Physical Chemistry
2nd Edition
ISBN: 9781285969770
Author: Ball
Publisher: Cengage
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Question
Chapter 14, Problem 14.92E
Interpretation Introduction
Interpretation:
The derivation of expression used in the solution of example 14.21a is to be provided.
Concept introduction:
The P and R branch of lines are produced because of rotational and vibrational spectrum occurring together. The P and R branch of lines are due to change in the rotational level of molecule with the vibrational change. There some selection rules for the transitions to occur according to which these lines are formed and given names as P and R branch lines.
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a. The change in the Gibbs energy of a certain constant pressure process is found to fit the expression:
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Chapter 14 Solutions
Physical Chemistry
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