(a) Interpretation: The molecule from the given pair of molecule that possesses the fewer different vibrational frequency is to be stated. Concept introduction: The vibration of the atoms present in a molecule takes place in a periodic motion and that molecule possess the constant rotational and translational motions then it is known as a vibrational frequency of a molecule.

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Answer 1

Question

Chapter 14, Problem 14.75E

Interpretation Introduction

(a)

Interpretation:

The molecule from the given pair of molecule that possesses the fewer different vibrational frequency is to be stated.

Concept introduction:

The vibration of the atoms present in a molecule takes place in a periodic motion and that molecule possess the constant rotational and translational motions then it is known as a vibrational frequency of a molecule.

Interpretation Introduction

(b)

Interpretation:

The molecule from the given pair of molecule that possesses the fewer different vibrational frequency is to be stated.

Concept introduction:

The vibration of the atoms present in a molecule takes place in a periodic motion and that molecule possess the constant rotational and translational motions then it is known as a vibrational frequency of a molecule.

Interpretation Introduction

(c)

Interpretation:

The molecule from the given pair of molecule that possesses the fewer different vibrational frequency is to be stated.

Concept introduction:

The vibration of the atoms present in a molecule takes place in a periodic motion and that molecule possess the constant rotational and translational motions then it is known as a vibrational frequency of a molecule.

Interpretation Introduction

(d)

Interpretation:

The molecule from the given pair of molecule that possesses the fewer different vibrational frequency is to be stated.

Concept introduction:

The vibration of the atoms present in a molecule takes place in a periodic motion and that molecule possess the constant rotational and translational motions then it is known as a vibrational frequency of a molecule.

Interpretation Introduction

(e)

Interpretation:

The molecule from the given pair of molecule that possesses the fewer different vibrational frequency is to be stated.

Concept introduction:

The vibration of the atoms present in a molecule takes place in a periodic motion and that molecule possess the constant rotational and translational motions then it is known as a vibrational frequency of a molecule.

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Part II. Given two isomers: 2-methylpentane (A) and 2,2-dimethyl butane (B) answer the following: (a) match structures of isomers given their mass spectra below (spectra A and spectra B) (b) Draw the fragments given the following prominent peaks from each spectrum: Spectra A m/2 =43 and 1/2-57 spectra B m/2 = 43 (c) why is 1/2=57 peak in spectrum A more intense compared to the same peak in spectrum B. Relative abundance Relative abundance 100 A 50 29 29 0 10 -0 -0 100 B 50 720 30 41 43 57 71 4-0 40 50 60 70 m/z 43 57 8-0 m/z = 86 M 90 100 71 m/z = 86 M -O 0 10 20 30 40 50 60 70 80 -88 m/z 90 100

Part IV. C6H5 CH2CH2OH is an aromatic compound which was subjected to Electron Ionization - mass spectrometry (El-MS) analysis. Prominent m/2 values: m/2 = 104 and m/2 = 9) was obtained. Draw the structures of these fragments.

For each reaction shown below follow the curved arrows to complete each equationby showing the structure of the products. Identify the acid, the base, the conjugated acid andconjugated base. Consutl the pKa table and choose the direciton theequilibrium goes. However show the curved arrows. Please explain if possible.

Answer 2

Question

Chapter 14, Problem 14.75E

Interpretation Introduction

(a)

Interpretation:

The molecule from the given pair of molecule that possesses the fewer different vibrational frequency is to be stated.

Concept introduction:

The vibration of the atoms present in a molecule takes place in a periodic motion and that molecule possess the constant rotational and translational motions then it is known as a vibrational frequency of a molecule.

Interpretation Introduction

(b)

Interpretation:

The molecule from the given pair of molecule that possesses the fewer different vibrational frequency is to be stated.

Concept introduction:

The vibration of the atoms present in a molecule takes place in a periodic motion and that molecule possess the constant rotational and translational motions then it is known as a vibrational frequency of a molecule.

Interpretation Introduction

(c)

Interpretation:

The molecule from the given pair of molecule that possesses the fewer different vibrational frequency is to be stated.

Concept introduction:

The vibration of the atoms present in a molecule takes place in a periodic motion and that molecule possess the constant rotational and translational motions then it is known as a vibrational frequency of a molecule.

Interpretation Introduction

(d)

Interpretation:

The molecule from the given pair of molecule that possesses the fewer different vibrational frequency is to be stated.

Concept introduction:

The vibration of the atoms present in a molecule takes place in a periodic motion and that molecule possess the constant rotational and translational motions then it is known as a vibrational frequency of a molecule.

Interpretation Introduction

(e)

Interpretation:

The molecule from the given pair of molecule that possesses the fewer different vibrational frequency is to be stated.

