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OWLv2 for Moore/Stanitski's Chemistry: The Molecular Science, 5th Edition, [Instant Access], 1 term (6 months)
5th Edition
ISBN: 9781285460420
Author: John W. Moore; Conrad L. Stanitski
Publisher: Cengage Learning US
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Chapter 14, Problem 23QRT
Interpretation Introduction
Interpretation:
Balanced chemical equation has to be written to show aqueous solution of pyruvic acid is acidic.
Concept Introduction:
Balanced chemical equation is the one in which the number of atoms of same kind are equal on both sides of the equation.
Water acts as a base and also as an acid. In presence of base, water acts as an acid resulting in formation of a basic solution and vice-versa.
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You have now performed a liquid-liquid extraction protocol in Experiment 4. In doing so, you
manipulated and exploited the acid-base chemistry of one or more of the compounds in your
mixture to facilitate their separation into different phases. The key to understanding how liquid-
liquid extractions work is by knowing which layer a compound is in, and in what protonation state.
The following liquid-liquid extraction is different from the one you performed in Experiment
4, but it uses the same type of logic. Your task is to show how to separate apart Compound
A and Compound B.
. Complete the following flowchart of a liquid-liquid extraction. Handwritten work is
encouraged.
•
Draw by hand (neatly) only the appropriate organic compound(s) in the boxes.
.
Specify the reagent(s)/chemicals (name is fine) and concentration as required in Boxes 4
and 5.
•
Box 7a requires the solvent (name is fine).
•
Box 7b requires one inorganic compound.
• You can neatly complete this assignment by hand and…
b) Elucidate compound D w) mt at 170 nd shows c-1 stretch at 550cm;'
The compound has the ff electronic transitions: 0%o* and no a*
1H NMR Spectrum
(CDCl3, 400 MHz)
3.5
3.0
2.5
2.0
1.5
1.0
0.5 ppm
13C{H} NMR Spectrum
(CDCl3, 100 MHz)
Solvent
80
70
60
50
40
30
20
10
0 ppm
ppm
¹H-13C me-HSQC Spectrum
ppm
(CDCl3, 400 MHz)
5
¹H-¹H COSY Spectrum
(CDCl3, 400 MHz)
0.5
10
3.5
3.0
2.5
2.0
1.5 1.0
10
15
20
20
25
30
30
-35
-1.0
1.5
-2.0
-2.5
3.0
-3.5
0.5
ppm
3.5
3.0
2.5
2.0
1.5
1.0
0.5
ppm
Show work with explanation. don't give Ai generated solution
Chapter 14 Solutions
OWLv2 for Moore/Stanitski's Chemistry: The Molecular Science, 5th Edition, [Instant Access], 1 term (6 months)
Ch. 14.1 - Identify each molecule or ion as a Brnsted-Lowry...Ch. 14.1 - Using Le Chatelier’s Principle
Use Le Chatelier’s...Ch. 14.1 - Prob. 14.3ECh. 14.1 - Complete the table.
Ch. 14.1 - Prob. 14.4ECh. 14.1 - Prob. 14.5ECh. 14.2 - Prob. 14.6CECh. 14.2 - Prob. 14.7ECh. 14.3 - Prob. 14.2PSPCh. 14.3 - Prob. 14.3PSP
Ch. 14.4 - Calculate the pH of a 0.040-M NaOH solution.
