(a) Interpretation: The number of total normal modes of vibration in H 2 S is to be calculated. Concept introduction: Spectroscopy method is used to identify the structure of the molecule. It is based on the interactions between matter and electromagnetic radiations. An electronic state of energy has its own vibrational states. The energy between the electronic states is large followed by vibrational states and then rotational states. During an electronic transition, electron from ground state moves straight to the excited state keeping the internuclear distance constant.

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Answer 1

Question

Chapter 14, Problem 14.48E

Interpretation Introduction

(a)

Interpretation:

The number of total normal modes of vibration in H2S is to be calculated.

Concept introduction:

Spectroscopy method is used to identify the structure of the molecule. It is based on the interactions between matter and electromagnetic radiations. An electronic state of energy has its own vibrational states. The energy between the electronic states is large followed by vibrational states and then rotational states. During an electronic transition, electron from ground state moves straight to the excited state keeping the internuclear distance constant.

Interpretation Introduction

(b)

Interpretation:

The number of total normal modes of vibration in OCS is to be calculated.

Concept introduction:

Spectroscopy method is used to identify the structure of the molecule. It is based on the interactions between matter and electromagnetic radiations. An electronic state of energy has its own vibrational states. The energy between the electronic states is large followed by vibrational states and then rotational states. During an electronic transition, electron from ground state moves straight to the excited state keeping the internuclear distance constant.

Interpretation Introduction

(c)

Interpretation:

The number of total normal modes of vibration in SO42− is to be calculated.

Concept introduction:

Spectroscopy method is used to identify the structure of the molecule. It is based on the interactions between matter and electromagnetic radiations. An electronic state of energy has its own vibrational states. The energy between the electronic states is large followed by vibrational states and then rotational states. During an electronic transition, electron from ground state moves straight to the excited state keeping the internuclear distance constant.

Interpretation Introduction

(d)

The number of total normal modes of vibration in COCl2 is to be calculated.

Concept introduction:

Spectroscopy method is used to identify the structure of the molecule. It is based on the interactions between matter and electromagnetic radiations. An electronic state of energy has its own vibrational states. The energy between the electronic states is large followed by vibrational states and then rotational states. During an electronic transition, electron from ground state moves straight to the excited state keeping the internuclear distance constant.

Interpretation Introduction

(e)

Interpretation:

The number of total normal modes of vibration in Cl2 is to be calculated.

Concept introduction:

Spectroscopy method is used to identify the structure of the molecule. It is based on the interactions between matter and electromagnetic radiations. An electronic state of energy has its own vibrational states. The energy between the electronic states is large followed by vibrational states and then rotational states. During an electronic transition, electron from ground state moves straight to the excited state keeping the internuclear distance constant.

Interpretation Introduction

(f)

Interpretation:

The number of total normal modes of vibration in a linear molecule having 20 atoms is to be calculated.

Concept introduction:

Spectroscopy method is used to identify the structure of the molecule. It is based on the interactions between matter and electromagnetic radiations. An electronic state of energy has its own vibrational states. The energy between the electronic states is large followed by vibrational states and then rotational states. During an electronic transition, electron from ground state moves straight to the excited state keeping the internuclear distance constant.

Interpretation Introduction

(g)

Interpretation:

The number of total normal modes of vibration in a nonlinear molecule having 20 atoms is to be calculated.

Concept introduction:

Spectroscopy method is used to identify the structure of the molecule. It is based on the interactions between matter and electromagnetic radiations. An electronic state of energy has its own vibrational states. The energy between the electronic states is large followed by vibrational states and then rotational states. During an electronic transition, electron from ground state moves straight to the excited state keeping the internuclear distance constant.

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Propagation of uncertainty. You have a stock solution certified by the manufacturer to contain 150.0±0.03 µg SO42-/mL. You would like to dilute it by a factor of 100 to obtain 1.500 µg/mL. Calculate the uncertainty in the two methods of dilution below. Use the following uncertainty values for glassware: Glassware Uncertainty (assume glassware has been calibrated and treat the values below as random error) 1.00 mL volumetric pipet 0.01 mL 10.00 mL volumetric pipet 0.02 mL 100.00 mL volumetric flask 0.08 mL Transfer 10.00 mL with a volumetric pipet and dilute it to 100 mL with a volumetric flask. Then take 10.00 mL of the resulting solution and dilute it a second time with a 100 mL flask. 2. Transfer 1.00 mL with a volumetric pipet and dilute it to 100 mL with a volumetric flask.

