bases are those species that can donate a pair of electrons. They may not accept a proton, but they need to have a lone pair of electrons to be donated for bond formation.
Predict the major organic product(s) of the following reactions. Indicate which of the following mechanisms is in operation: SN1, SN2, E1, or E2.
(c)
(4pts)
Mechanism:
heat
(E1)
CH3OH
+
1.5pts each
_E1 _ (1pt)
Br
CH3OH
(d)
(4pts)
Mechanism:
SN1
(1pt)
(e)
(3pts)
1111 I
H
10
Ill!!
H
LDA
THF (solvent)
Mechanism: E2
(1pt)
NC
(f)
Bri!!!!!
CH3
NaCN
(3pts)
acetone
Mechanism: SN2
(1pt)
(SN1)
-OCH3
OCH3
1.5pts each
2pts for either product
1pt if incorrect
stereochemistry
H
Br
(g)
“,、
(3pts)
H
CH3OH
+21
Mechanism:
SN2
(1pt)
H
CH3
2pts
1pt if incorrect
stereochemistry
H
2pts
1pt if incorrect
stereochemistry
A mixture of butyl acrylate and 4'-chloropropiophenone has been taken for proton NMR analysis. Based on this proton NMR, determine the relative percentage of each compound in the mixture
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