Physical Chemistry
2nd Edition
ISBN: 9781133958437
Author: Ball, David W. (david Warren), BAER, Tomas
Publisher: Wadsworth Cengage Learning,
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Chapter 15, Problem 15.31E
Use group-theoretical arguments to determine the term symbols for
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Identifying the major species in weak acid or weak base equilibria
The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at
equilibrium. You can leave out water itself.
Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the
formulas of the species that will act as neither acids nor bases in the 'other' row.
You will find it useful to keep in mind that NH3 is a weak base.
acids: ☐
1.8 mol of HCl is added to
1.0 L of a 1.0M NH3
bases: ☐
solution.
other: ☐
0.18 mol of HNO3 is added
to 1.0 L of a solution that is
1.4M in both NH3 and
NH₁Br.
acids:
bases: ☐
other: ☐
0,0,...
?
000
18
Ar
B
1
Using reaction free energy to predict equilibrium composition
Consider the following equilibrium:
2NH3 (g) = N2 (g) +3H₂
—N2 (g) AGº = 34. kJ
Now suppose a reaction vessel is filled with 4.19 atm of ammonia (NH3) and 9.94 atm of nitrogen (N2) at 378. °C. Answer the following questions about this
system:
rise
Under these conditions, will the pressure of NH 3 tend to rise or fall?
☐ x10
fall
Х
Is it possible to reverse this tendency by adding H₂?
In other words, if you said the pressure of NH 3 will tend to rise, can that
be changed to a tendency to fall by adding H₂? Similarly, if you said the
pressure of NH3 will tend to fall, can that be changed to a tendency to
rise by adding H₂?
If you said the tendency can be reversed in the second question, calculate
the minimum pressure of H₂ needed to reverse it.
Round your answer to 2 significant digits.
yes
no
atm
00.
18
Ar
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Identifying the major species in weak acid or weak base equilibria
The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at
equilibrium. You can leave out water itself.
Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the
formulas of the species that will act as neither acids nor bases in the 'other' row.
You will find it useful to keep in mind that HF is a weak acid.
2.2 mol of NaOH is added to
1.0 L of a 1.4M HF
solution.
acids:
П
bases:
Х
other: ☐
ப
acids:
0.51 mol of KOH is added to
1.0 L of a solution that is
bases:
1.3M in both HF and NaF.
other: ☐
00.
18
Ar
Chapter 15 Solutions
Physical Chemistry
Ch. 15 - Linearly polarized light can be assigned a...Ch. 15 - Linearly polarized light can be assigned a...Ch. 15 - Prob. 15.3ECh. 15 - Determine the value of R for deuterium (2H) and...Ch. 15 - Prob. 15.5ECh. 15 - Draw a Grotrian-type diagram for the first four...Ch. 15 - What is the value of the change in energy, E, for...Ch. 15 - Prob. 15.8ECh. 15 - List the possible values of L, ML, S, MS, J, and...Ch. 15 - Prob. 15.10E
Ch. 15 - Prob. 15.11ECh. 15 - Prob. 15.12ECh. 15 - Prob. 15.13ECh. 15 - What is the term symbol for the ground state of a...Ch. 15 - Prob. 15.15ECh. 15 - Prob. 15.16ECh. 15 - Prob. 15.17ECh. 15 - Prob. 15.18ECh. 15 - Prob. 15.19ECh. 15 - Prob. 15.20ECh. 15 - Prob. 15.21ECh. 15 - Prob. 15.22ECh. 15 - Use Hunds rules to predict the term symbol of the...Ch. 15 - Prob. 15.24ECh. 15 - Prob. 15.25ECh. 15 - An Mg atom is in the excited electron...Ch. 15 - Prob. 15.27ECh. 15 - Prob. 15.28ECh. 15 - Prob. 15.29ECh. 15 - Prob. 15.30ECh. 15 - Use group-theoretical arguments to determine the...Ch. 15 - The GeF molecule, which exists in the gas phase at...Ch. 15 - The SrH molecule in a 2+ electronic ground state....Ch. 15 - Prob. 15.34ECh. 15 - What are the values of and for NF in its 3...Ch. 15 - Prob. 15.36ECh. 15 - Determine the ground-state term symbol of the...Ch. 15 - Prob. 15.38ECh. 15 - Prob. 15.39ECh. 15 - Prob. 15.40ECh. 15 - Prob. 15.41ECh. 15 - Prob. 15.42ECh. 15 - The 1, 1'-diethyl-2, 2'-dicarbocyanine cation has...Ch. 15 - Prob. 15.44ECh. 15 - Naphthacene, C18H12, consists of four benzene...Ch. 15 - Prob. 15.46ECh. 15 - Prob. 15.47ECh. 15 - Construct the Hckel determinants for...Ch. 15 - Prob. 15.49ECh. 15 - Using the Internet, find a Hckel determinant...Ch. 15 - Prob. 15.51ECh. 15 - Explain why cyclopentadiene easily accepts an...Ch. 15 - Prob. 15.53ECh. 15 - Prob. 15.54ECh. 15 - Prob. 15.55ECh. 15 - Prob. 15.56ECh. 15 - Prob. 15.57ECh. 15 - Prob. 15.58ECh. 15 - Would the light from fireflies be considered an...Ch. 15 - Prob. 15.60ECh. 15 - Prob. 15.61ECh. 15 - Prob. 15.62ECh. 15 - How many 632.8-nm photons must a He-Ne laser emit...Ch. 15 - Prob. 15.64ECh. 15 - Green He-Ne lasers are also available; they emit...Ch. 15 - Blu-ray disks and high-density DVDs use an indium...Ch. 15 - Prob. 15.67ECh. 15 - Explain why X-ray lasers would be extremely...Ch. 15 - Prob. 15.69E
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