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Answer 2

Question

Chapter 14, Problem 14.48E

Interpretation Introduction

(a)

Interpretation:

The number of total normal modes of vibration in H2S is to be calculated.

Concept introduction:

Spectroscopy method is used to identify the structure of the molecule. It is based on the interactions between matter and electromagnetic radiations. An electronic state of energy has its own vibrational states. The energy between the electronic states is large followed by vibrational states and then rotational states. During an electronic transition, electron from ground state moves straight to the excited state keeping the internuclear distance constant.

Interpretation Introduction

(b)

Interpretation:

The number of total normal modes of vibration in OCS is to be calculated.

Concept introduction:

Spectroscopy method is used to identify the structure of the molecule. It is based on the interactions between matter and electromagnetic radiations. An electronic state of energy has its own vibrational states. The energy between the electronic states is large followed by vibrational states and then rotational states. During an electronic transition, electron from ground state moves straight to the excited state keeping the internuclear distance constant.

Interpretation Introduction

(c)

Interpretation:

The number of total normal modes of vibration in SO42− is to be calculated.

Concept introduction:

Spectroscopy method is used to identify the structure of the molecule. It is based on the interactions between matter and electromagnetic radiations. An electronic state of energy has its own vibrational states. The energy between the electronic states is large followed by vibrational states and then rotational states. During an electronic transition, electron from ground state moves straight to the excited state keeping the internuclear distance constant.

Interpretation Introduction

(d)

The number of total normal modes of vibration in COCl2 is to be calculated.

Concept introduction:

Spectroscopy method is used to identify the structure of the molecule. It is based on the interactions between matter and electromagnetic radiations. An electronic state of energy has its own vibrational states. The energy between the electronic states is large followed by vibrational states and then rotational states. During an electronic transition, electron from ground state moves straight to the excited state keeping the internuclear distance constant.

Interpretation Introduction

(e)

Interpretation:

The number of total normal modes of vibration in Cl2 is to be calculated.

Concept introduction:

Spectroscopy method is used to identify the structure of the molecule. It is based on the interactions between matter and electromagnetic radiations. An electronic state of energy has its own vibrational states. The energy between the electronic states is large followed by vibrational states and then rotational states. During an electronic transition, electron from ground state moves straight to the excited state keeping the internuclear distance constant.

Interpretation Introduction

(f)

Interpretation:

The number of total normal modes of vibration in a linear molecule having 20 atoms is to be calculated.

Concept introduction:

Spectroscopy method is used to identify the structure of the molecule. It is based on the interactions between matter and electromagnetic radiations. An electronic state of energy has its own vibrational states. The energy between the electronic states is large followed by vibrational states and then rotational states. During an electronic transition, electron from ground state moves straight to the excited state keeping the internuclear distance constant.

Interpretation Introduction

(g)

Interpretation:

The number of total normal modes of vibration in a nonlinear molecule having 20 atoms is to be calculated.

Concept introduction:

Spectroscopy method is used to identify the structure of the molecule. It is based on the interactions between matter and electromagnetic radiations. An electronic state of energy has its own vibrational states. The energy between the electronic states is large followed by vibrational states and then rotational states. During an electronic transition, electron from ground state moves straight to the excited state keeping the internuclear distance constant.

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Answer 3

Question

Chapter 14, Problem 14.48E

Interpretation Introduction

(a)

Interpretation:

The number of total normal modes of vibration in H2S is to be calculated.

Concept introduction:

Spectroscopy method is used to identify the structure of the molecule. It is based on the interactions between matter and electromagnetic radiations. An electronic state of energy has its own vibrational states. The energy between the electronic states is large followed by vibrational states and then rotational states. During an electronic transition, electron from ground state moves straight to the excited state keeping the internuclear distance constant.

