THERMODYNAMICS (LL)-W/ACCESS >CUSTOM<
9th Edition
ISBN: 9781266657610
Author: CENGEL
Publisher: MCG CUSTOM
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Chapter 13.3, Problem 47P
To determine
Whether the specific internal energy of a gas mixture equals to the sum of the specific internal energies of each individual gas in the mixture.
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A mixture of gaseous reactants is put into a cylinder, where a chemical reaction turns them into gaseous products. The
cylinder has a piston that moves in or out, as necessary, to keep a constant pressure on the mixture of 1 atm. The
cylinder is also submerged in a large insulated water bath. (See sketch at right.)
1 atm pressure
piston
cylinder
From previous experiments, this chemical reaction is known to absorb 322. kJ of energy.
water bath
The temperature of the water bath is monitored, and it is determined from this data that 188. kJ of heat flows out of the
gases
system during the reaction.
O exothermic
Is the reaction exothermic or endothermic?
O endothermic
O up
Does the temperature of the water bath go up or
?
O down
down?
O neither
O in
Does the piston move in or out?
O out
O neither
O does work
Does the gas mixture do work, or is work done
on it?
O work
done on it
O neither
How much work is done on (or by) the gas
mixture? Be sure your answer has the correct
number of…
Which is the physical property to express deviations of pressure between an ideal mixture and areal gas mixture?
Problem 13.033 Specific Heat and Molecular Weight
The volumetric analysis of a mixture of gases is 30 percent oxygen, 40 percent nitrogen, 10 percent carbon dioxide, and 20 percent
methane. Calculate the apparent specific heats and molecular weight of this mixture of gases. The universal gas constant is Ru = 8.314
kJ/kmol-K. Use the table containing the molar mass, gas constant, and critical-point properties and the table containing the ideal-gas
specific heats of various common gases.
The apparent molecular weight of this mixture of gases is
The constant-pressure specific heat of the mixture is
The constant-volume specific heat of the mixture is
kg/kmol.
kJ/kg-K.
kJ/kg-K.
Chapter 13 Solutions
THERMODYNAMICS (LL)-W/ACCESS >CUSTOM<
Ch. 13.3 - What are mass and mole fractions?Ch. 13.3 - Consider a mixture of several gases of identical...Ch. 13.3 - The sum of the mole fractions for an ideal-gas...Ch. 13.3 - Somebody claims that the mass and mole fractions...Ch. 13.3 - Consider a mixture of two gases. Can the apparent...Ch. 13.3 - What is the apparent molar mass for a gas mixture?...Ch. 13.3 - Prob. 7PCh. 13.3 - The composition of moist air is given on a molar...Ch. 13.3 - Prob. 9PCh. 13.3 - Prob. 10P
