Chemistry For Today: General, Organic, And Biochemistry, Loose-leaf Version
9th Edition
ISBN: 9781305968707
Author: Spencer L. Seager
Publisher: Brooks Cole
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Chapter 14, Problem 14.55E
The addition of water to aldehydes and ketones occurs rapidly, although it is not thermodynamically favored. What would be the product for the reaction above? Hint: Think of the self-ionization of water and the polarity of the carbonyl group.
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Draw an ester with the formula C3H6O2
AND
Draw the structures for a specific aldehyde and a specific ketone that have the formula C3H6O
Which is true?
A primary alcohol can undergo single oxidation to a give a carboxylic acid.
A primary alcohol can undergo double oxidation to a give a carboxylic acid.
Carboxylic acids boil at considerably higher temperatures than do alcohols or
aldehydes of similar molecular weights. This is because they:
form stable cyclic hydrogen-bonded dimers
have more oxygens
O are more acidic
have more carbon atoms
Chapter 14 Solutions
Chemistry For Today: General, Organic, And Biochemistry, Loose-leaf Version
Ch. 14 - Prob. 14.1ECh. 14 - Prob. 14.2ECh. 14 - Identify each of the following compounds as an...Ch. 14 - Identify each of the following compounds as an...Ch. 14 - Prob. 14.5ECh. 14 - Prob. 14.6ECh. 14 - Prob. 14.7ECh. 14 - Prob. 14.8ECh. 14 - Draw structural formulas and give IUPAC names for...Ch. 14 - Draw structural formulas and give IUPAC names for...
Ch. 14 - Each of the following names is wrong. Give the...Ch. 14 - Each of the following names is wrong. Give the...Ch. 14 - Prob. 14.13ECh. 14 - Prob. 14.14ECh. 14 - Prob. 14.15ECh. 14 - Explain why propane boils at 42C, whereas ethanal,...Ch. 14 - Use a dotted line to show hydrogen bonding between...Ch. 14 - Use a dotted line to show hydrogen bonding between...Ch. 14 - Prob. 14.19ECh. 14 - Prob. 14.20ECh. 14 - Prob. 14.21ECh. 14 - Prob. 14.22ECh. 14 - Prob. 14.23ECh. 14 - Prob. 14.24ECh. 14 - Label each of the following as acetals, ketals, or...Ch. 14 - Label each of the following as acetals, ketals, or...Ch. 14 - Label each of the following structures as a cyclic...Ch. 14 - Label each of the following structures as a...Ch. 14 - What two functional groups react to form the...Ch. 14 - Hemiacetals are sometimes referred to as potential...Ch. 14 - Complete the following statements: a. Oxidation of...Ch. 14 - Prob. 14.32ECh. 14 - Prob. 14.33ECh. 14 - Prob. 14.34ECh. 14 - Prob. 14.35ECh. 14 - Not all aldehyde give a positve Bendicts test....Ch. 14 - A stockroom assistant prepares three bottles, each...Ch. 14 - Glucose, the sugar present within the blood, gives...Ch. 14 - Fructose, present with glucose in honey, reacts...Ch. 14 - Prob. 14.40ECh. 14 - Prob. 14.41ECh. 14 - Complete the following equations. If no reaction...Ch. 14 - Complete the following equations. If no reaction...Ch. 14 - Describe the products that result when hydrogen...Ch. 14 - Prob. 14.45ECh. 14 - Draw structural formulas for the products of the...Ch. 14 - The following compounds are cyclic acetals or...Ch. 14 - The following compounds are cyclic acetals or...Ch. 14 - Write equations to show how the following...Ch. 14 - Prob. 14.50ECh. 14 - Identify the most important aldehyde and ketone...Ch. 14 - Using Table 14.3, name an aldehyde or ketone used...Ch. 14 - Prob. 14.53ECh. 14 - CH3COH(O)CH3COOHacetaldehydeaceticacid You need to...Ch. 14 - The addition of water to aldehydes and ketones...Ch. 14 - Prob. 14.56ECh. 14 - Formaldehyde levels above 0.10mg/1000L of ambient...Ch. 14 - In the IUPAC name for the following ketone, it is...Ch. 14 - Why can formaldehyde (CH2O) be prepared in the...Ch. 14 - Other addition reactions of aldehydes occur....Ch. 14 - Prob. 14.61ECh. 14 - Prob. 14.62ECh. 14 - Vanilla flavoring is either extracted from a...Ch. 14 - Prob. 14.64ECh. 14 - The use of acetone in laboratory experiments must...Ch. 14 - Prob. 14.66ECh. 14 - Prob. 14.67ECh. 14 - Which of the following would be classified as a...
