The term stability in terms of kinetic and thermodynamic perspective should be explained with the example that shows the differences between them. Concept Introduction: Rate of reaction represents the change of concentration of a reactant or a product with respect to time. It can be expressed either by the reduce amount of reactant in per unit time or increase the amount of product in per unit time.

Question

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Answer 1

Question

Chapter 15, Problem 1DQ

Interpretation Introduction

Interpretation:

The term stability in terms of kinetic and thermodynamic perspective should be explained with the example that shows the differences between them.

Concept Introduction:

Rate of reaction represents the change of concentration of a reactant or a product with respect to time. It can be expressed either by the reduce amount of reactant in per unit time or increase the amount of product in per unit time.

Expert Solution & Answer

Answer to Problem 1DQ

Kinetically stability depends upon the rate of the reaction whereas thermodynamically stability depends on whether the reaction is favorable or not. The conversion of diamond into graphite is a kinetically stable and thermodynamic unstable.

Explanation of Solution

Kinetic stability of the reaction basically deals with the rate of the reaction. It occurs when reactant reacts very slowly. There is an inverse relationship between rate of reaction and kinetic stability. In other words, when the reaction is slow then it has greater kinetic stability.

Thermodynamic stability of the reaction deals on the spontaneity of the reaction. In other words, it depends on whether the reaction is spontaneous or not and also the change in free energy. It is independent from the pathway followed by the reactants and the products.

Consider an example of conversion of diamond into graphite. It has negative value of ΔG that means it is a thermodynamically unstable and will occur spontaneously. However, the reaction will take very long time that means it is kinetically stable. Therefore, it is kinetically stable not thermodynamic.

Conclusion

Kinetically stability depends upon the rate of the reaction whereas thermodynamically stability depends on whether the reaction is favorable or not. The conversion of diamond into graphite is a kinetically stable and thermodynamic unstable.

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Answer 2

Question

Chapter 15, Problem 1DQ

Interpretation Introduction

Interpretation:

The term stability in terms of kinetic and thermodynamic perspective should be explained with the example that shows the differences between them.

Concept Introduction:

Rate of reaction represents the change of concentration of a reactant or a product with respect to time. It can be expressed either by the reduce amount of reactant in per unit time or increase the amount of product in per unit time.

Expert Solution & Answer

Answer to Problem 1DQ

Kinetically stability depends upon the rate of the reaction whereas thermodynamically stability depends on whether the reaction is favorable or not. The conversion of diamond into graphite is a kinetically stable and thermodynamic unstable.

Explanation of Solution

Kinetic stability of the reaction basically deals with the rate of the reaction. It occurs when reactant reacts very slowly. There is an inverse relationship between rate of reaction and kinetic stability. In other words, when the reaction is slow then it has greater kinetic stability.

Thermodynamic stability of the reaction deals on the spontaneity of the reaction. In other words, it depends on whether the reaction is spontaneous or not and also the change in free energy. It is independent from the pathway followed by the reactants and the products.

Consider an example of conversion of diamond into graphite. It has negative value of ΔG that means it is a thermodynamically unstable and will occur spontaneously. However, the reaction will take very long time that means it is kinetically stable. Therefore, it is kinetically stable not thermodynamic.

Conclusion

Kinetically stability depends upon the rate of the reaction whereas thermodynamically stability depends on whether the reaction is favorable or not. The conversion of diamond into graphite is a kinetically stable and thermodynamic unstable.

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Answer 3

Question

Chapter 15, Problem 1DQ

Interpretation Introduction

Interpretation:

The term stability in terms of kinetic and thermodynamic perspective should be explained with the example that shows the differences between them.

Concept Introduction:

Rate of reaction represents the change of concentration of a reactant or a product with respect to time. It can be expressed either by the reduce amount of reactant in per unit time or increase the amount of product in per unit time.