Concept introduction:

The vibration of the atoms present in a molecule takes place in a periodic motion and that molecule possess the constant rotational and translational motions then it is known as a vibrational frequency of a molecule.

Expert Solution & Answer

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Answer 3

Question

Chapter 14, Problem 14.75E

Interpretation Introduction

(a)

Interpretation:

The molecule from the given pair of molecule that possesses the fewer different vibrational frequency is to be stated.

Concept introduction:

The vibration of the atoms present in a molecule takes place in a periodic motion and that molecule possess the constant rotational and translational motions then it is known as a vibrational frequency of a molecule.

Interpretation Introduction

(b)

Interpretation:

The molecule from the given pair of molecule that possesses the fewer different vibrational frequency is to be stated.

Concept introduction:

The vibration of the atoms present in a molecule takes place in a periodic motion and that molecule possess the constant rotational and translational motions then it is known as a vibrational frequency of a molecule.

Interpretation Introduction

(c)

Interpretation:

The molecule from the given pair of molecule that possesses the fewer different vibrational frequency is to be stated.

Concept introduction:

The vibration of the atoms present in a molecule takes place in a periodic motion and that molecule possess the constant rotational and translational motions then it is known as a vibrational frequency of a molecule.

Interpretation Introduction

(d)

Interpretation:

The molecule from the given pair of molecule that possesses the fewer different vibrational frequency is to be stated.

Concept introduction:

The vibration of the atoms present in a molecule takes place in a periodic motion and that molecule possess the constant rotational and translational motions then it is known as a vibrational frequency of a molecule.

Interpretation Introduction

(e)

Interpretation:

The molecule from the given pair of molecule that possesses the fewer different vibrational frequency is to be stated.

Concept introduction:

The vibration of the atoms present in a molecule takes place in a periodic motion and that molecule possess the constant rotational and translational motions then it is known as a vibrational frequency of a molecule.

Expert Solution & Answer

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See solution

Answer 4

Question

Chapter 14, Problem 14.75E

Interpretation Introduction

(a)

Interpretation:

The molecule from the given pair of molecule that possesses the fewer different vibrational frequency is to be stated.

Concept introduction:

The vibration of the atoms present in a molecule takes place in a periodic motion and that molecule possess the constant rotational and translational motions then it is known as a vibrational frequency of a molecule.

Interpretation Introduction

(b)

Interpretation:

The molecule from the given pair of molecule that possesses the fewer different vibrational frequency is to be stated.

Concept introduction:

The vibration of the atoms present in a molecule takes place in a periodic motion and that molecule possess the constant rotational and translational motions then it is known as a vibrational frequency of a molecule.

Interpretation Introduction

(c)

Interpretation:

The molecule from the given pair of molecule that possesses the fewer different vibrational frequency is to be stated.

Concept introduction:

The vibration of the atoms present in a molecule takes place in a periodic motion and that molecule possess the constant rotational and translational motions then it is known as a vibrational frequency of a molecule.

Interpretation Introduction

(d)

Interpretation:

The molecule from the given pair of molecule that possesses the fewer different vibrational frequency is to be stated.

Concept introduction:

The vibration of the atoms present in a molecule takes place in a periodic motion and that molecule possess the constant rotational and translational motions then it is known as a vibrational frequency of a molecule.

Interpretation Introduction

(e)

Interpretation:

The molecule from the given pair of molecule that possesses the fewer different vibrational frequency is to be stated.

Concept introduction:

The vibration of the atoms present in a molecule takes place in a periodic motion and that molecule possess the constant rotational and translational motions then it is known as a vibrational frequency of a molecule.

Expert Solution & Answer

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See solution

Answer 5

Chapter 14, Problem 14.75E

Interpretation Introduction

(a)

Interpretation:

The molecule from the given pair of molecule that possesses the fewer different vibrational frequency is to be stated.

Concept introduction:

The vibration of the atoms present in a molecule takes place in a periodic motion and that molecule possess the constant rotational and translational motions then it is known as a vibrational frequency of a molecule.

Interpretation Introduction

(b)

Interpretation:

The molecule from the given pair of molecule that possesses the fewer different vibrational frequency is to be stated.

Concept introduction:

The vibration of the atoms present in a molecule takes place in a periodic motion and that molecule possess the constant rotational and translational motions then it is known as a vibrational frequency of a molecule.

Interpretation Introduction

(c)

Interpretation:

The molecule from the given pair of molecule that possesses the fewer different vibrational frequency is to be stated.

Concept introduction:

The vibration of the atoms present in a molecule takes place in a periodic motion and that molecule possess the constant rotational and translational motions then it is known as a vibrational frequency of a molecule.

