
Chemistry Principles And Practice
3rd Edition
ISBN: 9781305295803
Author: David Reger; Scott Ball; Daniel Goode
Publisher: Cengage Learning
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Chapter 15, Problem 15.115QE
Interpretation Introduction
Interpretation:
Fraction of benzoic acid ionized in
Concept Introduction:
The ionization of a hypothetical weak acid
The formula to calculate the fraction ionized is as follows:
Here,
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Using reaction free energy to predict equilibrium composition
Consider the following equilibrium:
2NO(g) +Cl₂ (g) = 2NOC1 (g) AGº = -41. kJ
Now suppose a reaction vessel is filled with 8.90 atm of chlorine (C12) and 5.71 atm of nitrosyl chloride (NOC1) at 1075. °C. Answer the following questions
about this system:
rise
Under these conditions, will the pressure of NOCI tend to rise or fall?
x10
fall
Is it possible to reverse this tendency by adding NO?
In other words, if you said the pressure of NOCI will tend to rise, can that
be changed to a tendency to fall by adding NO? Similarly, if you said the
pressure of NOCI will tend to fall, can that be changed to a tendency to
rise by adding NO?
yes
no
If you said the tendency can be reversed in the second question, calculate
the minimum pressure of NO needed to reverse it.
Round your answer to 2 significant digits.
atm
☑
18
Ar
Identifying the major species in weak acid or weak base equilibria
The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at
equilibrium. You can leave out water itself.
Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the
formulas of the species that will act as neither acids nor bases in the 'other' row.
You will find it useful to keep in mind that HCN is a weak acid.
acids:
0.29 mol of NaOH is added
to 1.0 L of a 1.2M HCN
solution.
bases:
☑
other:
0.09 mol of HCl is added to
acids:
1.0 L of a solution that is
bases:
0.3M in both HCN and
KCN.
other:
0,0,...
?
00.
18
Ar
日
Chapter 15 Solutions
Chemistry Principles And Practice
Ch. 15 - Prob. 15.1QECh. 15 - Can a compound be an Arrhenius base and not a...Ch. 15 - Water is not the only solvent that undergoes...Ch. 15 - Write two BrnstedLowry acid-base reactions and...Ch. 15 - Define pH and explain why pH, rather than...Ch. 15 - Prob. 15.6QECh. 15 - Prob. 15.7QECh. 15 - Prob. 15.8QECh. 15 - Prob. 15.9QECh. 15 - Prob. 15.10QE
Ch. 15 - Prob. 15.11QECh. 15 - Prob. 15.12QECh. 15 - Why have chemists not tabulated the fraction...Ch. 15 - Prob. 15.15QECh. 15 - Prob. 15.16QECh. 15 - Prob. 15.17QECh. 15 - Prob. 15.18QECh. 15 - Define oxyacid and give examples from among the...Ch. 15 - Prob. 15.20QECh. 15 - Prob. 15.21QECh. 15 - Prob. 15.22QECh. 15 - Prob. 15.23QECh. 15 - Prob. 15.24QECh. 15 - Prob. 15.25QECh. 15 - Write the formula and name for the conjugate acid...Ch. 15 - For each of the following reactions, identify the...Ch. 15 - Prob. 15.28QECh. 15 - Prob. 15.29QECh. 15 - Prob. 15.30QECh. 15 - Prob. 15.31QECh. 15 - Write an equation to describe the proton transfer...Ch. 15 - Prob. 15.33QECh. 15 - Determine the hydrogen ion or hydroxide ion...Ch. 