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OWLv2 for Moore/Stanitski's Chemistry: The Molecular Science, 5th Edition, [Instant Access], 1 term (6 months)
5th Edition
ISBN: 9781285460420
Author: John W. Moore; Conrad L. Stanitski
Publisher: Cengage Learning US
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Chapter 13, Problem 85QRT
Interpretation Introduction
Interpretation:
The formation of silt at delta of rivers when the river meets seawater has to be explained.
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Students have asked these similar questions
Wintergreen from Aspirin:
1. In isolating the salicylic acid, why is it important to press out as much of the water as possible?
2. Write the mechanism of the esterification reaction you did.
3.
What characteristic absorption band changes would you expect in the IR spectrum on going from aspirin to salicyclic acid and
then to methyl salicylate as you did in the experiment today? Give approximate wavenumbers associated with each functional
group change.
What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What
other impurities are present in your product and how do you know?
Synthesis of ZybanⓇ:
1. Write a mechanism for the bromination of m-chloropropiophenone.
Br₂
CH2Cl2
Cl
Br
2. Give the expected m/z (to a round number) for the molecular ion from the product above (including isotopic peaks).
3. What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What
other impurities are present in your product and how do you know?
Synthesis of Ibuprofen-Part 2:
1. Some pain relievers including ibuprofen (MotrinⓇ) and naproxen (Aleve®) are "α-arylpropanoic acids." Look up the structure
of naproxen (AleveⓇ), another a-arylpropionic acid. Using the same reactions that we used for making ibuprofen, show how
to make naproxen from the compound below. Show all intermediates and reagents in your synthesis.
Show how you would prepare ibuprofen starting from p-isobutylbenzene rather than p-isobutylacetophenenone. What reaction
steps would need to change/add?
3. What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What
other impurities are present in your product and how do you know?
Chapter 13 Solutions
OWLv2 for Moore/Stanitski's Chemistry: The Molecular Science, 5th Edition, [Instant Access], 1 term (6 months)
Ch. 13.1 - How could the data in Table 13.2 be used to...Ch. 13.1 - Prob. 13.2CECh. 13.1 - Prob. 13.1PSPCh. 13.1 - Prob. 13.2PSPCh. 13.2 - Prob. 13.3ECh. 13.2 - Determine whether each of these masses of NH4Cl...Ch. 13.4 - Prob. 13.5CECh. 13.4 - Explain why water that has been used to cool a...Ch. 13.4 - If a substance has a positive enthalpy of...Ch. 13.5 - Suppose that a trout stream at 25 C is in...
Ch. 13.6 - Prob. 13.4PSPCh. 13.6 - Prob. 13.8ECh. 13.6 - Drinking water may contain small quantities of...Ch. 13.6 - Prob. 13.9CECh. 13.6 - A 500-mL bottle of Evian bottled water contains 12...Ch. 13.6 - The mass fraction of gold in seawater is 1 103...Ch. 13.6 - Prob. 13.6PSPCh. 13.6 - Prob. 13.7PSPCh. 13.6 - Prob. 13.8PSPCh. 13.6 - Prob. 13.9PSPCh. 13.6 - Prob. 13.12ECh. 13.6 - Prob. 13.13CECh. 13.7 - The vapor pressure of an aqueous solution of urea....Ch. 13.7 - Prob. 13.14ECh. 13.7 - Prob. 13.15ECh. 13.7 - Prob. 13.11PSPCh. 13.7 - Suppose that you are closing a cabin in the north...Ch. 13.7 - A student determines the freezing point to be 5.15...Ch. 13.7 - Prob. 13.17CECh. 13.7 - Prob. 13.13PSPCh. 13.9 - Prob. 13.18CECh. 13.10 - Prob. 13.19ECh. 13.10 - Prob. 13.20ECh. 13 - Prob. 1QRTCh. 13 - Prob. 2QRTCh. 13 - Prob. 3QRTCh. 13 - Prob. 4QRTCh. 13 - Prob. 5QRTCh. 13 - Prob. 6QRTCh. 13 - Prob. 7QRTCh. 