Physical Chemistry
Physical Chemistry
2nd Edition
ISBN: 9781133958437
Author: Ball, David W. (david Warren), BAER, Tomas
Publisher: Wadsworth Cengage Learning,
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Chapter 15, Problem 15.3E
Interpretation Introduction

Interpretation:

The reason why the electronic transitions are considered dipole-moment allowed is to be stated.

Concept introduction:

The electronic transitions should have nonzero transition moment and should be given by the expression shown below.

M=Ψfinal*μ^Ψinitialdτ

Where,

Ψfinal* and Ψinitial are the final and initial wavefunctions.

μ^ is the electric dipole operator.

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Chapter 15 Solutions

Physical Chemistry

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