Connect 1-Semester Online Access for Principles of General, Organic & Biochemistry
Connect 1-Semester Online Access for Principles of General, Organic & Biochemistry
2nd Edition
ISBN: 9780077633707
Author: Janice Smith
Publisher: Mcgraw-hill Higher Education (us)
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Chapter 15, Problem 15.45AP

(a)

Interpretation Introduction

Interpretation:

Skeleton structure of fatty acid A with cis double bond has to be drawn.

Concept Introduction:

Fatty acid leads to formation of lipids and consists of a carboxyl group (COOH) with long straight chain of carbon and hydrogen atoms. Long straight-chain can be saturated as well as unsaturated. They comprise of a hydrophobic and hydrophilic part in their structure. The nonpolar or hydrophobic part of the chain consists of hydrocarbons that are insoluble in water. Therefore, fatty acids are not soluble in water.

(b)

Interpretation Introduction

Interpretation:

The omega-n designation for fatty acid A has to be identified.

Concept Introduction:

Fatty acids with unsaturation are classified as omega-n acids; here n is the carbon number from that the beginning of first double bond occurs in a carbon chain.

(c)

Interpretation Introduction

Interpretation:

Stereoisomer of fatty acid A has to be drawn.

Concept Introduction:

Some molecules have similar molecular structure but differ in the spatial arrangement of atoms that is atoms are located differently in space. Such molecules are termed as stereoisomers.

(d)

Interpretation Introduction

Interpretation:

Structure of wax formed from fatty acid A and CH3(CH2)10OH has to be drawn.

Concept Introduction:

Waxes are the type of nonpolar lipids that contain esters and are formed by the reaction of carboxylic acid with long chain alcohol by the removal of water. Generally, waxes are extracted from plants and animals. The reaction that explains the formation of wax is as follows:

Connect 1-Semester Online Access for Principles of General, Organic & Biochemistry, Chapter 15, Problem 15.45AP

Here, R and R are different alkyl groups.

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Arrange the fatty acids from highest melting point to lowest melting point. - CH3(CH2)10COOH - CH3(CH2)7CH=CH(CH2)7COOH - CH3(CH2)4(CH=CHCH2)4(CH2)2COOH - CH3(CH2)14COOH  Select the statements about fatty acid melting points that are true.  - A saturated fatty acid with a greater molar mass has a higher melting point than a saturated fatty acid with a lower molar mass. - A saturated fatty acid with a greater molar mass has a lower melting point than a saturated fatty acid with a lower molar mass. - A saturated fatty acid has a higher melting point than an unsaturated fatty acid. - A saturated fatty acid has a lower melting point than an unsaturated fatty acid.
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Chapter 15 Solutions

Connect 1-Semester Online Access for Principles of General, Organic & Biochemistry

Ch. 15.5 - Draw the products formed from hydrolysis of each...Ch. 15.5 - Prob. 15.12PCh. 15.6 - Draw the structure of two different cephalins...Ch. 15.6 - Classify each lipid as a triacylglycerol,...Ch. 15.7 - Why are phospholipids rather than triacylglycerols...Ch. 15.7 - Prob. 15.16PCh. 15.8 - Prob. 15.17PCh. 15.8 - Prob. 15.18PCh. 15.9 - Prob. 15.19PCh. 15.9 - Prob. 15.20PCh. 15.10 - Why is it much easier to overdose on a fat-soluble...Ch. 15.10 - Prob. 15.22PCh. 15 - Prob. 15.23UKCCh. 15 - Prob. 15.24UKCCh. 15 - Prob. 15.25UKCCh. 15 - What hydrolysis products are formed when the wax...Ch. 15 - Prob. 15.27UKCCh. 15 - Prob. 15.28UKCCh. 15 - Draw the products formed when the given...Ch. 15 - Prob. 15.30UKCCh. 15 - Prob. 15.31UKCCh. 15 - Prob. 15.32UKCCh. 15 - Prob. 15.33APCh. 15 - Label each compound as a hydrolyzable or...Ch. 15 - Prob. 15.35APCh. 15 - Prob. 15.36APCh. 15 - Prob. 15.37APCh. 15 - How does each of the following affect the melting...Ch. 15 - Rank the fatty acids in order of increasing...Ch. 15 - How would you expect the melting points of the...Ch. 15 - Prob. 15.41APCh. 15 - Why are soaps water soluble, but the fatty acids...Ch. 15 - Draw the structure of a wax formed from palmitic...Ch. 15 - Prob. 15.44APCh. 15 - Prob. 15.45APCh. 15 - Prob. 15.46APCh. 15 - Prob. 15.47APCh. 15 - What hydrolysis products are formed when each wax...Ch. 15 - Draw a triacylglycerol that fits each description:...Ch. 15 - Draw a triacylglycerol that fits each description:...Ch. 15 - Prob. 15.51APCh. 15 - Prob. 15.52APCh. 15 - Prob. 15.53APCh. 15 - Prob. 15.54APCh. 15 - Prob. 15.55APCh. 15 - Draw the products formed when the given...Ch. 15 - Prob. 15.57APCh. 15 - Prob. 15.58APCh. 15 - Prob. 15.59APCh. 15 - Prob. 15.60APCh. 15 - Prob. 15.61APCh. 15 - Why are LDLs soluble in the blood?Ch. 15 - Describe the role of HDLs and LDLs in cholesterol...Ch. 15 - Prob. 15.64APCh. 15 - Prob. 15.65APCh. 15 - Prob. 15.66APCh. 15 - Answer each question with regards to vitamins A...Ch. 15 - Answer each question in Problem 15.67 for vitamins...Ch. 15 - Prob. 15.69APCh. 15 - Prob. 15.70APCh. 15 - Prob. 15.71APCh. 15 - How are soaps and phosphoacylglycerols similar in...Ch. 15 - Some fish oils contain triacylglycerols formed...Ch. 15 - Some marine plankton contain triacylglycerols...Ch. 15 - Prob. 15.75APCh. 15 - Prob. 15.76APCh. 15 - Prob. 15.77APCh. 15 - Prob. 15.78APCh. 15 - Prob. 15.79CPCh. 15 - Prob. 15.80CP
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