GENERAL,ORGANIC, & BIOLOGICAL CHEM-ACCES
GENERAL,ORGANIC, & BIOLOGICAL CHEM-ACCES
4th Edition
ISBN: 9781265982959
Author: SMITH
Publisher: MCG
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Chapter 14.5, Problem 14.6P
Interpretation Introduction

(a)

Interpretation:

The alkene formed when the given alcohol is treated with H2SO4 should be determined. The major product should be predicted using Zaitsev rule.

  GENERAL,ORGANIC, & BIOLOGICAL CHEM-ACCES, Chapter 14.5, Problem 14.6P , additional homework tip  1

Concept Introduction:

When H2O is lost from a material it is called dehydration. When an alcohol is treated with a strong acid such as H2SO4, a water molecule is lost by breaking two adjacent bonds C-OH and C-H and forming a new double bond, producing an alkene. This is an elimination reaction.

  GENERAL,ORGANIC, & BIOLOGICAL CHEM-ACCES, Chapter 14.5, Problem 14.6P , additional homework tip  2

In this reaction more than one type of alkene may produce. But one of them is the major product.

According to Zaitsev rule, the major product alkene formed by elimination, is that which possess more alkyl groups bonded to it

Interpretation Introduction

(b)

Interpretation:

The alkene formed when the given alcohol is treated with H2SO4 should be determined. The major product should be predicted using Zaitsev rule.

  GENERAL,ORGANIC, & BIOLOGICAL CHEM-ACCES, Chapter 14.5, Problem 14.6P , additional homework tip  3

Concept Introduction:

When H2O is lost from a material it is called dehydration. When an alcohol is treated with a strong acid such as H2SO4, a water molecule is lost by breaking two adjacent bonds C-OH and C-H and forming a new double bond, producing an alkene. This is an elimination reaction.

  GENERAL,ORGANIC, & BIOLOGICAL CHEM-ACCES, Chapter 14.5, Problem 14.6P , additional homework tip  4

In this reaction more than one type of alkene may produce. But one of them is the major product.

According to Zaitsev rule, the major product alkene formed by elimination, is that which possess more alkyl groups bonded to it

Interpretation Introduction

(c)

Interpretation:

The alkene formed when the given alcohol is treated with H2SO4 should be determined. The major product should be predicted using Zaitsev rule.

  GENERAL,ORGANIC, & BIOLOGICAL CHEM-ACCES, Chapter 14.5, Problem 14.6P , additional homework tip  5

Concept Introduction:

When H2O is lost from a material it is called dehydration. When an alcohol is treated with a strong acid such as H2SO4, a water molecule is lost by breaking two adjacent bonds C-OH and C-H and forming a new double bond, producing an alkene. This is an elimination reaction.

  GENERAL,ORGANIC, & BIOLOGICAL CHEM-ACCES, Chapter 14.5, Problem 14.6P , additional homework tip  6

In this reaction more than one type of alkene may produce. But one of them is the major product.

According to Zaitsev rule, the major product alkene formed by elimination, is that which possess more alkyl groups bonded to it

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Please answer the question and provide a detailed drawing of the structure. If there will not be a new C – C bond, then the box under the drawing area will be checked.  Will the following reaction make a molecule with a new C – C bond as its major product:  Draw the major organic product or products, if the reaction will work. Be sure you use wedge and dash bonds if necessary, for example to distinguish between major products with different stereochemistry.
Please do not use AI.  AI cannot "see" the molecules properly, and it therefore gives the wrong answer while giving incorrect descriptions of the visual images we're looking at.  All of these compounds would be produced (I think).  In my book, I don't see any rules about yield in this case, like explaining that one product would be present in less yield for this reason or that reason.  Please explain why some of these produce less yield than others.

