Biochemistry: The Molecular Basis of Life
6th Edition
ISBN: 9780190209896
Author: Trudy McKee, James R. McKee
Publisher: Oxford University Press
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Chapter 15, Problem 74TQ
Summary Introduction
To review:
The Krebs bicycle and calculate the ATPs degraded or synthesized and if the urea cycle is theenergy-requiring or synthesizing reaction.
Introduction:
The relationship between the CAC (citric acid cycle) and the urea cycle is often referred to as the Krebs bicycle. The urea cycle is a process of several biochemical reactions that occur in ureotelic animals for the conversion of toxic ammonia to nontoxic urea. This was the first
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Chapter 15 Solutions
Biochemistry: The Molecular Basis of Life
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- Give examples of balanced redox reactions that match the following:-Catabolic-Anabolic-Oxidative-Reductivearrow_forwardIf there are 20uM of a GLUT2 transporter on the surface of a cell, each able to move 8 per second, and 50mM glucose outside of the cell, what is the flux into the cell in mM/sec?arrow_forwardA transporter is responsible for antiporting calcium and glucose. The transporter brings glucose into the cell and sends calcium out of the cell. If blood [calcium] = 2.55mM and intracellular [calcium] = 7uM, blood [glucose] = 5.2mM, and intracellular [glucose] = 40uM, what is the free energy of transport? Assume a membrane potential of 62mV (negative inside).arrow_forward
- An ATP-coupled transporter is used to import 1 phosphate from the extracellular environment. Intracellular phosphate exists at 65mM, while it is 2mM outside.Assume a free energy change of ATP hydrolysis of -42.7 kJ/mol. What is the net free energy change of the coupled reaction? Assume a membrane potential of 70mV.arrow_forwardAnother transporter brings 3 chloride ions into the cell. Outside, chloride has a concentration of 107mM, and 4mM inside the cell. Assuming a membrane potential of 62mV (negative inside), what is the free energy of transport of these ions?arrow_forwardFor the Oxaloacetate -> Malate reaction, assume the normal ratio of NAD/NADH, what is the maximum ratio of Malate/Oxaloacetate that will allow reaction progress?arrow_forward
- A particular particle is trying to cross a membrane by simple diffusion from a high concentration of 20mM to a low concentration of 20uM. If a membrane is 15uM in width, and the diffusion coefficient of the particle is 5 uM/sec, what is the influx in uM/sec?arrow_forwardMechanisms: 1. Give a full arrow-pushing mechanism for the hydrolysis of the gamma phosphate of ATP by an ATPase. 2. Give a full arrow pushing mechanism of the spontaneous redox reaction between NAD+/NADH and oxaloacetate/malate.arrow_forwardDefine the difference between primary and secondary active transport. Is one preferable to another?arrow_forward
- Which B vitamin is responsible for generating the following:- FAD/FMN-NAD/NADH/NADP/NADPH-Coenzyme Aarrow_forwardWhat is the free energy change of an NADH mediated reduction of acetaldehyde to ethanol if blood ethanol is 0.2% by volume, and [Acetaldehyde] = 9uM. Assume the ratio of NAD/NADH is the same as discussed in class.arrow_forwardWhat is the role of each redox cofactor in the cell? Be specific about subcellular localization, etcarrow_forward
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