General, Organic, & Biological Chemistry
General, Organic, & Biological Chemistry
3rd Edition
ISBN: 9780073511245
Author: Janice Gorzynski Smith Dr.
Publisher: McGraw-Hill Education
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Chapter 15, Problem 15.31P
Interpretation Introduction

(a)

Interpretation:

The chirality center needs to be labeled in the given compound.

  CH3CH2CHCl2

Concept Introduction:

Chirality is the presence of an asymmetric carbon center in a molecule and a molecule which contains a chiral center cannot superimpose on its mirror image.

  General, Organic, & Biological Chemistry, Chapter 15, Problem 15.31P , additional homework tip  1

In the above diagram, where C is the chiral center/ asymmetric carbon center.

A, B, D, E are four different functional groups.

Interpretation Introduction

(b)

Interpretation:

Chirality center of the CH3-CHCH3-CH2-CHCl-CH3 molecule, should be labeled and identified.

Concept Introduction:

Chirality is the presence of an asymmetric carbon center in a molecule and a molecule which contains a chiral center cannot superimpose on its mirror image.

  General, Organic, & Biological Chemistry, Chapter 15, Problem 15.31P , additional homework tip  2

In the above diagram, where C is the chiral center/ asymmetric carbon center.

A, B, D, E are four different functional groups.

Interpretation Introduction

(c)

Interpretation:

Chirality center in the given molecule, should be labeled and identified.

  General, Organic, & Biological Chemistry, Chapter 15, Problem 15.31P , additional homework tip  3

Concept Introduction:

Chirality is the presence of an asymmetric carbon center in a molecule and a molecule which contains a chiral center cannot superimpose on its mirror image.

  General, Organic, & Biological Chemistry, Chapter 15, Problem 15.31P , additional homework tip  4

In the above diagram, where C is the chiral center/ asymmetric carbon center.

A, B, D, E are four different functional groups.

Interpretation Introduction

(d)

Interpretation:

Chirality center in the given molecule, should be labeled and identified.

  General, Organic, & Biological Chemistry, Chapter 15, Problem 15.31P , additional homework tip  5

Concept Introduction:

Chirality is the presence of an asymmetric carbon center in a molecule and a molecule which contains a chiral center cannot superimpose on its mirror image.

  General, Organic, & Biological Chemistry, Chapter 15, Problem 15.31P , additional homework tip  6

In the above diagram, where C is the chiral center/ asymmetric carbon center.

A, B, D, E are four different functional groups.

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Questions 4 and 5
For a titration of 40.00 mL of 0.0500 M oxalic acid H2C2O4 with 0.1000 M KOH, calculate the pH at each of the following volume of KOH used in the titration: 1) before the titration begin;2) 15 mL; 3) 20 mL; 4) 25 mL; 5) 40 mL; 6) 50 mL. Ka1 = 5.90×10^-2, Ka2 = 6.50×10^-5 for oxalic acid.
Predict the major organic product(s), if any, of the following reactions.  Assume all reagents are in excess unless otherwise indicated.

Chapter 15 Solutions

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