15 - Prob. 15.35QECh. 15 - The hydroxide ion concentrations in wines actually...Ch. 15 - Prob. 15.37QECh. 15 - Prob. 15.38QECh. 15 - Prob. 15.39QECh. 15 - Prob. 15.40QECh. 15 - Prob. 15.41QECh. 15 - Prob. 15.42QECh. 15 - Prob. 15.43QECh. 15 - Prob. 15.44QECh. 15 - Prob. 15.45QECh. 15 - Prob. 15.46QECh. 15 - A saturated solution of milk of magnesia, Mg(OH)2,...Ch. 15 - Find [OH] and the pH of the following solutions....Ch. 15 - Write the chemical equation for the ionization of...Ch. 15 - Prob. 15.50QECh. 15 - Prob. 15.51QECh. 15 - Prob. 15.52QECh. 15 - Prob. 15.53QECh. 15 - Assuming that the conductivity of an acid solution...Ch. 15 - Prob. 15.55QECh. 15 - Prob. 15.56QECh. 15 - Prob. 15.57QECh. 15 - Prob. 15.58QECh. 15 - Prob. 15.59QECh. 15 - A 0.10 M solution of chloroacetic acid, ClCH2COOH,...Ch. 15 - Prob. 15.61QECh. 15 - Prob. 15.62QECh. 15 - Prob. 15.63QECh. 15 - Prob. 15.64QECh. 15 - Prob. 15.65QECh. 15 - Prob. 15.66QECh. 15 - Prob. 15.67QECh. 15 - Prob. 15.68QECh. 15 - Write the chemical equation for the ionization of...Ch. 15 - Prob. 15.70QECh. 15 - Hydrazine, N2H4, is weak base with Kb = 1.3 106....Ch. 15 - Prob. 15.72QECh. 15 - Prob. 15.73QECh. 15 - Prob. 15.74QECh. 15 - Calculate the [OH] and the pH of a 0.024 M...Ch. 15 - Prob. 15.76QECh. 15 - Prob. 15.77QECh. 15 - Prob. 15.78QECh. 15 - Prob. 15.79QECh. 15 - Prob. 15.80QECh. 15 - Find the value of Kb for the conjugate base of the...Ch. 15 - Consider sodium acrylate, NaC3H3O2. Ka for acrylic...Ch. 15 - Prob. 15.83QECh. 15 - Prob. 15.84QECh. 15 - Prob. 15.85QECh. 15 - Prob. 15.86QECh. 15 - Prob. 15.87QECh. 15 - Prob. 15.88QECh. 15 - Prob. 15.89QECh. 15 - Prob. 15.90QECh. 15 - Prob. 15.91QECh. 15 - Prob. 15.92QECh. 15 - Prob. 15.93QECh. 15 - Prob. 15.94QECh. 15 - Explain how to calculate the pH of a solution that...Ch. 15 - Prob. 15.96QECh. 15 - Prob. 15.97QECh. 15 - Prob. 15.98QECh. 15 - Hypofluorous acid, HOF, is known, but fluorous...Ch. 15 - Prob. 15.100QECh. 15 - Prob. 15.101QECh. 15 - Prob. 15.102QECh. 15 - Which of each pair of acids is stronger? Why? (a)...Ch. 15 - Prob. 15.104QECh. 15 - Prob. 15.105QECh. 15 - Prob. 15.106QECh. 15 - Prob. 15.107QECh. 15 - Prob. 15.108QECh. 15 - Prob. 15.109QECh. 15 - Prob. 15.110QECh. 15 - Prob. 15.111QECh. 15 - Prob. 15.112QECh. 15 - Prob. 15.113QECh. 15 - Prob. 15.114QECh. 15 - Prob. 15.115QECh. 15 - Prob. 15.116QECh. 15 - Prob. 15.117QECh. 15 - Prob. 15.118QECh. 15 - Prob. 15.119QECh. 15 - Prob. 15.120QECh. 15 - A solution is made by diluting 25.0 mL of...Ch. 15 - A Liquid HF undergoes an autoionization reaction:...Ch. 15 - Pure liquid ammonia ionizes in a manner similar to...Ch. 15 - Prob. 15.124QECh. 15 - Prob. 15.125QECh. 15 - Prob. 15.126QECh. 15 - Prob. 15.127QECh. 15 - Prob. 15.128QECh. 15 - An aqueous solution contains formic acid and...Ch. 15 - A solution is made by dissolving 15.0 g sodium...Ch. 15 - Calculate the pH of a solution prepared by adding...Ch. 15 - Prob. 15.132QECh. 15 - Prob. 15.133QECh. 15 - When perchloric acid ionizes, it makes the...Ch. 15 - Prob. 15.135QE
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