EBK FOUNDATIONS OF COLLEGE CHEMISTRY
EBK FOUNDATIONS OF COLLEGE CHEMISTRY
15th Edition
ISBN: 9781118930144
Author: Willard
Publisher: JOHN WILEY+SONS INC.
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Chapter 15, Problem 51AE

(a)

Interpretation Introduction

Interpretation:

Whether a substance that turns red litmus to blue is acidic, basic or neutral has to be determined.

Concept Introduction:

Acids are substances usually sour in taste, corrosive and turn blue litmus turns red. The bases are substances that are soapy to touch bitter and have ability to turn red litmus to blue. The neutral substances show no color change on test with litmus solution.

(b)

Interpretation Introduction

Interpretation:

Whether a substance with 6 as pH is acidic, basic or neutral has to be identified.

Concept Introduction:

The acidity strength is quantified by the magnitude of a parameter called pH. The strong acids tend to lower values of pH. This is since pH represents negative logarithm of concentration of H+ ion. So higher the concentration of H+ ion lower will be pH.

The expression to evaluate pOH is as follows:

  pOH=log[OH]

Here,

[OH] denotes concentration of OH ions.

The expression to evaluate pH from pOH is as follows:

  pH=14pOH

(c)

Interpretation Introduction

Interpretation:

Whether a substance with 1×107 M as concentration of H+ ion is acidic, basic or neutral has to be identified.

Concept Introduction:

The acidity strength is quantified by the magnitude of a parameter called pH. The strong acids tend to lower values of pH. This is since pH represents negative logarithm of concentration of H+ ion. So higher the concentration of H+ ion lower will be pH.

The expression to evaluate pH is as follows:

  pH=log[H+]

Here,

[H+] denotes concentration of H+ ions.

(d)

Interpretation Introduction

Interpretation:

Whether a substance that has 1×108 M as concentration of OH ion is acidic, basic or neutral has to be identified.

Concept Introduction:

Refer to part (b).

(e)

Interpretation Introduction

Interpretation:

Whether a substance that turns blue litmus to red is acidic, basic or neutral has to be determined.

Concept Introduction:

Refer to part (a).

(f)

Interpretation Introduction

Interpretation:

Whether a substance with 12 as pH is acidic, basic or neutral has to be identified.

Concept Introduction:

Refer to part (b).

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19.78 Write the products of the following sequences of reactions. Refer to your reaction road- maps to see how the combined reactions allow you to "navigate" between the different functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18 roadmaps along with your new Chapter 19 roadmap for these. (a) 1. BHS 2. H₂O₂ 3. H₂CrO4 4. SOCI₂ (b) 1. Cl₂/hv 2. KOLBU 3. H₂O, catalytic H₂SO4 4. H₂CrO4 Reaction Roadmap An alkene 5. EtOH 6.0.5 Equiv. NaOEt/EtOH 7. Mild H₂O An alkane 1.0 2. (CH3)₂S 3. H₂CrO (d) (c) 4. Excess EtOH, catalytic H₂SO OH 4. Mild H₂O* 5.0.5 Equiv. NaOEt/EtOH An alkene 6. Mild H₂O* A carboxylic acid 7. Mild H₂O* 1. SOC₁₂ 2. EtOH 3.0.5 Equiv. NaOEt/E:OH 5.1.0 Equiv. NaOEt 6. NH₂ (e) 1. 0.5 Equiv. NaOEt/EtOH 2. Mild H₂O* Br (f) i H An aldehyde 1. Catalytic NaOE/EtOH 2. H₂O*, heat 3. (CH,CH₂)₂Culi 4. Mild H₂O* 5.1.0 Equiv. LDA Br An ester 4. NaOH, H₂O 5. Mild H₂O* 6. Heat 7. MgBr 8. Mild H₂O* 7. Mild H₂O+
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Chapter 15 Solutions

EBK FOUNDATIONS OF COLLEGE CHEMISTRY

Ch. 15 - Prob. 3RQCh. 15 - Prob. 4RQCh. 15 - Prob. 5RQCh. 15 - Prob. 6RQCh. 15 - Prob. 7RQCh. 15 - Prob. 8RQCh. 15 - Prob. 9RQCh. 15 - Prob. 10RQCh. 15 - Prob. 11RQCh. 15 - Prob. 12RQCh. 15 - Prob. 13RQCh. 15 - Prob. 14RQCh. 15 - Prob. 15RQCh. 15 - Prob. 16RQCh. 15 - Prob. 17RQCh. 15 - Prob. 18RQCh. 15 - Prob. 19RQCh. 15 - Prob. 20RQCh. 15 - Prob. 21RQCh. 15 - Prob. 22RQCh. 15 - Prob. 23RQCh. 15 - Prob. 24RQCh. 15 - Prob. 25RQCh. 15 - Prob. 26RQCh. 15 - Prob. 27RQCh. 15 - Prob. 28RQCh. 15 - Prob. 1PECh. 15 - Prob. 2PECh. 15 - Prob. 3PECh. 15 - Prob. 4PECh. 15 - Prob. 5PECh. 15 - Prob. 6PECh. 15 - Prob. 7PECh. 15 - Prob. 8PECh. 15 - Prob. 9PECh. 15 - Prob. 10PECh. 15 - Prob. 11PECh. 15 - Prob. 12PECh. 15 - Prob. 13PECh. 15 - Prob. 14PECh. 15 - Prob. 15PECh. 15 - Prob. 16PECh. 15 - Prob. 17PECh. 15 - Prob. 18PECh. 15 - Prob. 19PECh. 15 - Prob. 20PECh. 15 - Prob. 21PECh. 15 - Prob. 22PECh. 15 - Prob. 23PECh. 15 - Prob. 24PECh. 15 - Prob. 25PECh. 15 - Prob. 26PECh. 15 - Prob. 27PECh. 15 - Prob. 28PECh. 15 - Prob. 29PECh. 15 - Prob. 30PECh. 15 - Prob. 31PECh. 15 - Prob. 32PECh. 15 - Prob. 33PECh. 15 - Prob. 34PECh. 15 - Prob. 35PECh. 15 - Prob. 36PECh. 15 - Prob. 37PECh. 15 - Prob. 38PECh. 15 - Prob. 39PECh. 15 - Prob. 40PECh. 15 - Prob. 41PECh. 15 - Prob. 42PECh. 15 - Prob. 43PECh. 15 - Prob. 44PECh. 15 - Prob. 45AECh. 15 - Prob. 46AECh. 15 - Prob. 47AECh. 15 - Prob. 48AECh. 15 - Prob. 49AECh. 15 - Prob. 50AECh. 15 - Prob. 51AECh. 15 - Prob. 52AECh. 15 - Prob. 53AECh. 15 - Prob. 54AECh. 15 - Prob. 55AECh. 15 - Prob. 56AECh. 15 - Prob. 57AECh. 15 - Prob. 58AECh. 15 - Prob. 59AECh. 15 - Prob. 60AECh. 15 - Prob. 61AECh. 15 - Prob. 62AECh. 15 - Prob. 63AECh. 15 - Prob. 64AECh. 15 - Prob. 65AECh. 15 - Prob. 66AECh. 15 - Prob. 67AECh. 15 - Prob. 68AECh. 15 - Prob. 69AECh. 15 - Prob. 70AECh. 15 - Prob. 71AECh. 15 - Prob. 72AECh. 15 - Prob. 73CECh. 15 - Prob. 74CE
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