The values of rotational constant, B for SF 6 and UF 6 are to be calculated. The differences between their B values, taking into account their atomic masses is to be commented. Concept introduction: In a molecule, the rotational energy level corresponds to the different probable ways in which the portion of a molecule rotates around the chemical bond that binds it to the rest of the molecule. Every rotational energy level possesses degeneracy. The two-body system is represented as a one-body system by a reduced mass. It is expressed by a quantity μ . The inertial mass of the moving body with respect to the body which is at rest is simplified to a reduced mass when there are only mutual interactions between the two bodies. The spherical top refers to a symmetric rotor that has the same value for all moments of inertia. For spherical tops, I a = I b = I c .

Question

1A H 2A Li Be Use the References to access important values if needed for this question. 8A 3A 4A 5A 6A 7A He B C N O F Ne Na Mg 3B 4B 5B 6B 7B 8B-1B 2B Al Si P 1B 2B Al Si P S Cl Ar K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe * Cs Ba La Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn Fr Ra Ac Rf Ha ****** Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr Analyze the following reaction by looking at the electron configurations given below each box. Put a number and a symbol in each box to show the number and kind of the corresponding atom or ion. Use the smallest integers possible. cation anion + + Shell 1: 2 Shell 2: 8 Shell 3: 1 Shell 1 : 2 Shell 2 : 6 Shell 1 : 2 Shell 2: 8 Shell 1: 2 Shell 2: 8

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Chapter 14, Problem 14.16E

Interpretation Introduction

Interpretation:

The values of rotational constant, B for SF6 and UF6 are to be calculated. The differences between their B values, taking into account their atomic masses is to be commented.

Concept introduction:

In a molecule, the rotational energy level corresponds to the different probable ways in which the portion of a molecule rotates around the chemical bond that binds it to the rest of the molecule. Every rotational energy level possesses degeneracy.

The two-body system is represented as a one-body system by a reduced mass. It is expressed by a quantity μ. The inertial mass of the moving body with respect to the body which is at rest is simplified to a reduced mass when there are only mutual interactions between the two bodies.

The spherical top refers to a symmetric rotor that has the same value for all moments of inertia. For spherical tops, Ia=Ib=Ic.

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