Interpretation Introduction

(b)

Interpretation:

The number of total normal modes of vibration in OCS is to be calculated.

Concept introduction:

Spectroscopy method is used to identify the structure of the molecule. It is based on the interactions between matter and electromagnetic radiations. An electronic state of energy has its own vibrational states. The energy between the electronic states is large followed by vibrational states and then rotational states. During an electronic transition, electron from ground state moves straight to the excited state keeping the internuclear distance constant.

Interpretation Introduction

(c)

Interpretation:

The number of total normal modes of vibration in SO42− is to be calculated.

Concept introduction:

Spectroscopy method is used to identify the structure of the molecule. It is based on the interactions between matter and electromagnetic radiations. An electronic state of energy has its own vibrational states. The energy between the electronic states is large followed by vibrational states and then rotational states. During an electronic transition, electron from ground state moves straight to the excited state keeping the internuclear distance constant.

Interpretation Introduction

(d)

The number of total normal modes of vibration in COCl2 is to be calculated.

Concept introduction:

Spectroscopy method is used to identify the structure of the molecule. It is based on the interactions between matter and electromagnetic radiations. An electronic state of energy has its own vibrational states. The energy between the electronic states is large followed by vibrational states and then rotational states. During an electronic transition, electron from ground state moves straight to the excited state keeping the internuclear distance constant.

Interpretation Introduction

(e)

Interpretation:

The number of total normal modes of vibration in Cl2 is to be calculated.

Concept introduction:

Spectroscopy method is used to identify the structure of the molecule. It is based on the interactions between matter and electromagnetic radiations. An electronic state of energy has its own vibrational states. The energy between the electronic states is large followed by vibrational states and then rotational states. During an electronic transition, electron from ground state moves straight to the excited state keeping the internuclear distance constant.

Interpretation Introduction

(f)

Interpretation:

The number of total normal modes of vibration in a linear molecule having 20 atoms is to be calculated.

Concept introduction:

Spectroscopy method is used to identify the structure of the molecule. It is based on the interactions between matter and electromagnetic radiations. An electronic state of energy has its own vibrational states. The energy between the electronic states is large followed by vibrational states and then rotational states. During an electronic transition, electron from ground state moves straight to the excited state keeping the internuclear distance constant.

Interpretation Introduction

(g)

Interpretation:

The number of total normal modes of vibration in a nonlinear molecule having 20 atoms is to be calculated.

Concept introduction:

Spectroscopy method is used to identify the structure of the molecule. It is based on the interactions between matter and electromagnetic radiations. An electronic state of energy has its own vibrational states. The energy between the electronic states is large followed by vibrational states and then rotational states. During an electronic transition, electron from ground state moves straight to the excited state keeping the internuclear distance constant.

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Answer 4

Question

Chapter 14, Problem 14.48E

Interpretation Introduction

(a)

Interpretation:

The number of total normal modes of vibration in H2S is to be calculated.

Concept introduction:

Spectroscopy method is used to identify the structure of the molecule. It is based on the interactions between matter and electromagnetic radiations. An electronic state of energy has its own vibrational states. The energy between the electronic states is large followed by vibrational states and then rotational states. During an electronic transition, electron from ground state moves straight to the excited state keeping the internuclear distance constant.

Interpretation Introduction

(b)

Interpretation:

The number of total normal modes of vibration in OCS is to be calculated.

Concept introduction:

Spectroscopy method is used to identify the structure of the molecule. It is based on the interactions between matter and electromagnetic radiations. An electronic state of energy has its own vibrational states. The energy between the electronic states is large followed by vibrational states and then rotational states. During an electronic transition, electron from ground state moves straight to the excited state keeping the internuclear distance constant.

Interpretation Introduction

(c)

Interpretation:

The number of total normal modes of vibration in SO42− is to be calculated.

Concept introduction:

Spectroscopy method is used to identify the structure of the molecule. It is based on the interactions between matter and electromagnetic radiations. An electronic state of energy has its own vibrational states. The energy between the electronic states is large followed by vibrational states and then rotational states. During an electronic transition, electron from ground state moves straight to the excited state keeping the internuclear distance constant.