Ch. 13.3 - A gas mixture consists of 20 percent O2, 30...Ch. 13.3 - Prob. 12PCh. 13.3 - Prob. 13PCh. 13.3 - Consider a mixture of two gases A and B. Show that...Ch. 13.3 - Is a mixture of ideal gases also an ideal gas?...Ch. 13.3 - Express Daltons law of additive pressures. Does...Ch. 13.3 - Express Amagats law of additive volumes. Does this...Ch. 13.3 - Prob. 18PCh. 13.3 - How is the P-v-T behavior of a component in an...Ch. 13.3 - Prob. 20PCh. 13.3 - Prob. 21PCh. 13.3 - Prob. 22PCh. 13.3 - Consider a rigid tank that contains a mixture of...Ch. 13.3 - Prob. 24PCh. 13.3 - Is this statement correct? The temperature of an...Ch. 13.3 - Is this statement correct? The volume of an...Ch. 13.3 - Is this statement correct? The pressure of an...Ch. 13.3 - A gas mixture at 300 K and 200 kPa consists of 1...Ch. 13.3 - Prob. 29PCh. 13.3 - Separation units often use membranes, absorbers,...Ch. 13.3 - Prob. 31PCh. 13.3 - The mass fractions of a mixture of gases are 15...Ch. 13.3 - The volumetric analysis of a mixture of gases is...Ch. 13.3 - An engineer has proposed mixing extra oxygen with...Ch. 13.3 - A rigid tank contains 0.5 kmol of Ar and 2 kmol of...Ch. 13.3 - A mixture of gases consists of 0.9 kg of oxygen,...Ch. 13.3 - Prob. 37PCh. 13.3 - One pound-mass of a gas whose density is 0.001...Ch. 13.3 - A 30 percent (by mass) ethane and 70 percent...Ch. 13.3 - Prob. 40PCh. 13.3 - Prob. 41PCh. 13.3 - A rigid tank that contains 2 kg of N2 at 25C and...Ch. 13.3 - Prob. 43PCh. 13.3 - Prob. 44PCh. 13.3 - Prob. 45PCh. 13.3 - Is the total internal energy of an ideal-gas...Ch. 13.3 - Prob. 47PCh. 13.3 - Prob. 48PCh. 13.3 - Prob. 49PCh. 13.3 - Prob. 50PCh. 13.3 - The volumetric analysis of a mixture of gases is...Ch. 13.3 - A mixture of nitrogen and carbon dioxide has a...Ch. 13.3 - The mass fractions of a mixture of gases are 15...Ch. 13.3 - A mixture of gases consists of 0.1 kg of oxygen, 1...Ch. 13.3 - An insulated tank that contains 1 kg of O2at 15C...Ch. 13.3 - An insulated rigid tank is divided into two...Ch. 13.3 - Prob. 59PCh. 13.3 - A mixture of 65 percent N2 and 35 percent CO2...Ch. 13.3 - Prob. 62PCh. 13.3 - Prob. 63PCh. 13.3 - Prob. 66PCh. 13.3 - Prob. 67PCh. 13.3 - Prob. 68PCh. 13.3 - Prob. 69PCh. 13.3 - The gas passing through the turbine of a simple...Ch. 13.3 - Prob. 71PCh. 13.3 - A pistoncylinder device contains 6 kg of H2 and 21...Ch. 13.3 - Prob. 73PCh. 13.3 - Prob. 74PCh. 13.3 - Prob. 75PCh. 13.3 - Prob. 76PCh. 13.3 - Prob. 77PCh. 13.3 - Prob. 78PCh. 13.3 - Prob. 79PCh. 13.3 - Prob. 81PCh. 13.3 - Fresh water is obtained from seawater at a rate of...Ch. 13.3 - Is it possible for an adiabatic liquid-vapor...Ch. 13.3 - Prob. 84PCh. 13.3 - Prob. 85RPCh. 13.3 - The products of combustion of a hydrocarbon fuel...Ch. 13.3 - A mixture of gases is assembled by first filling...Ch. 13.3 - Prob. 90RPCh. 13.3 - Prob. 91RPCh. 13.3 - Prob. 92RPCh. 13.3 - A rigid tank contains a mixture of 4 kg of He and...Ch. 13.3 - A spring-loaded pistoncylinder device contains a...Ch. 13.3 - Prob. 95RPCh. 13.3 - Reconsider Prob. 1395. Calculate the total work...Ch. 13.3 - Prob. 97RPCh. 13.3 - Prob. 100RPCh. 13.3 - Prob. 101RPCh. 13.3 - Prob. 102FEPCh. 13.3 - An ideal-gas mixture whose apparent molar mass is...Ch. 13.3 - An ideal-gas mixture consists of 2 kmol of N2and 4...Ch. 13.3 - Prob. 105FEPCh. 13.3 - Prob. 106FEPCh. 13.3 - An ideal-gas mixture consists of 3 kg of Ar and 6...Ch. 13.3 - Prob. 108FEPCh. 13.3 - Prob. 109FEPCh. 13.3 - Prob. 110FEPCh. 13.3 - Prob. 111FEP
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