Physical Chemistry
2nd Edition
ISBN: 9781133958437
Author: Ball, David W. (david Warren), BAER, Tomas
Publisher: Wadsworth Cengage Learning,
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Chapter 15, Problem 15.35E
What are the values of
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Chapter 15 Solutions
Physical Chemistry
Ch. 15 - Linearly polarized light can be assigned a...Ch. 15 - Linearly polarized light can be assigned a...Ch. 15 - Prob. 15.3ECh. 15 - Determine the value of R for deuterium (2H) and...Ch. 15 - Prob. 15.5ECh. 15 - Draw a Grotrian-type diagram for the first four...Ch. 15 - What is the value of the change in energy, E, for...Ch. 15 - Prob. 15.8ECh. 15 - List the possible values of L, ML, S, MS, J, and...Ch. 15 - Prob. 15.10E
Ch. 15 - Prob. 15.11ECh. 15 - Prob. 15.12ECh. 15 - Prob. 15.13ECh. 15 - What is the term symbol for the ground state of a...Ch. 15 - Prob. 15.15ECh. 15 - Prob. 15.16ECh. 15 - Prob. 15.17ECh. 15 - Prob. 15.18ECh. 15 - Prob. 15.19ECh. 15 - Prob. 15.20ECh. 15 - Prob. 15.21ECh. 15 - Prob. 15.22ECh. 15 - Use Hunds rules to predict the term symbol of the...Ch. 15 - Prob. 15.24ECh. 15 - Prob. 15.25ECh. 15 - An Mg atom is in the excited electron...Ch. 15 - Prob. 15.27ECh. 15 - Prob. 15.28ECh. 15 - Prob. 15.29ECh. 15 - Prob. 15.30ECh. 15 - Use group-theoretical arguments to determine the...Ch. 15 - The GeF molecule, which exists in the gas phase at...Ch. 15 - The SrH molecule in a 2+ electronic ground state....Ch. 15 - Prob. 15.34ECh. 15 - What are the values of and for NF in its 3...Ch. 15 - Prob. 15.36ECh. 15 - Determine the ground-state term symbol of the...Ch. 15 - Prob. 15.38ECh. 15 - Prob. 15.39ECh. 15 - Prob. 15.40ECh. 15 - Prob. 15.41ECh. 15 - Prob. 15.42ECh. 15 - The 1, 1'-diethyl-2, 2'-dicarbocyanine cation has...Ch. 15 - Prob. 15.44ECh. 15 - Naphthacene, C18H12, consists of four benzene...Ch. 15 - Prob. 15.46ECh. 15 - Prob. 15.47ECh. 15 - Construct the Hckel determinants for...Ch. 15 - Prob. 15.49ECh. 15 - Using the Internet, find a Hckel determinant...Ch. 15 - Prob. 15.51ECh. 15 - Explain why cyclopentadiene easily accepts an...Ch. 15 - Prob. 15.53ECh. 15 - Prob. 15.54ECh. 15 - Prob. 15.55ECh. 15 - Prob. 15.56ECh. 15 - Prob. 15.57ECh. 15 - Prob. 15.58ECh. 15 - Would the light from fireflies be considered an...Ch. 15 - Prob. 15.60ECh. 15 - Prob. 15.61ECh. 15 - Prob. 15.62ECh. 15 - How many 632.8-nm photons must a He-Ne laser emit...Ch. 15 - Prob. 15.64ECh. 15 - Green He-Ne lasers are also available; they emit...Ch. 15 - Blu-ray disks and high-density DVDs use an indium...Ch. 15 - Prob. 15.67ECh. 15 - Explain why X-ray lasers would be extremely...Ch. 15 - Prob. 15.69E
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- although we associate Pz 2. Now we will move on to diatomic molecules. In atoms all p-orbitals are equivalent with m/= 0, and px py with m/= ±1. In diatomic molecules these orbitals are in fact separated, with pz associated with o orbitals along the internuclear axis and px py associated with л orbitals (m/= ±1). In determining electron configurations we do indeed separate them: N₂ (KK¹ 0₂²). and O2 (KKogu ng *2). 4 a. Two excited states of N₂ are associated with Tu transitions. Tg and og → ou* i. Draw the MO energy level scheme (p-orbitals only) for the N₂ ground state and for these two excited states. ii. Obtain the term symbols for the two excited states and order them according to Hund's rules. iii. Write the wave functions for each of the terms obtained in ii) above. iv. Pick one wave function from each excited state and show it obeys the Pauli Principle.arrow_forwardThe ground state of NO2 is A1 in the group C2v. To what excited states may it be excited by electric dipole transitions, and what polarization of light is it necessary to use?arrow_forward5. The ground state of NO2 is A1. To what excited states may it be excited by electric dipole transitions, and what polarizations of light is it necessary to use to get the transition.arrow_forward
- How would you explain the role of electron correlation in the accurate determination of molecular properties, and what is the significance of this correlation in quantum chemistry calculations?arrow_forwardWrite the noble gas orbital box electronic configuration of (i) S, and (ii) Ca*.arrow_forwardSuppose that the H2+ ion is excited by light so that an electron moves from a lower-energy to a higher energy MO. Would you expect the excited- state H2+ ion to be stable or to fall apart? Explain.arrow_forward
- Write the complete ground-state electron configuration of Cd²+. For multi-digit superscripts or coefficients, use each number in succession.arrow_forward[Ne]3s 3p* is electronic configuration of O Sulphur O oxygen O carbon O nitrogenarrow_forwardEvaluate the energy for two MO's generated by combining an H 1s atomic orbital with a F 2p atomic orbital. Use the equation: 1 2–252[H, 1 [H+H»- 2SH2]± 2-2s? + 4H, + H, -4SH„H„ -2H(H, +2SH, – 28²H,)| Carry out the calculation for S = 0.1, 0.2, and 0.6 to mimic the effect of decreasing the atomic separation in the molecule. Use the parameters: H,,= -13.6 ev, H22 = -18.6 eV, and H,2 = -1.75S H11H22 .arrow_forward
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