Interpretation Introduction

(d)

The number of total normal modes of vibration in COCl2 is to be calculated.

Concept introduction:

Spectroscopy method is used to identify the structure of the molecule. It is based on the interactions between matter and electromagnetic radiations. An electronic state of energy has its own vibrational states. The energy between the electronic states is large followed by vibrational states and then rotational states. During an electronic transition, electron from ground state moves straight to the excited state keeping the internuclear distance constant.

Interpretation Introduction

(e)

Interpretation:

The number of total normal modes of vibration in Cl2 is to be calculated.

Concept introduction:

Spectroscopy method is used to identify the structure of the molecule. It is based on the interactions between matter and electromagnetic radiations. An electronic state of energy has its own vibrational states. The energy between the electronic states is large followed by vibrational states and then rotational states. During an electronic transition, electron from ground state moves straight to the excited state keeping the internuclear distance constant.

Interpretation Introduction

(f)

Interpretation:

The number of total normal modes of vibration in a linear molecule having 20 atoms is to be calculated.

Concept introduction:

Spectroscopy method is used to identify the structure of the molecule. It is based on the interactions between matter and electromagnetic radiations. An electronic state of energy has its own vibrational states. The energy between the electronic states is large followed by vibrational states and then rotational states. During an electronic transition, electron from ground state moves straight to the excited state keeping the internuclear distance constant.

Interpretation Introduction

(g)

Interpretation:

The number of total normal modes of vibration in a nonlinear molecule having 20 atoms is to be calculated.

Concept introduction:

Spectroscopy method is used to identify the structure of the molecule. It is based on the interactions between matter and electromagnetic radiations. An electronic state of energy has its own vibrational states. The energy between the electronic states is large followed by vibrational states and then rotational states. During an electronic transition, electron from ground state moves straight to the excited state keeping the internuclear distance constant.

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Answer 5

Chapter 14, Problem 14.48E

Interpretation Introduction

(a)

Interpretation:

The number of total normal modes of vibration in H2S is to be calculated.

Concept introduction:

Spectroscopy method is used to identify the structure of the molecule. It is based on the interactions between matter and electromagnetic radiations. An electronic state of energy has its own vibrational states. The energy between the electronic states is large followed by vibrational states and then rotational states. During an electronic transition, electron from ground state moves straight to the excited state keeping the internuclear distance constant.

Interpretation Introduction

(b)

Interpretation:

The number of total normal modes of vibration in OCS is to be calculated.

Concept introduction:

Spectroscopy method is used to identify the structure of the molecule. It is based on the interactions between matter and electromagnetic radiations. An electronic state of energy has its own vibrational states. The energy between the electronic states is large followed by vibrational states and then rotational states. During an electronic transition, electron from ground state moves straight to the excited state keeping the internuclear distance constant.

Interpretation Introduction

(c)

Interpretation:

The number of total normal modes of vibration in SO42− is to be calculated.

Concept introduction:

Spectroscopy method is used to identify the structure of the molecule. It is based on the interactions between matter and electromagnetic radiations. An electronic state of energy has its own vibrational states. The energy between the electronic states is large followed by vibrational states and then rotational states. During an electronic transition, electron from ground state moves straight to the excited state keeping the internuclear distance constant.

Interpretation Introduction

(d)

The number of total normal modes of vibration in COCl2 is to be calculated.

Concept introduction:

Spectroscopy method is used to identify the structure of the molecule. It is based on the interactions between matter and electromagnetic radiations. An electronic state of energy has its own vibrational states. The energy between the electronic states is large followed by vibrational states and then rotational states. During an electronic transition, electron from ground state moves straight to the excited state keeping the internuclear distance constant.

Interpretation Introduction

(e)

Interpretation:

The number of total normal modes of vibration in Cl2 is to be calculated.

Concept introduction:

Spectroscopy method is used to identify the structure of the molecule. It is based on the interactions between matter and electromagnetic radiations. An electronic state of energy has its own vibrational states. The energy between the electronic states is large followed by vibrational states and then rotational states. During an electronic transition, electron from ground state moves straight to the excited state keeping the internuclear distance constant.

