General, Organic, & Biological Chemistry
General, Organic, & Biological Chemistry
3rd Edition
ISBN: 9780073511245
Author: Janice Gorzynski Smith Dr.
Publisher: McGraw-Hill Education
Question
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Chapter 15.8, Problem 15.22P
Interpretation Introduction

(a)

Interpretation:

The enantiomeric compound of W needs to be determined.

Concept introduction:

In chemistry, enantiomers are two stereoisomers that are mirror images of each other.

Interpretation Introduction

(b)

Interpretation:

The enantiomeric compound of Xneeds to be determined.

Concept introduction:

In chemistry, enantiomers are two stereoisomers that are mirror images of each other.

Interpretation Introduction

(c)

Interpretation:

The diastereomericcompound of Yneeds to be determined.

Concept introduction:

Diastereomers are compounds with same molecular formula, and also they should be non-mirror & non-identical stereoisomers.

Interpretation Introduction

(d)

Interpretation:

Thediastereomericcompound of Zneeds to be determined.

Concept introduction:

Diastereomers are compounds with same molecular formula, and also they should be non-mirror & non-identical stereoisomers.

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Assign ALL signals for the proton and carbon NMR spectra on the following pages.
7.5 1.93 2.05 C B A 4 3 5 The Joh. 9 7 8 1 2 7.5 7.0 6.5 6.0 5.5 5.0 4.5 4.0 3.5 3.0 2.5 2.0 1.5 1.0 ppm 9 7 8 0.86 OH 10 4 3 5 1 2 7.5 7.0 6.5 6.0 5.5 5.0 4.5 4.0 3.5 3.0 2.5 2.0 1.5 1.0 ppm 9 7 8 CI 4 3 5 1 2 7.0 6.5 6.0 5.5 5.0 4.5 4.0 3.5 3.0 2.5 2.0 2.21 4.00 1.5 2.00 2.07 1.0 ppm 2.76
Assign the functional group bands on the IR spectra.

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General, Organic, & Biological Chemistry

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