Ch. 14.4 - In a hospital laboratory the pH of a bile sample...Ch. 14.4 - Prob. 14.8CECh. 14.4 - Prob. 14.9ECh. 14.4 - Prob. 14.10ECh. 14.5 - Write the ionization equation and ionization...Ch. 14.5 - Write the ionization equation and the Kb...Ch. 14.5 - Prob. 14.11CECh. 14.5 - Prob. 14.12CECh. 14.5 - Prob. 14.13ECh. 14.6 - Prob. 14.14CECh. 14.6 - Prob. 14.15CECh. 14.6 - Prob. 14.16CECh. 14.6 - Prob. 14.17CECh. 14.6 - Prob. 14.18CECh. 14.7 - Lactic acid is a monoprotic acid that occurs...Ch. 14.7 - Prob. 14.9PSPCh. 14.7 - Prob. 14.19ECh. 14.7 - Prob. 14.10PSPCh. 14.7 - Prob. 14.20ECh. 14.8 - Prob. 14.11PSPCh. 14.8 - Prob. 14.21CECh. 14.8 - Prob. 14.12PSPCh. 14.8 - Prob. 14.22ECh. 14.8 - Prob. 14.23CECh. 14.8 - Prob. 14.24CECh. 14.9 - Predict whether each of these is a Lewis acid or a...Ch. 14.9 - Prob. 14.26ECh. 14.9 - Prob. 14.27ECh. 14.10 - Prob. 14.28ECh. 14.10 - Prob. 14.13PSPCh. 14.10 - Prob. 14.29ECh. 14.10 -
Calculate the pH of 5.2-M aqueous sodium...Ch. 14 - Lactic acid, CH3CH(OH)COOH, is a weak monoprotic...Ch. 14 - Define a Brnsted-Lowry acid and a Brnsted-Lowry...Ch. 14 - Prob. 2QRTCh. 14 - Prob. 3QRTCh. 14 - Prob. 4QRTCh. 14 - Prob. 5QRTCh. 14 - Prob. 6QRTCh. 14 - Prob. 7QRTCh. 14 - Prob. 8QRTCh. 14 - Write a chemical equation to describe the proton...Ch. 14 - Write a chemical equation to describe the proton...Ch. 14 - Prob. 11QRTCh. 14 - Prob. 12QRTCh. 14 - Prob. 13QRTCh. 14 - Prob. 14QRTCh. 14 - Prob. 15QRTCh. 14 - Prob. 16QRTCh. 14 - Prob. 17QRTCh. 14 - Prob. 18QRTCh. 14 - Prob. 19QRTCh. 14 - Prob. 20QRTCh. 14 - Prob. 21QRTCh. 14 - Prob. 22QRTCh. 14 - Prob. 23QRTCh. 14 - Formic acid, HCOOH, is found in ants. Write a...Ch. 14 - Milk of magnesia, Mg(OH)2, has a pH of 10.5....Ch. 14 - A sample of coffee has a pH of 4.3. Calculate the...Ch. 14 - Calculate the pH of a solution that is 0.025-M in...Ch. 14 - Calculate the pH of a 0.0013-M solution of HNO3....Ch. 14 - Prob. 29QRTCh. 14 - Prob. 30QRTCh. 14 - A 1000.-mL solution of hydrochloric acid has a pH...Ch. 14 - Prob. 32QRTCh. 14 - Prob. 33QRTCh. 14 - Prob. 34QRTCh. 14 - Figure 14.3 shows the pH of some common solutions....Ch. 14 - Figure 14.3 shows the pH of some common solutions....Ch. 14 - The measured pH of a sample of seawater is 8.30....Ch. 14 - Prob. 38QRTCh. 14 - Valine is an amino acid with this Lewis structure:...Ch. 14 - Leucine is an amino acid with this Lewis...Ch. 14 - Prob. 41QRTCh. 14 - Prob. 42QRTCh. 14 - Prob. 43QRTCh. 14 - Prob. 44QRTCh. 14 - Prob. 45QRTCh. 14 - Prob. 46QRTCh. 14 - Prob. 47QRTCh. 14 - Prob. 48QRTCh. 14 - Prob. 49QRTCh. 14 - Prob. 50QRTCh. 14 - Prob. 51QRTCh. 14 - Prob. 52QRTCh. 14 - Prob. 53QRTCh. 14 - Prob. 54QRTCh. 14 -
A 0.015-M solution of cyanic acid has a pH of...Ch. 14 - Prob. 56QRTCh. 14 -
The pH of a 0.10-M solution of propanoic acid,...Ch. 14 - Prob. 58QRTCh. 14 - Prob. 59QRTCh. 14 - Prob. 60QRTCh. 14 - Prob. 61QRTCh. 14 - Amantadine, C10H15NH2, is a weak base used in the...Ch. 14 - Prob. 63QRTCh. 14 -
