Concept explainers
a.
Interpretation:
Chiral centers in the given monosaccharide has to be labelled, the monosaccharide has to be classified as D or L, the enantiomer of the given monosaccharide has to be drawn and also the Fischer projection formula has to be given.
Concept Introduction:
A carbon atom that is bonded to four different groups is known as a chiral carbon atom. This can rotate the plane polarized light. D- and L- isomers of monosaccharide can be identified by looking into the chiral center that is farther from the carbonyl group. In a Fischer projection, if the
Enantiomers are two stereoisomers of a compound that rotate the plane polarized light exactly opposite. The configuration present in the enantiomers will be exactly opposite to each other.
Fischer projection formula simply uses cross for representing tetrahedral carbon atom. The carbon atom that is present in the intersection point in cross. The horizontal bonds means they are coming forward and they are present on wedge bond. The vertical bonds means they are pointing away and they are present on dashed lines.
b.
Interpretation:
Chiral centers in the given monosaccharide has to be labelled, the monosaccharide has to be classified as D or L, the enantiomer of the given monosaccharide has to be drawn and also the Fischer projection formula has to be given.
Concept Introduction:
Refer part “a.”.
c.
Interpretation:
Chiral centers in the given monosaccharide has to be labelled, the monosaccharide has to be classified as D or L, the enantiomer of the given monosaccharide has to be drawn and also the Fischer projection formula has to be given.
Concept Introduction:
Refer part “a.”.
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Chapter 14 Solutions
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- The following 'H NMR spectrum was taken with a 750 MHz spectrometer: 1.0 0.5 0.0 10.0 9.0 8.0 7.0 6.0 5.0 4.0 3.0 ' 2.0 1.0 0.0 (ppm) What is the difference Av in the frequency of RF ac Δν ac radiation absorbed by the a and c protons? (Note: it's not equal to the difference in chemical shifts.) Round your answer to 2 significant digits, and be sure it has an appropriate unit symbol. = O O a will shift left, c will shift right. O a will shift right, c will shift left. a and c will both shift left, with more space between them. Suppose a new spectrum is taken with a 500 MHz spectrometer. What will be true about this new spectrum? O a and c will both shift left, with less space between them. O a and c will both shift right, with more space between them. O a and c will both shift right, with less space between them. Which protons have the largest energy gap between spin up and spin down states? O None of the above. ○ a Ob Explanation Check C Ar B 2025 McGraw Hill LLC. All Rights Reserved.…arrow_forwardWhat mass of Na2CO3 must you add to 125g of water to prepare 0.200 m Na2CO3? Calculate mole fraction of Na2CO3, mass percent, and molarity of the resulting solution. MM (g/mol): Na2CO3 105.99; water 18.02. Final solution density is 1.04 g/mL.arrow_forward(ME EX2) Prblms Can you please explain problems to me in detail, step by step? Thank you so much! If needed color code them for me.arrow_forward
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