Expert Solution & Answer

Answer to Problem 1DQ

Kinetically stability depends upon the rate of the reaction whereas thermodynamically stability depends on whether the reaction is favorable or not. The conversion of diamond into graphite is a kinetically stable and thermodynamic unstable.

Explanation of Solution

Kinetic stability of the reaction basically deals with the rate of the reaction. It occurs when reactant reacts very slowly. There is an inverse relationship between rate of reaction and kinetic stability. In other words, when the reaction is slow then it has greater kinetic stability.

Thermodynamic stability of the reaction deals on the spontaneity of the reaction. In other words, it depends on whether the reaction is spontaneous or not and also the change in free energy. It is independent from the pathway followed by the reactants and the products.

Consider an example of conversion of diamond into graphite. It has negative value of ΔG that means it is a thermodynamically unstable and will occur spontaneously. However, the reaction will take very long time that means it is kinetically stable. Therefore, it is kinetically stable not thermodynamic.

Conclusion

Kinetically stability depends upon the rate of the reaction whereas thermodynamically stability depends on whether the reaction is favorable or not. The conversion of diamond into graphite is a kinetically stable and thermodynamic unstable.

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Answer 4

Question

Chapter 15, Problem 1DQ

Interpretation Introduction

Interpretation:

The term stability in terms of kinetic and thermodynamic perspective should be explained with the example that shows the differences between them.

Concept Introduction:

Rate of reaction represents the change of concentration of a reactant or a product with respect to time. It can be expressed either by the reduce amount of reactant in per unit time or increase the amount of product in per unit time.

Expert Solution & Answer

Answer to Problem 1DQ

Kinetically stability depends upon the rate of the reaction whereas thermodynamically stability depends on whether the reaction is favorable or not. The conversion of diamond into graphite is a kinetically stable and thermodynamic unstable.

Explanation of Solution

Kinetic stability of the reaction basically deals with the rate of the reaction. It occurs when reactant reacts very slowly. There is an inverse relationship between rate of reaction and kinetic stability. In other words, when the reaction is slow then it has greater kinetic stability.

Thermodynamic stability of the reaction deals on the spontaneity of the reaction. In other words, it depends on whether the reaction is spontaneous or not and also the change in free energy. It is independent from the pathway followed by the reactants and the products.

Consider an example of conversion of diamond into graphite. It has negative value of ΔG that means it is a thermodynamically unstable and will occur spontaneously. However, the reaction will take very long time that means it is kinetically stable. Therefore, it is kinetically stable not thermodynamic.

Conclusion

Kinetically stability depends upon the rate of the reaction whereas thermodynamically stability depends on whether the reaction is favorable or not. The conversion of diamond into graphite is a kinetically stable and thermodynamic unstable.

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Answer 5

Chapter 15, Problem 1DQ

Interpretation Introduction

Interpretation:

The term stability in terms of kinetic and thermodynamic perspective should be explained with the example that shows the differences between them.

Concept Introduction:

Rate of reaction represents the change of concentration of a reactant or a product with respect to time. It can be expressed either by the reduce amount of reactant in per unit time or increase the amount of product in per unit time.

Expert Solution & Answer

Answer to Problem 1DQ

Kinetically stability depends upon the rate of the reaction whereas thermodynamically stability depends on whether the reaction is favorable or not. The conversion of diamond into graphite is a kinetically stable and thermodynamic unstable.

Explanation of Solution

Kinetic stability of the reaction basically deals with the rate of the reaction. It occurs when reactant reacts very slowly. There is an inverse relationship between rate of reaction and kinetic stability. In other words, when the reaction is slow then it has greater kinetic stability.

Thermodynamic stability of the reaction deals on the spontaneity of the reaction. In other words, it depends on whether the reaction is spontaneous or not and also the change in free energy. It is independent from the pathway followed by the reactants and the products.

Consider an example of conversion of diamond into graphite. It has negative value of ΔG that means it is a thermodynamically unstable and will occur spontaneously. However, the reaction will take very long time that means it is kinetically stable. Therefore, it is kinetically stable not thermodynamic.

