Chemistry For Today: General, Organic, And Biochemistry, Loose-leaf Version
9th Edition
ISBN: 9781305968707
Author: Spencer L. Seager
Publisher: Brooks Cole
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Chapter 14, Problem 14.44E
Describe the products that result when hydrogen
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Mark the correct statements about the structural features of alkenes and alkynes. *
A- Free rotation is not possible around a double or triple bond.
B- A triple bond is shorter and stronger than a double bond.
C- A pi-bond can only form by overlap of p-orbitals on adjacent atoms if these atoms are from the same element.
D- The pi-bond in an alkene is weaker than the sigma bond because the sideways overlap of p-orbitals is less than the head-to-head overlap of sp² hybrid orbitals.
E- All the bond angles in an alkyne are 180°.
If the bromine group is replaced with -H. Will the yield of the product increase or decrease? Explain your reason
4. Write down the structure of the product.
Br
2 КОН
ethanol
Br
Chapter 14 Solutions
Chemistry For Today: General, Organic, And Biochemistry, Loose-leaf Version
Ch. 14 - Prob. 14.1ECh. 14 - Prob. 14.2ECh. 14 - Identify each of the following compounds as an...Ch. 14 - Identify each of the following compounds as an...Ch. 14 - Prob. 14.5ECh. 14 - Prob. 14.6ECh. 14 - Prob. 14.7ECh. 14 - Prob. 14.8ECh. 14 - Draw structural formulas and give IUPAC names for...Ch. 14 - Draw structural formulas and give IUPAC names for...
Ch. 14 - Each of the following names is wrong. Give the...Ch. 14 - Each of the following names is wrong. Give the...Ch. 14 - Prob. 14.13ECh. 14 - Prob. 14.14ECh. 14 - Prob. 14.15ECh. 14 - Explain why propane boils at 42C, whereas ethanal,...Ch. 14 - Use a dotted line to show hydrogen bonding between...Ch. 14 - Use a dotted line to show hydrogen bonding between...Ch. 14 - Prob. 14.19ECh. 14 - Prob. 14.20ECh. 14 - Prob. 14.21ECh. 14 - Prob. 14.22ECh. 14 - Prob. 14.23ECh. 14 - Prob. 14.24ECh. 14 - Label each of the following as acetals, ketals, or...Ch. 14 - Label each of the following as acetals, ketals, or...Ch. 14 - Label each of the following structures as a cyclic...Ch. 14 - Label each of the following structures as a...Ch. 14 - What two functional groups react to form the...Ch. 14 - Hemiacetals are sometimes referred to as potential...Ch. 14 - Complete the following statements: a. Oxidation of...Ch. 14 - Prob. 14.32ECh. 14 - Prob. 14.33ECh. 14 - Prob. 14.34ECh. 14 - Prob. 14.35ECh. 14 - Not all aldehyde give a positve Bendicts test....Ch. 14 - A stockroom assistant prepares three bottles, each...Ch. 14 - Glucose, the sugar present within the blood, gives...Ch. 14 - Fructose, present with glucose in honey, reacts...Ch. 14 - Prob. 14.40ECh. 14 - Prob. 14.41ECh. 14 - Complete the following equations. If no reaction...Ch. 14 - Complete the following equations. If no reaction...Ch. 14 - Describe the products that result when hydrogen...Ch. 14 - Prob. 14.45ECh. 14 - Draw structural formulas for the products of the...Ch. 14 - The following compounds are cyclic acetals or...Ch. 14 - The following compounds are cyclic acetals or...Ch. 14 - Write equations to show how the following...Ch. 14 - Prob. 14.50ECh. 14 - Identify the most important aldehyde and ketone...Ch. 14 - Using Table 14.3, name an aldehyde or ketone used...Ch. 14 - Prob. 14.53ECh. 14 - CH3COH(O)CH3COOHacetaldehydeaceticacid You need to...Ch. 14 - The addition of water to aldehydes and ketones...Ch. 14 - Prob. 14.56ECh. 14 - Formaldehyde levels above 0.10mg/1000L of ambient...Ch. 14 - In the IUPAC name for the following ketone, it is...Ch. 14 - Why can formaldehyde (CH2O) be prepared in the...Ch. 14 - Other addition reactions of aldehydes occur....Ch. 14 - Prob. 14.61ECh. 14 - Prob. 14.62ECh. 14 - Vanilla flavoring is either extracted from a...Ch. 14 - Prob. 14.64ECh. 14 - The use of acetone in laboratory experiments must...Ch. 14 - Prob. 14.66ECh. 14 - Prob. 14.67ECh. 14 - Which of the following would be classified as a...
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- What functional group distinguishes each of the following hydrocarbon derivatives? a. halohydrocarbons b. alcohols c. ethers d. aldehydes e. ketones f. carboxylic acids g. esters h. amines Give examples of each functional group. What prefix or suffix is used to name each functional group? What are the bond angles in each? Describe the bonding in each functional group. What is the difference between a primary, secondary, and tertiary alcohol? For the functional groups in ah, when is a number required to indicate the position of the functional group? Carboxylic acids are often written as RCOOH. What does COOH indicate and what does R indicate? Aldehydes are sometimes written as RCHO. What does CHO indicate?arrow_forwardAlkoxy radicals (R¬O # ) are generally more stable than alkyl (R # ) radicals. Write an equation showing an alkyl free radical (from burning gasoline) abstracting a hydrogen atom from tert-butyl alcohol, (CH 3)3COH. Explain why tert-butyl alcohol works as an antiknock additive for gasoline.arrow_forwardIs the reaction between an alkene and a halogen a substitution reaction(displacement reaction) or another reaction? Explain the reaction mechanism by giving an example.arrow_forward
- Excess bromine gas is added to ethyne. The product of this reaction is: 1,1,2,2-tetrabromoethane O 1,2-dibromoethene 1,1-dibromoethane O 1,2-dibromoethanearrow_forwardPlease answer question 14 and 15.arrow_forward1. Most margarines have been hydrogenated to maintain a soft, homogeneous mixture. While the product is easy to spread, this has made the product an unhealthy choice. A hydrogenation reaction is used to convert an alkene to an alkane. a carboxylic acid to an aldehyde. an alkene to a ketone an aromatic hydrocarbon to a linear hydrocarbonarrow_forward
- Name and draw structural formulas for the two possible products of each alkene addition reaction. Use Markovnikov's rule to predict which is the major product.arrow_forwardIs the reaction between an alkene and a halogen a substitution reaction or some other reaction? Explain the reaction mechanism by giving an example.arrow_forwardClassify the following organic reactionsarrow_forward
- type of organic reactionarrow_forwardWhat kinds of reagents add to the weak, electron-rich π bond of alkenes?arrow_forwardThis type of hydrocarbons contain at least one double or triple bond. Unsaturated hydrocarbons Saturated hydrocarbons Polyunsaturated hydrocarbons O Supersaturated hydrocarbons The most acidic among the hydrocarbons. Alkynes Alkenes Alkanes Arenes The number of secondary carbon(s) in this compound. CH3 CH,-C CHCH, CH3 CIarrow_forward
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