Chemistry For Today: General, Organic, And Biochemistry, Loose-leaf Version
9th Edition
ISBN: 9781305968707
Author: Spencer L. Seager
Publisher: Brooks Cole
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Question
Chapter 14, Problem 14.40E
Interpretation Introduction
Interpretation:
The arrow that shows the carbons of the cyclic hemiacetal that was originally part of the
Concept introduction:
Intramolecular reactions occur when carbonyl and hydroxyl functionalities are present on different carbon atoms. This results in the formation of cyclic hemiacetal or cyclic hemiketal.
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1. Which functional group is found in aldehydes?
a. CHO
b. -CH;OH
c. -COOH
d. RCOR'
2. Which functional group is found in ketones?
a. -CHO
CH:OH
c. -COOH
RCOR'
3. Which structural feature is common to aldehydes and ketones?
a, an oxygen atom bonded to both a carbon atom and a hydrogen atom
b. an oxygen atom bonded to two carbon atoms
c. an oxygen atom double bonded to a carbon atom
d. two oxygen atoms bonded to the same carbon atom
4. What is the IUPAC name for the following compound?
a. I-pentaldehyde b. l-pentanal
c. pentanal
d. pentanealdehyde
Cetoa of Fi
Give the IUPAC name for each of the following:
Glycerol contains:
Select one:
a. Oxygens double-bonded to carbon, with alkyls on both sides
b. oxygens single-bonded to primary and secondary carbons
O c. oxygens which are each bonded to two alkyl groups
Od. Oxygens double-bonded to carbon, with alkyls on one side only
Oe. Oxygens double-bonded to carbon, with an alkyl on one side and an --OH on the other side
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Chapter 14 Solutions
Chemistry For Today: General, Organic, And Biochemistry, Loose-leaf Version
Ch. 14 - Prob. 14.1ECh. 14 - Prob. 14.2ECh. 14 - Identify each of the following compounds as an...Ch. 14 - Identify each of the following compounds as an...Ch. 14 - Prob. 14.5ECh. 14 - Prob. 14.6ECh. 14 - Prob. 14.7ECh. 14 - Prob. 14.8ECh. 14 - Draw structural formulas and give IUPAC names for...Ch. 14 - Draw structural formulas and give IUPAC names for...
Ch. 14 - Each of the following names is wrong. Give the...Ch. 14 - Each of the following names is wrong. Give the...Ch. 14 - Prob. 14.13ECh. 14 - Prob. 14.14ECh. 14 - Prob. 14.15ECh. 14 - Explain why propane boils at 42C, whereas ethanal,...Ch. 14 - Use a dotted line to show hydrogen bonding between...Ch. 14 - Use a dotted line to show hydrogen bonding between...Ch. 14 - Prob. 14.19ECh. 14 - Prob. 14.20ECh. 14 - Prob. 14.21ECh. 14 - Prob. 14.22ECh. 14 - Prob. 14.23ECh. 14 - Prob. 14.24ECh. 14 - Label each of the following as acetals, ketals, or...Ch. 14 - Label each of the following as acetals, ketals, or...Ch. 14 - Label each of the following structures as a cyclic...Ch. 14 - Label each of the following structures as a...Ch. 14 - What two functional groups react to form the...Ch. 14 - Hemiacetals are sometimes referred to as potential...Ch. 14 - Complete the following statements: a. Oxidation of...Ch. 14 - Prob. 14.32ECh. 14 - Prob. 14.33ECh. 14 - Prob. 14.34ECh. 14 - Prob. 14.35ECh. 14 - Not all aldehyde give a positve Bendicts test....Ch. 14 - A stockroom assistant prepares three bottles, each...Ch. 14 - Glucose, the sugar present within the blood, gives...Ch. 14 - Fructose, present with glucose in honey, reacts...Ch. 14 - Prob. 14.40ECh. 14 - Prob. 14.41ECh. 14 - Complete the following equations. If no reaction...Ch. 14 - Complete the following equations. If no reaction...Ch. 14 - Describe the products that result when hydrogen...Ch. 14 - Prob. 14.45ECh. 14 - Draw structural formulas for the products of the...Ch. 14 - The following compounds are cyclic acetals or...Ch. 14 - The following compounds are cyclic acetals or...Ch. 14 - Write equations to show how the following...Ch. 14 - Prob. 14.50ECh. 14 - Identify the most important aldehyde and ketone...Ch. 14 - Using Table 14.3, name an aldehyde or ketone used...Ch. 14 - Prob. 14.53ECh. 14 - CH3COH(O)CH3COOHacetaldehydeaceticacid You need to...Ch. 14 - The addition of water to aldehydes and ketones...Ch. 14 - Prob. 14.56ECh. 14 - Formaldehyde levels above 0.10mg/1000L of ambient...Ch. 14 - In the IUPAC name for the following ketone, it is...Ch. 14 - Why can formaldehyde (CH2O) be prepared in the...Ch. 14 - Other addition reactions of aldehydes occur....Ch. 14 - Prob. 14.61ECh. 14 - Prob. 14.62ECh. 14 - Vanilla flavoring is either extracted from a...Ch. 14 - Prob. 14.64ECh. 14 - The use of acetone in laboratory experiments must...Ch. 14 - Prob. 14.66ECh. 14 - Prob. 14.67ECh. 14 - Which of the following would be classified as a...
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- Give the IUPAC name for the following compound:arrow_forwardGlycerol contains: a. oxygens which are each bonded to two alkyl groups b. oxygens single-bonded to primary and secondary carbons c. Oxygens double-bonded to carbon, with alkyls on both sides d. Oxygens double-bonded to carbon, with alkyls on one side only e. Oxygens double-bonded to carbon, with an alkyl on one side and an --OH on the other sidearrow_forwardDraw the chemical structure for each of the followingarrow_forward
- он C-H ÓR Compound that contains a group like that shown above. a. acetal Ob. aldehyde c. Benedict's reagent d. carbonyl Oe. hemiacetal Of. hemiketal Og. hydrolysis h. ketal i. ketone Oj. Tollen's reagent 2.arrow_forwardThe IUPAC name of the compound is?arrow_forwardAn alcohol undergoes dehydration in the presence of a catalyst to form and .arrow_forward
- 1. Differentiate Ethyl alcohol from methyl alcohol. 2. Compare aldehydes and ketones as to (Use acetaldehyde and acetone as examples). A. Reaction with cone. NaOH, heated B. Reaction with Tollen’s reagentarrow_forwardQUESTION 2 Classify the following as an Alcohol, Phenol, Thiol, Ether, Aldehyde or Ketone. CH2 CH2 H H3C OA Alcohol ОВ. phenol OC Thiol O D.Ether OE Aldehyde OF. Ketonearrow_forwardProvide the IUPAC name for the following structure -CH3 H3C H3C CH3arrow_forward
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