13 - Prob. 8QRTCh. 13 - Prob. 9QRTCh. 13 - Prob. 10QRTCh. 13 - Prob. 11QRTCh. 13 - Prob. 12QRTCh. 13 - Prob. 13QRTCh. 13 - Prob. 14QRTCh. 13 - Beakers (a), (b), and (c) are representations of...Ch. 13 - Prob. 16QRTCh. 13 - Simple acids such as formic acid, HCOOH, and...Ch. 13 - Prob. 18QRTCh. 13 - Prob. 19QRTCh. 13 - Prob. 20QRTCh. 13 - Prob. 21QRTCh. 13 - Prob. 22QRTCh. 13 - Prob. 23QRTCh. 13 - Prob. 24QRTCh. 13 - Prob. 25QRTCh. 13 - Prob. 26QRTCh. 13 - Refer to Figure 13.10 ( Sec. 13-4b) to answer...Ch. 13 - Prob. 28QRTCh. 13 - Prob. 29QRTCh. 13 - Prob. 30QRTCh. 13 - The Henrys law constant for nitrogen in blood...Ch. 13 - Prob. 32QRTCh. 13 - Prob. 33QRTCh. 13 - Prob. 34QRTCh. 13 - Prob. 35QRTCh. 13 - Prob. 36QRTCh. 13 - Prob. 37QRTCh. 13 - Prob. 38QRTCh. 13 - Prob. 39QRTCh. 13 - Prob. 40QRTCh. 13 - A sample of water contains 0.010 ppm lead ions,...Ch. 13 - Prob. 42QRTCh. 13 - Prob. 43QRTCh. 13 - Prob. 44QRTCh. 13 - Prob. 45QRTCh. 13 - Prob. 46QRTCh. 13 - Prob. 47QRTCh. 13 - Prob. 48QRTCh. 13 - Prob. 49QRTCh. 13 - Prob. 50QRTCh. 13 - Consider a 13.0% solution of sulfuric acid,...Ch. 13 - You want to prepare a 1.0 mol/kg solution of...Ch. 13 - Prob. 53QRTCh. 13 - Prob. 54QRTCh. 13 - Prob. 55QRTCh. 13 - A 12-oz (355-mL) Pepsi contains 38.9 mg...Ch. 13 - Prob. 57QRTCh. 13 - Prob. 58QRTCh. 13 - Prob. 59QRTCh. 13 - Prob. 60QRTCh. 13 - Prob. 61QRTCh. 13 - Prob. 62QRTCh. 13 - Prob. 63QRTCh. 13 - Prob. 64QRTCh. 13 - Prob. 65QRTCh. 13 - Prob. 66QRTCh. 13 - Calculate the boiling point and the freezing point...Ch. 13 - Prob. 68QRTCh. 13 - Prob. 69QRTCh. 13 - Prob. 70QRTCh. 13 - Prob. 71QRTCh. 13 - Prob. 72QRTCh. 13 - The freezing point of p-dichlorobenzene is 53.1 C,...Ch. 13 - Prob. 74QRTCh. 13 - Prob. 75QRTCh. 13 - A 1.00 mol/kg aqueous sulfuric acid solution,...Ch. 13 - Prob. 77QRTCh. 13 - Prob. 78QRTCh. 13 - Prob. 79QRTCh. 13 - Prob. 80QRTCh. 13 - Prob. 81QRTCh. 13 - Differentiate between the dispersed phase and the...Ch. 13 - Prob. 83QRTCh. 13 - Prob. 84QRTCh. 13 - Prob. 85QRTCh. 13 - Prob. 86QRTCh. 13 - Prob. 87QRTCh. 13 - Prob. 88QRTCh. 13 - Prob. 89QRTCh. 13 - Prob. 90QRTCh. 13 - Prob. 91QRTCh. 13 - Prob. 92QRTCh. 13 - Prob. 93QRTCh. 13 - Prob. 94QRTCh. 13 - Prob. 95QRTCh. 13 - Prob. 96QRTCh. 13 - Prob. 97QRTCh. 13 - Prob. 98QRTCh. 13 - Prob. 99QRTCh. 13 - Prob. 100QRTCh. 13 - Prob. 101QRTCh. 13 - Prob. 102QRTCh. 13 - In The Rime of the Ancient Mariner the poet Samuel...Ch. 13 - Prob. 104QRTCh. 13 - Prob. 105QRTCh. 13 - Calculate the molality of a solution made by...Ch. 13 - Prob. 107QRTCh. 13 - Prob. 108QRTCh. 13 - Prob. 109QRTCh. 13 - Prob. 110QRTCh. 13 - The organic salt [(C4H9)4N][ClO4] consists of the...Ch. 13 - A solution, prepared by dissolving 9.41 g NaHSO3...Ch. 13 - A 0.250-M sodium sulfate solution is added to a...Ch. 13 - Prob. 114QRTCh. 13 - Prob. 115QRTCh. 13 - Prob. 116QRTCh. 13 - Prob. 117QRTCh. 13 - Prob. 118QRTCh. 13 - Prob. 119QRTCh. 13 - Refer to Figure 13.10 ( Sec. 13-4b) to determine...Ch. 13 - Prob. 121QRTCh. 13 - Prob. 122QRTCh. 13 - Prob. 123QRTCh. 13 - Prob. 124QRTCh. 13 - In your own words, explain why (a) seawater has a...Ch. 13 - Prob. 126QRTCh. 13 - Prob. 127QRTCh. 13 - Prob. 128QRTCh. 13 - Prob. 129QRTCh. 13 - Prob. 130QRTCh. 13 - Prob. 131QRTCh. 13 - A 0.109 mol/kg aqueous solution of formic...Ch. 13 - Prob. 133QRTCh. 13 - Maple syrup sap is 3% sugar (sucrose) and 97%...Ch. 13 - Prob. 137QRTCh. 13 - Prob. 13.ACPCh. 13 - Prob. 13.BCPCh. 13 - Prob. 13.CCP
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Solutions: Crash Course Chemistry #27; Author: Crash Course;https://www.youtube.com/watch?v=9h2f1Bjr0p4;License: Standard YouTube License, CC-BY