Interpretation Introduction

(f)

Interpretation:

The number of total normal modes of vibration in a linear molecule having 20 atoms is to be calculated.

Concept introduction:

Spectroscopy method is used to identify the structure of the molecule. It is based on the interactions between matter and electromagnetic radiations. An electronic state of energy has its own vibrational states. The energy between the electronic states is large followed by vibrational states and then rotational states. During an electronic transition, electron from ground state moves straight to the excited state keeping the internuclear distance constant.

Interpretation Introduction

(g)

Interpretation:

The number of total normal modes of vibration in a nonlinear molecule having 20 atoms is to be calculated.

Concept introduction:

Spectroscopy method is used to identify the structure of the molecule. It is based on the interactions between matter and electromagnetic radiations. An electronic state of energy has its own vibrational states. The energy between the electronic states is large followed by vibrational states and then rotational states. During an electronic transition, electron from ground state moves straight to the excited state keeping the internuclear distance constant.

Answer 6

Chapter 14, Problem 14.48E

Interpretation Introduction

(a)

Interpretation:

The number of total normal modes of vibration in H2S is to be calculated.

Concept introduction:

Spectroscopy method is used to identify the structure of the molecule. It is based on the interactions between matter and electromagnetic radiations. An electronic state of energy has its own vibrational states. The energy between the electronic states is large followed by vibrational states and then rotational states. During an electronic transition, electron from ground state moves straight to the excited state keeping the internuclear distance constant.

Answer 7

Chapter 14, Problem 14.48E

Interpretation Introduction

(a)

Interpretation:

The number of total normal modes of vibration in H2S is to be calculated.

Concept introduction:

Spectroscopy method is used to identify the structure of the molecule. It is based on the interactions between matter and electromagnetic radiations. An electronic state of energy has its own vibrational states. The energy between the electronic states is large followed by vibrational states and then rotational states. During an electronic transition, electron from ground state moves straight to the excited state keeping the internuclear distance constant.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The number of total normal modes of vibration in OCS is to be calculated.

Concept introduction:

Spectroscopy method is used to identify the structure of the molecule. It is based on the interactions between matter and electromagnetic radiations. An electronic state of energy has its own vibrational states. The energy between the electronic states is large followed by vibrational states and then rotational states. During an electronic transition, electron from ground state moves straight to the excited state keeping the internuclear distance constant.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The number of total normal modes of vibration in OCS is to be calculated.

Concept introduction:

Spectroscopy method is used to identify the structure of the molecule. It is based on the interactions between matter and electromagnetic radiations. An electronic state of energy has its own vibrational states. The energy between the electronic states is large followed by vibrational states and then rotational states. During an electronic transition, electron from ground state moves straight to the excited state keeping the internuclear distance constant.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The number of total normal modes of vibration in SO42− is to be calculated.

Concept introduction:

Spectroscopy method is used to identify the structure of the molecule. It is based on the interactions between matter and electromagnetic radiations. An electronic state of energy has its own vibrational states. The energy between the electronic states is large followed by vibrational states and then rotational states. During an electronic transition, electron from ground state moves straight to the excited state keeping the internuclear distance constant.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The number of total normal modes of vibration in SO42− is to be calculated.

Concept introduction:

Spectroscopy method is used to identify the structure of the molecule. It is based on the interactions between matter and electromagnetic radiations. An electronic state of energy has its own vibrational states. The energy between the electronic states is large followed by vibrational states and then rotational states. During an electronic transition, electron from ground state moves straight to the excited state keeping the internuclear distance constant.

Answer 12

Interpretation Introduction

(d)

The number of total normal modes of vibration in COCl2 is to be calculated.

Concept introduction:

Spectroscopy method is used to identify the structure of the molecule. It is based on the interactions between matter and electromagnetic radiations. An electronic state of energy has its own vibrational states. The energy between the electronic states is large followed by vibrational states and then rotational states. During an electronic transition, electron from ground state moves straight to the excited state keeping the internuclear distance constant.

