The unit for the rate of a chemical reaction should be stated. Concept Introduction: Rate of reaction represents the change of concentration of a reactant or a product with respect to time. It can be expressed either by reduce amount of reactant in per unit time or increase amount of product in per unit time.

Question

16. The proton NMR spectral information shown in this problem is for a compound with formula CioH,N. Expansions are shown for the region from 8.7 to 7.0 ppm. The normal carbon-13 spec- tral results, including DEPT-135 and DEPT-90 results, are tabulated: 7 J Normal Carbon DEPT-135 DEPT-90 19 ppm Positive No peak 122 Positive Positive cus и 124 Positive Positive 126 Positive Positive 128 No peak No peak 4° 129 Positive Positive 130 Positive Positive (144 No peak No peak 148 No peak No peak 150 Positive Positive してし

Answer 1

Question

Chapter 15, Problem 14E

(a)

Interpretation Introduction

Interpretation:

The unit for the rate of a chemical reaction should be stated.

Concept Introduction:

Rate of reaction represents the change of concentration of a reactant or a product with respect to time. It can be expressed either by reduce amount of reactant in per unit time or increase amount of product in per unit time.

(b)

Interpretation Introduction

Interpretation:

The unit for the rate constant of a zero-order reaction should be stated.

Concept Introduction:

Rate of reaction represents the change of concentration of a reactant or a product with respect to time. It can be expressed either by reduce amount of reactant in per unit time or increase amount of product in per unit time.

(c)

Interpretation Introduction

Interpretation:

The unit for the rate constant of a first-order reaction should be stated.

Concept Introduction:

Rate of reaction represents the change of concentration of a reactant or a product with respect to time. It can be expressed either by reduce amount of reactant in per unit time or increase amount of product in per unit time.

(d)

Interpretation Introduction

Interpretation:

The unit for the rate constant of a second-order reaction should be stated.

Concept Introduction:

Rate of reaction represents the change of concentration of a reactant or a product with respect to time. It can be expressed either by reduce amount of reactant in per unit time or increase amount of product in per unit time.

(e)

Interpretation Introduction

Interpretation:

The unit for the rate constant of a third-order reaction should be stated.

Concept Introduction:

Rate of reaction represents the change of concentration of a reactant or a product with respect to time. It can be expressed either by reduce amount of reactant in per unit time or increase amount of product in per unit time.

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16. The proton NMR spectral information shown in this problem is for a compound with formula CioH,N. Expansions are shown for the region from 8.7 to 7.0 ppm. The normal carbon-13 spec- tral results, including DEPT-135 and DEPT-90 results, are tabulated: 7 J Normal Carbon DEPT-135 DEPT-90 19 ppm Positive No peak 122 Positive Positive cus и 124 Positive Positive 126 Positive Positive 128 No peak No peak 4° 129 Positive Positive 130 Positive Positive (144 No peak No peak 148 No peak No peak 150 Positive Positive してし

3. Propose a synthesis for the following transformation. Do not draw an arrow-pushing mechanism below, but make sure to draw the product of each proposed step (3 points). + En CN CN

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Answer 2

Question

Chapter 15, Problem 14E

(a)

Interpretation Introduction

Interpretation:

The unit for the rate of a chemical reaction should be stated.

Concept Introduction:

Rate of reaction represents the change of concentration of a reactant or a product with respect to time. It can be expressed either by reduce amount of reactant in per unit time or increase amount of product in per unit time.

(b)

Interpretation Introduction

Interpretation:

The unit for the rate constant of a zero-order reaction should be stated.

Concept Introduction:

Rate of reaction represents the change of concentration of a reactant or a product with respect to time. It can be expressed either by reduce amount of reactant in per unit time or increase amount of product in per unit time.

(c)

Interpretation Introduction

Interpretation:

The unit for the rate constant of a first-order reaction should be stated.

Concept Introduction:

Rate of reaction represents the change of concentration of a reactant or a product with respect to time. It can be expressed either by reduce amount of reactant in per unit time or increase amount of product in per unit time.

(d)

Interpretation Introduction

Interpretation:

The unit for the rate constant of a second-order reaction should be stated.

