Chemistry Principles And Practice
3rd Edition
ISBN: 9781305295803
Author: David Reger; Scott Ball; Daniel Goode
Publisher: Cengage Learning
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Chapter 15, Problem 15.122QE
A Liquid HF undergoes an autoionization reaction:
- (a) Is KF an acid or a base in this solvent?
- (b) Perchloric acid, HCIO4, is a strong acid in liquid HF. Write the chemical equation for the ionization reaction.
- (c) Ammonia is a strong base in this solvent. Write the chemical equation for the ionization reaction.
- (d) Write the net ionic equation for the neutralization of perchloric acid with ammonia in this solvent.
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Draw the stepwise mechanism for the reactions
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Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone
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Chapter 15 Solutions
Chemistry Principles And Practice
Ch. 15 - Prob. 15.1QECh. 15 - Can a compound be an Arrhenius base and not a...Ch. 15 - Water is not the only solvent that undergoes...Ch. 15 - Write two BrnstedLowry acid-base reactions and...Ch. 15 - Define pH and explain why pH, rather than...Ch. 15 - Prob. 15.6QECh. 15 - Prob. 15.7QECh. 15 - Prob. 15.8QECh. 15 - Prob. 15.9QECh. 15 - Prob. 15.10QE
Ch. 15 - Prob. 15.11QECh. 15 - Prob. 15.12QECh. 15 - Why have chemists not tabulated the fraction...Ch. 15 - Prob. 15.15QECh. 15 - Prob. 15.16QECh. 15 - Prob. 15.17QECh. 15 - Prob. 15.18QECh. 15 - Define oxyacid and give examples from among the...Ch. 15 - Prob. 15.20QECh. 15 - Prob. 15.21QECh. 15 - Prob. 15.22QECh. 15 - Prob. 15.23QECh. 15 - Prob. 15.24QECh. 15 - Prob. 15.25QECh. 15 - Write the formula and name for the conjugate acid...Ch. 15 - For each of the following reactions, identify the...Ch. 15 - Prob. 15.28QECh. 15 - Prob. 15.29QECh. 15 - Prob. 15.30QECh. 15 - Prob. 15.31QECh. 15 - Write an equation to describe the proton transfer...Ch. 15 - Prob. 15.33QECh. 15 - Determine the hydrogen ion or hydroxide ion...Ch. 15 - Prob. 15.35QECh. 15 - The hydroxide ion concentrations in wines actually...Ch. 15 - Prob. 15.37QECh. 15 - Prob. 15.38QECh. 15 - Prob. 15.39QECh. 15 - Prob. 15.40QECh. 15 - Prob. 15.41QECh. 15 - Prob. 15.42QECh. 15 - Prob. 15.43QECh. 15 - Prob. 15.44QECh. 15 - Prob. 15.45QECh. 15 - Prob. 15.46QECh. 15 - A saturated solution of milk of magnesia, Mg(OH)2,...Ch. 15 - Find [OH] and the pH of the following solutions....Ch. 15 - Write the chemical equation for the ionization of...Ch. 15 - Prob. 15.50QECh. 15 - Prob. 15.51QECh. 15 - Prob. 15.52QECh. 15 - Prob. 15.53QECh. 15 - Assuming that the conductivity of an acid solution...Ch. 15 - Prob. 15.55QECh. 15 - Prob. 15.56QECh. 15 - Prob. 15.57QECh. 15 - Prob. 15.58QECh. 15 - Prob. 15.59QECh. 15 - A 0.10 M solution of chloroacetic acid, ClCH2COOH,...Ch. 15 - Prob. 15.61QECh. 15 - Prob. 15.62QECh. 15 - Prob. 15.63QECh. 15 - Prob. 15.64QECh. 15 - Prob. 15.65QECh. 15 - Prob. 15.66QECh. 15 - Prob. 15.67QECh. 15 - Prob. 15.68QECh. 15 - Write the chemical equation for the ionization of...Ch. 15 - Prob. 15.70QECh. 15 - Hydrazine, N2H4, is weak base with Kb = 1.3 106....Ch. 15 - Prob. 15.72QECh. 15 - Prob. 15.73QECh. 15 - Prob. 15.74QECh. 15 - Calculate the [OH] and the pH of a 0.024 M...Ch. 15 - Prob. 15.76QECh. 15 - Prob. 15.77QECh. 15 - Prob. 15.78QECh. 15 - Prob. 15.79QECh. 15 - Prob. 15.80QECh. 15 - Find the value of Kb for the conjugate base of the...Ch. 15 - Consider sodium acrylate, NaC3H3O2. Ka for acrylic...Ch. 15 - Prob. 15.83QECh. 15 - Prob. 15.84QECh. 15 - Prob. 15.85QECh. 15 - Prob. 15.86QECh. 15 - Prob. 15.87QECh. 15 - Prob. 15.88QECh. 15 - Prob. 15.89QECh. 15 - Prob. 15.90QECh. 15 - Prob. 15.91QECh. 15 - Prob. 15.92QECh. 15 - Prob. 15.93QECh. 15 - Prob. 15.94QECh. 15 - Explain how to calculate the pH of a solution that...Ch. 15 - Prob. 15.96QECh. 