Answer 13

Interpretation Introduction

(d)

The number of total normal modes of vibration in COCl2 is to be calculated.

Concept introduction:

Spectroscopy method is used to identify the structure of the molecule. It is based on the interactions between matter and electromagnetic radiations. An electronic state of energy has its own vibrational states. The energy between the electronic states is large followed by vibrational states and then rotational states. During an electronic transition, electron from ground state moves straight to the excited state keeping the internuclear distance constant.

Answer 14

Interpretation Introduction

(e)

Interpretation:

The number of total normal modes of vibration in Cl2 is to be calculated.

Concept introduction:

Spectroscopy method is used to identify the structure of the molecule. It is based on the interactions between matter and electromagnetic radiations. An electronic state of energy has its own vibrational states. The energy between the electronic states is large followed by vibrational states and then rotational states. During an electronic transition, electron from ground state moves straight to the excited state keeping the internuclear distance constant.

Answer 15

Interpretation Introduction

(e)

Interpretation:

The number of total normal modes of vibration in Cl2 is to be calculated.

Concept introduction:

Spectroscopy method is used to identify the structure of the molecule. It is based on the interactions between matter and electromagnetic radiations. An electronic state of energy has its own vibrational states. The energy between the electronic states is large followed by vibrational states and then rotational states. During an electronic transition, electron from ground state moves straight to the excited state keeping the internuclear distance constant.

Answer 16

Interpretation Introduction

(f)

Interpretation:

The number of total normal modes of vibration in a linear molecule having 20 atoms is to be calculated.

Concept introduction:

Spectroscopy method is used to identify the structure of the molecule. It is based on the interactions between matter and electromagnetic radiations. An electronic state of energy has its own vibrational states. The energy between the electronic states is large followed by vibrational states and then rotational states. During an electronic transition, electron from ground state moves straight to the excited state keeping the internuclear distance constant.

Answer 17

Interpretation Introduction

(f)

Interpretation:

The number of total normal modes of vibration in a linear molecule having 20 atoms is to be calculated.

Concept introduction:

Spectroscopy method is used to identify the structure of the molecule. It is based on the interactions between matter and electromagnetic radiations. An electronic state of energy has its own vibrational states. The energy between the electronic states is large followed by vibrational states and then rotational states. During an electronic transition, electron from ground state moves straight to the excited state keeping the internuclear distance constant.

Answer 18

Interpretation Introduction

(g)

Interpretation:

The number of total normal modes of vibration in a nonlinear molecule having 20 atoms is to be calculated.

Concept introduction:

Spectroscopy method is used to identify the structure of the molecule. It is based on the interactions between matter and electromagnetic radiations. An electronic state of energy has its own vibrational states. The energy between the electronic states is large followed by vibrational states and then rotational states. During an electronic transition, electron from ground state moves straight to the excited state keeping the internuclear distance constant.

Answer 19

Interpretation Introduction

(g)

Interpretation:

The number of total normal modes of vibration in a nonlinear molecule having 20 atoms is to be calculated.

Concept introduction:

Spectroscopy method is used to identify the structure of the molecule. It is based on the interactions between matter and electromagnetic radiations. An electronic state of energy has its own vibrational states. The energy between the electronic states is large followed by vibrational states and then rotational states. During an electronic transition, electron from ground state moves straight to the excited state keeping the internuclear distance constant.

Answer 20

Expert Solution & Answer

Answer 21

Expert Solution & Answer

Answer 22

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Answer 23

Ch. 14 - Prob. 14.1E Ch. 14 - Determine if the following integrals can be...Ch. 14 - What is the frequency of light having the...Ch. 14 - What is the wavelength of light having the given...Ch. 14 - What is the energy of light having each...Ch. 14 - The Cu(H2O)62+ complex has octahedral symmetry. Is...Ch. 14 - What are the wavelength, speed, and energy of a...Ch. 14 - Prob. 14.8E Ch. 14 - Prob. 14.9E Ch. 14 - Prob. 14.10E

Solution Summary: The author explains that the number of total normal modes of vibration for a nonlinear molecule is calculated by the formula shown below.

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