Thermodynamics: An Engineering Approach
8th Edition
ISBN: 9780073398174
Author: Yunus A. Cengel Dr., Michael A. Boles
Publisher: McGraw-Hill Education
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Chapter 13.3, Problem 100RP
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What is the Δr xn G o (in KJ/mole) for a mole of an ideal gas as pressure changes from 0.1 Pa to 1 x10 5 Pa?
(NOTE: Express answer in THREE SIGNIFICANT FIGURES.)
A cylinder contains oxygen at a pressure of 2.00 atm. The volume is 4.00 L, and the temperature is 300 K. Assume that the oxygen may be treated as an ideal gas. The oxygen is carried through the following processes: (i) Heated at constant pressure from the initial state (state 1) to state 2, which has T = 450 K. (ii) Cooled at constant volume to 250 K (state 3). (iii) Compressed at constant temperature to a volume of 4.00 L (state 4). (iv) Heated at constant volume to 300 K, which takes the system back to state 1. (a) Show these four processes in a pV-diagram, giving the numerical values of p and V in each of the four states. (b) Calculate Q and W for each of the four processes. (c) Calculate the net work done by the oxygen in the complete cycle. (d) What is the efficiency of this device as a heat engine? How does this compare to the efficiency of a Carnot-cycle engine operating between the same minimum and maximum temperatures of 250 K and 450 K?
At low pressures, the compressibility factor of a van der Waals gas is given by the equation:
Z = PV/RT = 1+(b- a/RT) P/RT
Calculate the fugacity of nitrogen gas at 3000 K and 0.05 bar. The van der Waals
constants of nitrogen gas are a = 1.408 L^2-bar-mol^2
and b = 0.03913 L-mol^-1. By investigating the fugacity coefficient, what can be said about nitrogen at this
temperature and pressure?
*final answer in 4 decimals
Chapter 13 Solutions
Thermodynamics: An Engineering Approach
Ch. 13.3 - Consider a mixture of several gases of identical...Ch. 13.3 - Somebody claims that the mass and mole fractions...Ch. 13.3 - The sum of the mole fractions for an ideal-gas...Ch. 13.3 - Consider a mixture of two gases. Can the apparent...Ch. 13.3 - What is the apparent molar mass for a gas mixture?...Ch. 13.3 - Prob. 6PCh. 13.3 - Consider a mixture of two gases A and B. Show that...Ch. 13.3 - The composition of moist air is given on a molar...Ch. 13.3 - Prob. 9PCh. 13.3 - Prob. 10P
Ch. 13.3 - Prob. 11PCh. 13.3 - Prob. 12PCh. 13.3 - Prob. 13PCh. 13.3 - Is a mixture of ideal gases also an ideal gas?...Ch. 13.3 - Express Daltons law of additive pressures. Does...Ch. 13.3 - Express Amagats law of additive volumes. Does this...Ch. 13.3 - How is the P-v-T behavior of a component in an...Ch. 13.3 - Prob. 18PCh. 13.3 - Prob. 19PCh. 13.3 - Prob. 20PCh. 13.3 - Prob. 21PCh. 13.3 - Consider a rigid tank that contains a mixture of...Ch. 13.3 - Is this statement correct? The volume of an...Ch. 13.3 - Is this statement correct? The temperature of an...Ch. 13.3 - Is this statement correct? The pressure of an...Ch. 13.3 - Prob. 26PCh. 13.3 - Prob. 27PCh. 13.3 - Prob. 28PCh. 13.3 - 13–29 A gas mixture at 350 K and 300 kPa has the...Ch. 13.3 - Prob. 30PCh. 13.3 - Prob. 31PCh. 13.3 - A rigid tank that contains 2 kg of N2 at 25C and...Ch. 13.3 - Prob. 33PCh. 13.3 - Prob. 34PCh. 13.3 - Prob. 35PCh. 13.3 - Prob. 36PCh. 13.3 - A 30 percent (by mass) ethane and 70 percent...Ch. 13.3 - Prob. 38PCh. 13.3 - Prob. 39PCh. 13.3 - Prob. 40PCh. 13.3 - Prob. 41PCh. 13.3 - Prob. 42PCh. 13.3 - Prob. 43PCh. 13.3 - Is the total internal energy of an ideal-gas...Ch. 13.3 - Prob. 45PCh. 13.3 - Prob. 46PCh. 13.3 - 13–47C Is the total internal energy change of an...Ch. 13.3 - Prob. 48PCh. 13.3 - Prob. 49PCh. 13.3 - The volumetric analysis of a mixture of gases is...Ch. 13.3 - Prob. 52PCh. 13.3 - Prob. 53PCh. 13.3 - Prob. 54PCh. 13.3 - Prob. 55PCh. 13.3 - Prob. 56PCh. 13.3 - An insulated tank that contains 1 kg of O2at 15C...Ch. 13.3 - Prob. 59PCh. 13.3 - Prob. 60PCh. 13.3 - Prob. 61PCh. 13.3 - Prob. 62PCh. 13.3 - Prob. 63PCh. 13.3 - Prob. 64PCh. 13.3 - Prob. 66PCh. 13.3 - Prob. 67PCh. 13.3 - Prob. 69PCh. 13.3 - A pistoncylinder device contains 6 kg of H2 and 21...Ch. 13.3 - Prob. 71PCh. 13.3 - Prob. 72PCh. 13.3 - Prob. 73PCh. 13.3 - Prob. 74PCh. 13.3 - Prob. 75PCh. 13.3 - Prob. 76PCh. 13.3 - Prob. 77PCh. 13.3 - Prob. 78PCh. 13.3 - Prob. 80PCh. 13.3 - Prob. 81PCh. 13.3 - Fresh water is obtained from seawater at a rate of...Ch. 13.3 - Prob. 83PCh. 13.3 - Prob. 84RPCh. 13.3 - The products of combustion of a hydrocarbon fuel...Ch. 13.3 - Prob. 89RPCh. 13.3 - Prob. 91RPCh. 13.3 - Prob. 92RPCh. 13.3 - A spring-loaded pistoncylinder device contains a...Ch. 13.3 - Prob. 94RPCh. 13.3 - Reconsider Prob. 1395. Calculate the total work...Ch. 13.3 - A rigid tank contains a mixture of 4 kg of He and...Ch. 13.3 - Prob. 97RPCh. 13.3 - Prob. 100RPCh. 13.3 - An ideal-gas mixture whose apparent molar mass is...Ch. 13.3 - 13–102 An ideal-gas mixture consists of 2 kmol of...Ch. 13.3 - An ideal-gas mixture consists of 2 kmol of N2and 4...Ch. 13.3 - Prob. 104FEPCh. 13.3 - Prob. 105FEPCh. 13.3 - An ideal-gas mixture consists of 3 kg of Ar and 6...Ch. 13.3 - Prob. 107FEPCh. 13.3 - Prob. 108FEPCh. 13.3 - Prob. 109FEPCh. 13.3 - Prob. 110FEP
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- Q4 Show that for a gas obeying van der Walls equation of state, 2a Cp – Cy = R + vTarrow_forwardA tank is filled with 2.5 kg water vapor at 150 bar and 350°C. Determine its volume (m3) using; Compressibility factor, Z from generalized compressibility chart steam table (can you provide the explanation too plz)arrow_forwardExplain the COMPRESSIBILITY FACTOR—A MEASURE OF DEVIATION FROM IDEAL-GAS BEHAVIORarrow_forward
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