Chapter 14 Solutions

GENERAL,ORGANIC, & BIOLOGICAL CHEM-ACCES

Ch. 14.5 - Prob. 14.4PPCh. 14.6 - Prob. 14.8PCh. 14.7 - Prob. 14.9PCh. 14.7 - Prob. 14.5PPCh. 14.7 - Prob. 14.10PCh. 14.7 - Name each ether. CH3OCH2CH2CH2CH3Ch. 14.7 - Prob. 14.11PCh. 14.8 - (a) Translate the hall and stick model of...Ch. 14.8 - Prob. 14.13PCh. 14.9 - Prob. 14.14PCh. 14.9 - Prob. 14.15PCh. 14.9 - Prob. 14.16PCh. 14.9 - Prob. 14.17PCh. 14.9 - Prob. 14.18PCh. 14.9 - Prob. 14.19PCh. 14.9 - Prob. 14.20PCh. 14.10 - Give the IUPAC name for each thiol.Ch. 14.10 - Prob. 14.21PCh. 14.10 - Prob. 14.22PCh. 14 - Classify each alcohol as 1°, 2°, or 3o a....Ch. 14 - Prob. 24PCh. 14 - Prob. 25PCh. 14 - Classify each halide hi A as 1°, 2°, or 3°. A is a...Ch. 14 - Prob. 27PCh. 14 - Draw the structure of a molecule that fits each...Ch. 14 - Draw the structure of the six constitutional...Ch. 14 - Draw the structure of the four constitutional...Ch. 14 - Draw the structure of l-propanethiol, a compound...Ch. 14 - Prob. 32PCh. 14 - Prob. 33PCh. 14 - Prob. 34PCh. 14 - Prob. 35PCh. 14 - Answer each question about alcohol B. Draw a...Ch. 14 - Prob. 37PCh. 14 - Give the IUAPC name for each alcohol.Ch. 14 - Prob. 39PCh. 14 - Prob. 40PCh. 14 - Prob. 41PCh. 14 - Prob. 42PCh. 14 - Draw the structures and give the IUPAC names for...Ch. 14 - Prob. 44PCh. 14 - Prob. 45PCh. 14 - Prob. 46PCh. 14 - Give the structure corresponding to each IUPAC...Ch. 14 - Give the structure corresponding to each IUPAC...Ch. 14 - Which compound in each pair has the higher boiling...Ch. 14 - Rank the compounds in order of increasing melting...Ch. 14 - Rank the following compounds in order of...Ch. 14 - Rank the following compounds in order of...Ch. 14 - Prob. 53PCh. 14 - Prob. 54PCh. 14 - Prob. 55PCh. 14 - Prob. 56PCh. 14 - Prob. 57PCh. 14 - Prob. 58PCh. 14 - Prob. 59PCh. 14 - Prob. 60PCh. 14 - Prob. 61PCh. 14 - Prob. 62PCh. 14 - Prob. 63PCh. 14 - Prob. 64PCh. 14 - Prob. 65PCh. 14 - Prob. 66PCh. 14 - Prob. 67PCh. 14 - Prob. 68PCh. 14 - Prob. 69PCh. 14 - Prob. 70PCh. 14 - Prob. 71PCh. 14 - Prob. 72PCh. 14 - Prob. 73PCh. 14 - Prob. 74PCh. 14 - Prob. 75PCh. 14 - Prob. 76PCh. 14 - Prob. 77PCh. 14 - Prob. 78PCh. 14 - Prob. 79PCh. 14 - Prob. 80PCh. 14 - With reference to the halogenated organic...Ch. 14 - Prob. 82PCh. 14 - Prob. 83PCh. 14 - Prob. 84PCh. 14 - Write out the chemical reaction that occurs when a...Ch. 14 - Prob. 86PCh. 14 - Prob. 87PCh. 14 - Lactic acid [CH3CH(OH)CO2H] gives sour milk its...Ch. 14 - Prob. 89PCh. 14 - Prob. 90PCh. 14 - Prob. 91PCh. 14 - Prob. 92PCh. 14 - Prob. 93PCh. 14 - Answer the following questions about alcohol B....Ch. 14 - Prob. 95CPCh. 14 - Dehydration of alcohol C forms two products of...
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