Concept Introduction:

Rate of reaction represents the change of concentration of a reactant or a product with respect to time. It can be expressed either by reduce amount of reactant in per unit time or increase amount of product in per unit time.

(e)

Interpretation Introduction

Interpretation:

The unit for the rate constant of a third-order reaction should be stated.

Concept Introduction:

Rate of reaction represents the change of concentration of a reactant or a product with respect to time. It can be expressed either by reduce amount of reactant in per unit time or increase amount of product in per unit time.

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Answer 3

Question

Chapter 15, Problem 14E

(a)

Interpretation Introduction

Interpretation:

The unit for the rate of a chemical reaction should be stated.

Concept Introduction:

Rate of reaction represents the change of concentration of a reactant or a product with respect to time. It can be expressed either by reduce amount of reactant in per unit time or increase amount of product in per unit time.

(b)

Interpretation Introduction

Interpretation:

The unit for the rate constant of a zero-order reaction should be stated.

Concept Introduction:

Rate of reaction represents the change of concentration of a reactant or a product with respect to time. It can be expressed either by reduce amount of reactant in per unit time or increase amount of product in per unit time.

(c)

Interpretation Introduction

Interpretation:

The unit for the rate constant of a first-order reaction should be stated.

Concept Introduction:

Rate of reaction represents the change of concentration of a reactant or a product with respect to time. It can be expressed either by reduce amount of reactant in per unit time or increase amount of product in per unit time.

(d)

Interpretation Introduction

Interpretation:

The unit for the rate constant of a second-order reaction should be stated.

Concept Introduction:

Rate of reaction represents the change of concentration of a reactant or a product with respect to time. It can be expressed either by reduce amount of reactant in per unit time or increase amount of product in per unit time.

(e)

Interpretation Introduction

Interpretation:

The unit for the rate constant of a third-order reaction should be stated.

Concept Introduction:

Rate of reaction represents the change of concentration of a reactant or a product with respect to time. It can be expressed either by reduce amount of reactant in per unit time or increase amount of product in per unit time.

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Answer 4

Question

Chapter 15, Problem 14E

(a)

Interpretation Introduction

Interpretation:

The unit for the rate of a chemical reaction should be stated.

Concept Introduction:

Rate of reaction represents the change of concentration of a reactant or a product with respect to time. It can be expressed either by reduce amount of reactant in per unit time or increase amount of product in per unit time.

(b)

Interpretation Introduction

Interpretation:

The unit for the rate constant of a zero-order reaction should be stated.

Concept Introduction:

Rate of reaction represents the change of concentration of a reactant or a product with respect to time. It can be expressed either by reduce amount of reactant in per unit time or increase amount of product in per unit time.

(c)

Interpretation Introduction

Interpretation:

The unit for the rate constant of a first-order reaction should be stated.

Concept Introduction:

Rate of reaction represents the change of concentration of a reactant or a product with respect to time. It can be expressed either by reduce amount of reactant in per unit time or increase amount of product in per unit time.

(d)

Interpretation Introduction

Interpretation:

The unit for the rate constant of a second-order reaction should be stated.

Concept Introduction:

Rate of reaction represents the change of concentration of a reactant or a product with respect to time. It can be expressed either by reduce amount of reactant in per unit time or increase amount of product in per unit time.

(e)

Interpretation Introduction

Interpretation:

The unit for the rate constant of a third-order reaction should be stated.

Concept Introduction:

Rate of reaction represents the change of concentration of a reactant or a product with respect to time. It can be expressed either by reduce amount of reactant in per unit time or increase amount of product in per unit time.

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Answer 5

Chapter 15, Problem 14E

(a)

Interpretation Introduction

Interpretation:

The unit for the rate of a chemical reaction should be stated.

Concept Introduction:

Rate of reaction represents the change of concentration of a reactant or a product with respect to time. It can be expressed either by reduce amount of reactant in per unit time or increase amount of product in per unit time.

(b)

Interpretation Introduction

Interpretation:

The unit for the rate constant of a zero-order reaction should be stated.

Concept Introduction:

Rate of reaction represents the change of concentration of a reactant or a product with respect to time. It can be expressed either by reduce amount of reactant in per unit time or increase amount of product in per unit time.

(c)

Interpretation Introduction

Interpretation:

The unit for the rate constant of a first-order reaction should be stated.