15 - Prob. 15.97QECh. 15 - Prob. 15.98QECh. 15 - Hypofluorous acid, HOF, is known, but fluorous...Ch. 15 - Prob. 15.100QECh. 15 - Prob. 15.101QECh. 15 - Prob. 15.102QECh. 15 - Which of each pair of acids is stronger? Why? (a)...Ch. 15 - Prob. 15.104QECh. 15 - Prob. 15.105QECh. 15 - Prob. 15.106QECh. 15 - Prob. 15.107QECh. 15 - Prob. 15.108QECh. 15 - Prob. 15.109QECh. 15 - Prob. 15.110QECh. 15 - Prob. 15.111QECh. 15 - Prob. 15.112QECh. 15 - Prob. 15.113QECh. 15 - Prob. 15.114QECh. 15 - Prob. 15.115QECh. 15 - Prob. 15.116QECh. 15 - Prob. 15.117QECh. 15 - Prob. 15.118QECh. 15 - Prob. 15.119QECh. 15 - Prob. 15.120QECh. 15 - A solution is made by diluting 25.0 mL of...Ch. 15 - A Liquid HF undergoes an autoionization reaction:...Ch. 15 - Pure liquid ammonia ionizes in a manner similar to...Ch. 15 - Prob. 15.124QECh. 15 - Prob. 15.125QECh. 15 - Prob. 15.126QECh. 15 - Prob. 15.127QECh. 15 - Prob. 15.128QECh. 15 - An aqueous solution contains formic acid and...Ch. 15 - A solution is made by dissolving 15.0 g sodium...Ch. 15 - Calculate the pH of a solution prepared by adding...Ch. 15 - Prob. 15.132QECh. 15 - Prob. 15.133QECh. 15 - When perchloric acid ionizes, it makes the...Ch. 15 - Prob. 15.135QE
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- Part I. Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff: Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone and (3,3-dimethyl-2-butanone) 2,3-dimethyl-1,3-butadiene. Give reasonable mechanism the formation of the products Forarrow_forwardShow the mechanism for these reactionsarrow_forwardDraw the stepwise mechanismarrow_forward
- Draw a structural formula of the principal product formed when benzonitrile is treated with each reagent. (a) H₂O (one equivalent), H₂SO₄, heat (b) H₂O (excess), H₂SO₄, heat (c) NaOH, H₂O, heat (d) LiAlH4, then H₂Oarrow_forwardDraw the stepwise mechanism for the reactionsarrow_forwardDraw stepwise mechanismarrow_forward
- Part I. Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff: a) Give the major reason for the exposure of benzophenone al isopropyl alcohol (w/acid) to direct sunlight of pina colone Mechanism For b) Pinacol (2,3-dimethy 1, 1-3-butanediol) on treatment w/ acid gives a mixture (3,3-dimethyl-2-butanone) and 2, 3-dimethyl-1,3-butadiene. Give reasonable the formation of the productsarrow_forwardwhat are the Iupac names for each structurearrow_forwardWhat are the IUPAC Names of all the compounds in the picture?arrow_forward
- 1) a) Give the dominant Intermolecular Force (IMF) in a sample of each of the following compounds. Please show your work. (8) SF2, CH,OH, C₂H₂ b) Based on your answers given above, list the compounds in order of their Boiling Point from low to high. (8)arrow_forward19.78 Write the products of the following sequences of reactions. Refer to your reaction road- maps to see how the combined reactions allow you to "navigate" between the different functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18 roadmaps along with your new Chapter 19 roadmap for these. (a) 1. BHS 2. H₂O₂ 3. H₂CrO4 4. SOCI₂ (b) 1. Cl₂/hv 2. KOLBU 3. H₂O, catalytic H₂SO4 4. H₂CrO4 Reaction Roadmap An alkene 5. EtOH 6.0.5 Equiv. NaOEt/EtOH 7. Mild H₂O An alkane 1.0 2. (CH3)₂S 3. H₂CrO (d) (c) 4. Excess EtOH, catalytic H₂SO OH 4. Mild H₂O* 5.0.5 Equiv. NaOEt/EtOH An alkene 6. Mild H₂O* A carboxylic acid 7. Mild H₂O* 1. SOC₁₂ 2. EtOH 3.0.5 Equiv. NaOEt/E:OH 5.1.0 Equiv. NaOEt 6. NH₂ (e) 1. 0.5 Equiv. NaOEt/EtOH 2. Mild H₂O* Br (f) i H An aldehyde 1. Catalytic NaOE/EtOH 2. H₂O*, heat 3. (CH,CH₂)₂Culi 4. Mild H₂O* 5.1.0 Equiv. LDA Br An ester 4. NaOH, H₂O 5. Mild H₂O* 6. Heat 7. MgBr 8. Mild H₂O* 7. Mild H₂O+arrow_forwardLi+ is a hard acid. With this in mind, which if the following compounds should be most soluble in water? Group of answer choices LiBr LiI LiF LiClarrow_forward
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