Conclusion

Kinetically stability depends upon the rate of the reaction whereas thermodynamically stability depends on whether the reaction is favorable or not. The conversion of diamond into graphite is a kinetically stable and thermodynamic unstable.

Answer 6

Chapter 15, Problem 1DQ

Interpretation Introduction

Interpretation:

The term stability in terms of kinetic and thermodynamic perspective should be explained with the example that shows the differences between them.

Concept Introduction:

Rate of reaction represents the change of concentration of a reactant or a product with respect to time. It can be expressed either by the reduce amount of reactant in per unit time or increase the amount of product in per unit time.

Expert Solution & Answer

Answer to Problem 1DQ

Kinetically stability depends upon the rate of the reaction whereas thermodynamically stability depends on whether the reaction is favorable or not. The conversion of diamond into graphite is a kinetically stable and thermodynamic unstable.

Explanation of Solution

Kinetic stability of the reaction basically deals with the rate of the reaction. It occurs when reactant reacts very slowly. There is an inverse relationship between rate of reaction and kinetic stability. In other words, when the reaction is slow then it has greater kinetic stability.

Thermodynamic stability of the reaction deals on the spontaneity of the reaction. In other words, it depends on whether the reaction is spontaneous or not and also the change in free energy. It is independent from the pathway followed by the reactants and the products.

Consider an example of conversion of diamond into graphite. It has negative value of ΔG that means it is a thermodynamically unstable and will occur spontaneously. However, the reaction will take very long time that means it is kinetically stable. Therefore, it is kinetically stable not thermodynamic.

Conclusion

Kinetically stability depends upon the rate of the reaction whereas thermodynamically stability depends on whether the reaction is favorable or not. The conversion of diamond into graphite is a kinetically stable and thermodynamic unstable.

Answer 7

Chapter 15, Problem 1DQ

Interpretation Introduction

Interpretation:

The term stability in terms of kinetic and thermodynamic perspective should be explained with the example that shows the differences between them.

Concept Introduction:

Rate of reaction represents the change of concentration of a reactant or a product with respect to time. It can be expressed either by the reduce amount of reactant in per unit time or increase the amount of product in per unit time.

Answer 8

Expert Solution & Answer

Answer to Problem 1DQ

Kinetically stability depends upon the rate of the reaction whereas thermodynamically stability depends on whether the reaction is favorable or not. The conversion of diamond into graphite is a kinetically stable and thermodynamic unstable.

Answer 9

Expert Solution & Answer

Answer 10

Expert Solution & Answer

Answer 11

Explanation of Solution

Kinetic stability of the reaction basically deals with the rate of the reaction. It occurs when reactant reacts very slowly. There is an inverse relationship between rate of reaction and kinetic stability. In other words, when the reaction is slow then it has greater kinetic stability.

Thermodynamic stability of the reaction deals on the spontaneity of the reaction. In other words, it depends on whether the reaction is spontaneous or not and also the change in free energy. It is independent from the pathway followed by the reactants and the products.

Consider an example of conversion of diamond into graphite. It has negative value of ΔG that means it is a thermodynamically unstable and will occur spontaneously. However, the reaction will take very long time that means it is kinetically stable. Therefore, it is kinetically stable not thermodynamic.

Answer 12

Conclusion

Kinetically stability depends upon the rate of the reaction whereas thermodynamically stability depends on whether the reaction is favorable or not. The conversion of diamond into graphite is a kinetically stable and thermodynamic unstable.

Answer 13

Ch. 15 - Prob. 1DQ Ch. 15 - Prob. 2DQ Ch. 15 - a graph of [A] versus time for zero-, first-, and...Ch. 15 - Prob. 4DQ Ch. 15 - Prob. 5DQ Ch. 15 - Prob. 6DQ Ch. 15 - Prob. 7DQ Ch. 15 - Prob. 8DQ Ch. 15 - Provide a conceptual rationale for the differences...Ch. 15 - Prob. 10E

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