Interpretation Introduction

(d)

Interpretation:

The molecule from the given pair of molecule that possesses the fewer different vibrational frequency is to be stated.

Concept introduction:

The vibration of the atoms present in a molecule takes place in a periodic motion and that molecule possess the constant rotational and translational motions then it is known as a vibrational frequency of a molecule.

Interpretation Introduction

(e)

Interpretation:

The molecule from the given pair of molecule that possesses the fewer different vibrational frequency is to be stated.

Concept introduction:

The vibration of the atoms present in a molecule takes place in a periodic motion and that molecule possess the constant rotational and translational motions then it is known as a vibrational frequency of a molecule.

Answer 6

Chapter 14, Problem 14.75E

Interpretation Introduction

(a)

Interpretation:

The molecule from the given pair of molecule that possesses the fewer different vibrational frequency is to be stated.

Concept introduction:

The vibration of the atoms present in a molecule takes place in a periodic motion and that molecule possess the constant rotational and translational motions then it is known as a vibrational frequency of a molecule.

Answer 7

Chapter 14, Problem 14.75E

Interpretation Introduction

(a)

Interpretation:

The molecule from the given pair of molecule that possesses the fewer different vibrational frequency is to be stated.

Concept introduction:

The vibration of the atoms present in a molecule takes place in a periodic motion and that molecule possess the constant rotational and translational motions then it is known as a vibrational frequency of a molecule.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The molecule from the given pair of molecule that possesses the fewer different vibrational frequency is to be stated.

Concept introduction:

The vibration of the atoms present in a molecule takes place in a periodic motion and that molecule possess the constant rotational and translational motions then it is known as a vibrational frequency of a molecule.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The molecule from the given pair of molecule that possesses the fewer different vibrational frequency is to be stated.

Concept introduction:

The vibration of the atoms present in a molecule takes place in a periodic motion and that molecule possess the constant rotational and translational motions then it is known as a vibrational frequency of a molecule.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The molecule from the given pair of molecule that possesses the fewer different vibrational frequency is to be stated.

Concept introduction:

The vibration of the atoms present in a molecule takes place in a periodic motion and that molecule possess the constant rotational and translational motions then it is known as a vibrational frequency of a molecule.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The molecule from the given pair of molecule that possesses the fewer different vibrational frequency is to be stated.

Concept introduction:

The vibration of the atoms present in a molecule takes place in a periodic motion and that molecule possess the constant rotational and translational motions then it is known as a vibrational frequency of a molecule.

Answer 12

Interpretation Introduction

(d)

Interpretation:

The molecule from the given pair of molecule that possesses the fewer different vibrational frequency is to be stated.

Concept introduction:

The vibration of the atoms present in a molecule takes place in a periodic motion and that molecule possess the constant rotational and translational motions then it is known as a vibrational frequency of a molecule.

Answer 13

Interpretation Introduction

(d)

Interpretation:

The molecule from the given pair of molecule that possesses the fewer different vibrational frequency is to be stated.

Concept introduction:

The vibration of the atoms present in a molecule takes place in a periodic motion and that molecule possess the constant rotational and translational motions then it is known as a vibrational frequency of a molecule.

Answer 14

Interpretation Introduction

(e)

Interpretation:

The molecule from the given pair of molecule that possesses the fewer different vibrational frequency is to be stated.

Concept introduction:

The vibration of the atoms present in a molecule takes place in a periodic motion and that molecule possess the constant rotational and translational motions then it is known as a vibrational frequency of a molecule.

Answer 15

Interpretation Introduction

(e)

Interpretation:

The molecule from the given pair of molecule that possesses the fewer different vibrational frequency is to be stated.

Concept introduction:

The vibration of the atoms present in a molecule takes place in a periodic motion and that molecule possess the constant rotational and translational motions then it is known as a vibrational frequency of a molecule.

Answer 16

Expert Solution & Answer

Answer 17

Expert Solution & Answer

Answer 18

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Answer 19

Ch. 14 - Prob. 14.1E Ch. 14 - Determine if the following integrals can be...Ch. 14 - What is the frequency of light having the...Ch. 14 - What is the wavelength of light having the given...Ch. 14 - What is the energy of light having each...Ch. 14 - The Cu(H2O)62+ complex has octahedral symmetry. Is...Ch. 14 - What are the wavelength, speed, and energy of a...Ch. 14 - Prob. 14.8E Ch. 14 - Prob. 14.9E Ch. 14 - Prob. 14.10E

Solution Summary: The author explains that the molecule from the given pair of compounds has the same number of vibrational frequencies.

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Chapter 14 Solutions