Concept Introduction:

Rate of reaction represents the change of concentration of a reactant or a product with respect to time. It can be expressed either by reduce amount of reactant in per unit time or increase amount of product in per unit time.

(d)

Interpretation Introduction

Interpretation:

The unit for the rate constant of a second-order reaction should be stated.

Concept Introduction:

Rate of reaction represents the change of concentration of a reactant or a product with respect to time. It can be expressed either by reduce amount of reactant in per unit time or increase amount of product in per unit time.

(e)

Interpretation Introduction

Interpretation:

The unit for the rate constant of a third-order reaction should be stated.

Concept Introduction:

Rate of reaction represents the change of concentration of a reactant or a product with respect to time. It can be expressed either by reduce amount of reactant in per unit time or increase amount of product in per unit time.

Answer 6

Chapter 15, Problem 14E

(a)

Interpretation Introduction

Interpretation:

The unit for the rate of a chemical reaction should be stated.

Concept Introduction:

Rate of reaction represents the change of concentration of a reactant or a product with respect to time. It can be expressed either by reduce amount of reactant in per unit time or increase amount of product in per unit time.

Answer 7

Chapter 15, Problem 14E

(a)

Interpretation Introduction

Interpretation:

The unit for the rate of a chemical reaction should be stated.

Concept Introduction:

Rate of reaction represents the change of concentration of a reactant or a product with respect to time. It can be expressed either by reduce amount of reactant in per unit time or increase amount of product in per unit time.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The unit for the rate constant of a zero-order reaction should be stated.

Concept Introduction:

Rate of reaction represents the change of concentration of a reactant or a product with respect to time. It can be expressed either by reduce amount of reactant in per unit time or increase amount of product in per unit time.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The unit for the rate constant of a zero-order reaction should be stated.

Concept Introduction:

Rate of reaction represents the change of concentration of a reactant or a product with respect to time. It can be expressed either by reduce amount of reactant in per unit time or increase amount of product in per unit time.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The unit for the rate constant of a first-order reaction should be stated.

Concept Introduction:

Rate of reaction represents the change of concentration of a reactant or a product with respect to time. It can be expressed either by reduce amount of reactant in per unit time or increase amount of product in per unit time.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The unit for the rate constant of a first-order reaction should be stated.

Concept Introduction:

Rate of reaction represents the change of concentration of a reactant or a product with respect to time. It can be expressed either by reduce amount of reactant in per unit time or increase amount of product in per unit time.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The unit for the rate constant of a second-order reaction should be stated.

Concept Introduction:

Rate of reaction represents the change of concentration of a reactant or a product with respect to time. It can be expressed either by reduce amount of reactant in per unit time or increase amount of product in per unit time.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The unit for the rate constant of a second-order reaction should be stated.

Concept Introduction:

Rate of reaction represents the change of concentration of a reactant or a product with respect to time. It can be expressed either by reduce amount of reactant in per unit time or increase amount of product in per unit time.

Answer 14

(e)

Interpretation Introduction

Interpretation:

The unit for the rate constant of a third-order reaction should be stated.

Concept Introduction:

Rate of reaction represents the change of concentration of a reactant or a product with respect to time. It can be expressed either by reduce amount of reactant in per unit time or increase amount of product in per unit time.

Answer 15

(e)

Interpretation Introduction

Interpretation:

The unit for the rate constant of a third-order reaction should be stated.

Concept Introduction:

Rate of reaction represents the change of concentration of a reactant or a product with respect to time. It can be expressed either by reduce amount of reactant in per unit time or increase amount of product in per unit time.

Answer 16

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Answer 27

Ch. 15 - Prob. 1DQ Ch. 15 - Prob. 2DQ Ch. 15 - a graph of [A] versus time for zero-, first-, and...Ch. 15 - Prob. 4DQ Ch. 15 - Prob. 5DQ Ch. 15 - Prob. 6DQ Ch. 15 - Prob. 7DQ Ch. 15 - Prob. 8DQ Ch. 15 - Provide a conceptual rationale for the differences...Ch. 15 - Prob. 10E

Solution Summary: The author explains that the unit for the rate of a chemical reaction should be stated.

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