Lactic acid, C3H6O3, occurs in sour milk as a...Ch. 14 - Prob. 65QRTCh. 14 - Complete each of these reactions by filling in the...Ch. 14 - Complete each of these reactions by filling in the...Ch. 14 - Predict which of these acid-base reactions are...Ch. 14 - Predict which of these acid-base reactions are...Ch. 14 - Prob. 70QRTCh. 14 - Prob. 71QRTCh. 14 - Prob. 72QRTCh. 14 - Prob. 73QRTCh. 14 - Prob. 74QRTCh. 14 - Prob. 75QRTCh. 14 - Prob. 76QRTCh. 14 - Prob. 77QRTCh. 14 - Prob. 78QRTCh. 14 - Prob. 79QRTCh. 14 - Prob. 80QRTCh. 14 - Prob. 81QRTCh. 14 - Trimethylamine, (CH3)3N, reacts readily with...Ch. 14 - Prob. 83QRTCh. 14 - Prob. 84QRTCh. 14 - Prob. 85QRTCh. 14 - Prob. 86QRTCh. 14 - Common soap is made by reacting sodium carbonate...Ch. 14 - Prob. 88QRTCh. 14 - Prob. 89QRTCh. 14 - Prob. 90QRTCh. 14 - Prob. 91QRTCh. 14 - Prob. 92QRTCh. 14 - Prob. 93QRTCh. 14 -
Several acids and their respective equilibrium...Ch. 14 - Prob. 95QRTCh. 14 - Prob. 96QRTCh. 14 - Does the pH of the solution increase, decrease, or...Ch. 14 - Does the pH of the solution increase, decrease, or...Ch. 14 - Prob. 99QRTCh. 14 - Prob. 100QRTCh. 14 - Prob. 101QRTCh. 14 - Prob. 102QRTCh. 14 - Prob. 103QRTCh. 14 - Prob. 104QRTCh. 14 - Prob. 105QRTCh. 14 - Prob. 106QRTCh. 14 - When all the water is evaporated from a sodium...Ch. 14 - Prob. 108QRTCh. 14 - Prob. 109QRTCh. 14 - Prob. 110QRTCh. 14 - Prob. 111QRTCh. 14 - Prob. 112QRTCh. 14 - Prob. 113QRTCh. 14 - Prob. 114QRTCh. 14 - Prob. 115QRTCh. 14 - Prob. 116QRTCh. 14 - Home gardeners spread aluminum sulfate powder...Ch. 14 - Prob. 118QRTCh. 14 - Prob. 119QRTCh. 14 - Prob. 120QRTCh. 14 - Prob. 121QRTCh. 14 - Prob. 122QRTCh. 14 - Prob. 123QRTCh. 14 - Prob. 124QRTCh. 14 - Prob. 125QRTCh. 14 - A chilled carbonated beverage is opened and warmed...Ch. 14 - Prob. 127QRTCh. 14 -
Explain why BrNH2 is a weaker base than ammonia,...Ch. 14 - Prob. 129QRTCh. 14 - Prob. 130QRTCh. 14 - At 25 C, a 0.10% aqueous solution of adipic acid,...Ch. 14 - Prob. 132QRTCh. 14 - Prob. 133QRTCh. 14 - Prob. 134QRTCh. 14 - Prob. 135QRTCh. 14 - Prob. 14.ACPCh. 14 - Develop a set of rules by which you could predict...
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- Redraw the flowchartarrow_forwardredraw the flowchart with boxes and molecules written in themarrow_forwardPart I. a) Elucidate the structure of compound A using the following information. • mass spectrum: m+ = 102, m/2=57 312=29 • IR spectrum: 1002.5 % TRANSMITTANCE Ngg 50 40 30 20 90 80 70 60 MICRONS 5 8 9 10 12 13 14 15 16 19 1740 cm M 10 0 4000 3600 3200 2800 2400 2000 1800 1600 13 • CNMR 'H -NMR Peak 8 ppm (H) Integration multiplicity a 1.5 (3H) triplet b 1.3 1.5 (3H) triplet C 2.3 1 (2H) quartet d 4.1 1 (2H) quartet & ppm (c) 10 15 28 60 177 (C=0) b) Elucidate the structure of compound B using the following information 13C/DEPT NMR 150.9 MHz IIL 1400 WAVENUMBERS (CM-1) DEPT-90 DEPT-135 85 80 75 70 65 60 55 50 45 40 35 30 25 20 ppm 1200 1000 800 600 400arrow_forward
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