
EBK FOUNDATIONS OF COLLEGE CHEMISTRY
15th Edition
ISBN: 9781118930144
Author: Willard
Publisher: JOHN WILEY+SONS INC.
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Chapter 15, Problem 3RQ
Interpretation Introduction
Interpretation:
Equations of neutralization of each of Arrhenius, Bronsted-Lowry and Lewis acid-bass have to be written.
Concept Introduction:
Arrhenius gave the broader picture and suggested that acids can release an excess of
Bronsted-Lowry acid outlined the definition of acids that donate
In accordance with Lewis concept, an acid species accepts an electron-pair from some other electron-rich species while a base that has generally more electron density donates it to another electron-deficient species.
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fcrip
= ↓ bandwidth Il temp
32. What impact (increase, decrease, or no change) does each of the following conditions have on the individual
components of the van Deemter equation and consequently, band broadening?
Increase temperature
Longer column
Using a gas mobile phase
instead of liquid
Smaller particle stationary phase
Multiple Paths
Diffusion
Mass Transfer
34. Figure 3 shows Van Deemter plots for a solute molecule using different column inner diameters (i.d.).
A) Predict whether decreasing the column inner diameters increase or decrease bandwidth.
B) Predict which van Deemter equation coefficient (A, B, or C) has the greatest effect on increasing or
decreasing bandwidth as a function of i.d. and justify your answer.
Figure 3 Van Deemter plots for hydroquinone using different column inner diameters (i.d. in μm). The data was
obtained from liquid chromatography experiments using fused-silica capillary columns packed with 1.0-μm particles.
35
20
H(um)
큰 20
15
90
0+
1500
100
75
550
01
02
594
05
μ(cm/sec)
30
15
10
elow are
experimentally determined van Deemter plots of column efficiency, H, vs. flow rate. H is a
quantitative measurement of band broadening. The left plot is for a liquid chromatography application and the
night is for gas chromatography. Compare and contrast these two plots in terms of the three band broadening
mechanisms presented in this activity. How are they similar? How do they differ? Justify your answers.?
0.4
H (mm)
0.2
0.1-
0.3-
0
0.5
H (mm)
8.0
7.0
6.0
5.0
4.0-
3.0
T
+++
1.0
1.5
0
2.0
4.0
Flow Rate, u (cm/s)
6.0
8.0
Flow Rate, u (cm/s)
Chapter 15 Solutions
EBK FOUNDATIONS OF COLLEGE CHEMISTRY
Ch. 15.1 - Prob. 15.1PCh. 15.1 - Prob. 15.2PCh. 15.2 - Prob. 15.3PCh. 15.2 - Prob. 15.4PCh. 15.3 - Prob. 15.5PCh. 15.4 - Prob. 15.6PCh. 15.5 - Prob. 15.7PCh. 15.6 - Prob. 15.8PCh. 15 - Prob. 1RQCh. 15 - Prob. 2RQ
Ch. 15 - Prob. 3RQCh. 15 - Prob. 4RQCh. 15 - Prob. 5RQCh. 15 - Prob. 6RQCh. 15 - Prob. 7RQCh. 15 - Prob. 8RQCh. 15 - Prob. 9RQCh. 15 - Prob. 10RQCh. 15 - Prob. 11RQCh. 15 - Prob. 12RQCh. 15 - Prob. 13RQCh. 15 - Prob. 14RQCh. 15 - Prob. 15RQCh. 15 - Prob. 16RQCh. 15 - Prob. 17RQCh. 15 - Prob. 18RQCh. 15 - Prob. 19RQCh. 15 - Prob. 20RQCh. 15 - Prob. 21RQCh. 15 - Prob. 22RQCh. 15 - Prob. 23RQCh. 15 - Prob. 24RQCh. 15 - Prob. 25RQCh. 15 - Prob. 26RQCh. 15 - Prob. 27RQCh. 15 - Prob. 28RQCh. 15 - Prob. 1PECh. 15 - Prob. 2PECh. 15 - Prob. 3PECh. 15 - Prob. 4PECh. 15 - Prob. 5PECh. 15 - Prob. 6PECh. 15 - Prob. 7PECh. 15 - Prob. 8PECh. 15 - Prob. 9PECh. 15 - Prob. 10PECh. 15 - Prob. 11PECh. 15 - Prob. 12PECh. 15 - Prob. 13PECh. 15 - Prob. 14PECh. 15 - Prob. 15PECh. 15 - Prob. 16PECh. 15 - Prob. 17PECh. 15 - Prob. 18PECh. 15 - Prob. 19PECh. 15 - Prob. 20PECh. 15 - Prob. 21PECh. 15 - Prob. 22PECh. 15 - Prob. 23PECh. 15 - Prob. 24PECh. 15 - Prob. 25PECh. 15 - Prob. 26PECh. 15 - Prob. 27PECh. 15 - Prob. 28PECh. 15 - Prob. 29PECh. 15 - Prob. 30PECh. 15 - Prob. 31PECh. 15 - Prob. 32PECh. 15 - Prob. 33PECh. 15 - Prob. 34PECh. 15 - Prob. 35PECh. 15 - Prob. 36PECh. 15 - Prob. 37PECh. 15 - Prob. 38PECh. 15 - Prob. 39PECh. 15 - Prob. 40PECh. 15 - Prob. 41PECh. 15 - Prob. 42PECh. 15 - Prob. 43PECh. 15 - Prob. 44PECh. 15 - Prob. 45AECh. 15 - Prob. 46AECh. 15 - Prob. 47AECh. 15 - Prob. 48AECh. 15 - Prob. 49AECh. 15 - Prob. 50AECh. 15 - Prob. 51AECh. 15 - Prob. 52AECh. 15 - Prob. 53AECh. 15 - Prob. 54AECh. 15 - Prob. 55AECh. 15 - Prob. 56AECh. 15 - Prob. 57AECh. 15 - Prob. 58AECh. 15 - Prob. 59AECh. 15 - Prob. 60AECh. 15 - Prob. 61AECh. 15 - Prob. 62AECh. 15 - Prob. 63AECh. 15 - Prob. 64AECh. 15 - Prob. 65AECh. 15 - Prob. 66AECh. 15 - Prob. 67AECh. 15 - Prob. 68AECh. 15 - Prob. 69AECh. 15 - Prob. 70AECh. 15 - Prob. 71AECh. 15 - Prob. 72AECh. 15 - Prob. 73CECh. 15 - Prob. 74CE
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