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- a) Aldehydes are easily converted (oxidised) to form carboxylic acids.Ketones, on the other hand, do not oxidise to form carboxylic acids.Suggest a reason why this is so.arrow_forwardAlkyl sulfonates undergo the same type of substitution reactions as alkyl halides and can also be prepared from alcohols. What advantage does the preparation of an alkyl sulfonate from an alcohol have over the preparation of an alkyl halide from an alcohol?arrow_forwardExplain about carbonyl compounds with a detailed look at aldehydes and ketones ?arrow_forward
- Consider the following nucleophilic substitution reaction: R CI Nal R I NaCl acetone Given that the reactants and the products look structurally similar, how can one determine if the substitution reaction took place? O Nal precipitates in acetone. O Nal dissolves in acetone. O NaCl precipitates in acetone. O NaCl dissolves in acetone.arrow_forwardPhenol and other derivatives with a single hydroxyl group on the aromatic ring are not easily oxidized to form a ketone. Why is this? Select all that apply: O Phenol is a secondary alcohol; secondary alcohols do not oxidize. O The carbon that the hydroxyl group is attached to in phenol does not have a hydrogen attached. Forming a double bond between the oxygen and the carbon would require breaking up the stable aromatic ring. Phenol is a tertiary alcohol, which does not oxidize.arrow_forwardDescribe how will you prepare an alcohol from an alkene.arrow_forward
- Both aldehydes and ketones contain carbonyl groups. In aldehydes, the carbonyl carbon atom is bonded to a hydrogen atom, whereas in ketones, the carbonyl carbon atom is bonded to another carbon atom. Select the true statements about aldehydes and ketones. - Ketones have lower boiling points than alcohols of similar size. - Aldehydes contain a carbon–oxygen double bond. - Butanal has a higher boiling point than 2-butanol. - Aldehydes with more than five carbon atoms are soluble in water, but not organic solvents. - Both aldehydes and ketones can hydrogen bond with water molecules. - Propanal is a gas at room temperature, whereas formaldehyde (methanal) is a liquid at room temperature.arrow_forward4. Compare the polarity and water solubility of alcohols, aldehydes, ketones, and carboxylic acids. Tabulate your answer.arrow_forwardConsider the reaction between an alcohol and tosyl chloride, followed by a nucleophile. Write the condensed formula of the expected main organic product. CH₂CH₂CH₂OH 1. TsClpyridine 2. CT CH, CI Incorrectarrow_forward
- What structural characteristic is shared by the aldehydes and the ketones? A) They both are straight chain compounds. B) Aldehydes and ketones both contain a carbonyl carbon. C) Both of these compound classes have as the smallest compound a 5 carbon skeleton. D) Aldehydes and ketones have no shared characteristics.arrow_forwardExplain why carboxylic acids have higher boiling points than other compounds with OH groups?arrow_forwardFunctional Group Classes Alcohol Amide Ester • CH₂CH₂OH * CHIO-CH, 7. H₂C1O Amine Ketone Circle each functional group(s) and identify the class to which each of the groups belongs. 9. H₂C Aldehyde Thiol Aromatics Carboxylic Acid 2. CH,SH 6. Alkenes 4. H₂NCH₂CH₂ 10. Ether NM₂ 11. Which of the functional groups in the top list must be on a terminalC in the carbon chain?arrow_forward
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