Introductory Chemistry: An Active Learning Approach
6th Edition
ISBN: 9781305079250
Author: Mark S. Cracolice, Ed Peters
Publisher: Cengage Learning
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Question
Chapter 13, Problem 71E
Interpretation Introduction
Interpretation:
A wedge-and-dash representation of
Concept Introduction:
The Lewis diagrams show the bonding between different atoms of a molecule and the lone pairs of electrons in the molecule. It shows how the valence electrons of an atom are arranged in the molecule. In Lewis diagram, two electrons are indicated as a line to show bonding between atoms.
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Part II. Given two isomers: 2-methylpentane (A) and 2,2-dimethyl butane (B) answer the following:
(a) match structures of isomers given their mass spectra below (spectra A and spectra B)
(b) Draw the fragments given the following prominent peaks from
each spectrum:
Spectra A m/2 =43 and 1/2-57
spectra B m/2 = 43
(c) why is 1/2=57 peak in spectrum A more intense compared
to the same peak in spectrum B.
Relative abundance
Relative abundance
100
A
50
29
29
0
10
-0
-0
100
B
50
720
30
41
43
57
71
4-0
40
50
60 70
m/z
43
57
8-0
m/z = 86
M
90 100
71
m/z = 86
M
-O
0
10 20 30
40 50
60
70
80
-88
m/z
90
100
Part IV. C6H5 CH2CH2OH is an aromatic compound which was subjected to Electron Ionization - mass
spectrometry (El-MS) analysis. Prominent m/2 values: m/2 = 104 and m/2 = 9) was obtained.
Draw the structures of these fragments.
For each reaction shown below follow the curved arrows to complete each equationby showing the structure of the products. Identify the acid, the base, the conjugated acid andconjugated base. Consutl the pKa table and choose the direciton theequilibrium goes. However show the curved arrows. Please explain if possible.
Chapter 13 Solutions
Introductory Chemistry: An Active Learning Approach
Ch. 13 - Draw the Lewis diagrams for each of the following...Ch. 13 - Prob. 2ECh. 13 - Prob. 3ECh. 13 - Prob. 4ECh. 13 - Draw the Lewis diagrams for each of the following...Ch. 13 - Prob. 6ECh. 13 - Draw the Lewis diagrams for each of the following...Ch. 13 - Prob. 8ECh. 13 - Prob. 9ECh. 13 - Prob. 10E
Ch. 13 - Prob. 11ECh. 13 - Prob. 12ECh. 13 - Prob. 13ECh. 13 - Prob. 14ECh. 13 - Prob. 15ECh. 13 - Prob. 16ECh. 13 - Prob. 17ECh. 13 - Prob. 18ECh. 13 - Prob. 19ECh. 13 - Prob. 20ECh. 13 - Prob. 21ECh. 13 - Prob. 22ECh. 13 - Prob. 23ECh. 13 - Prob. 24ECh. 13 - Prob. 25ECh. 13 - Prob. 26ECh. 13 - Prob. 27ECh. 13 - Prob. 28ECh. 13 - Prob. 29ECh. 13 - Prob. 30ECh. 13 - Prob. 31ECh. 13 - Prob. 32ECh. 13 - Prob. 33ECh. 13 - Prob. 34ECh. 13 - Prob. 35ECh. 13 - Prob. 36ECh. 13 - Prob. 37ECh. 13 - Prob. 38ECh. 13 - Prob. 39ECh. 13 - Prob. 40ECh. 13 - Prob. 41ECh. 13 - Prob. 42ECh. 13 - Prob. 43ECh. 13 - Prob. 44ECh. 13 - Is the carbon tetrachloride molecule, CCl4, which...Ch. 13 - Prob. 46ECh. 13 - Describe the shapes and compare the polarities of...Ch. 13 - Prob. 48ECh. 13 - Prob. 49ECh. 13 - Prob. 50ECh. 13 - Prob. 51ECh. 13 - Prob. 52ECh. 13 - Prob. 53ECh. 13 - Prob. 54ECh. 13 - Prob. 55ECh. 13 - Prob. 56ECh. 13 - Prob. 57ECh. 13 - Prob. 58ECh. 13 - Prob. 59ECh. 13 - Prob. 60ECh. 13 - Prob. 61ECh. 13 - Prob. 62ECh. 13 - Prob. 63ECh. 13 - Prob. 64ECh. 13 - Prob. 65ECh. 13 - Prob. 66ECh. 13 - Prob. 67ECh. 13 - Classify each of the following statements as true...Ch. 13 - Prob. 69ECh. 13 - Draw Lewis diagrams for these five acids of...Ch. 13 - Prob. 71ECh. 13 - Prob. 72ECh. 13 - Describe the shapes of C2H6 and C2H4. In doing so,...Ch. 13 - Prob. 74ECh. 13 - Prob. 75ECh. 13 - C4H10O is the formula of diethyl ether. The same...Ch. 13 - Prob. 77ECh. 13 - Prob. 78ECh. 13 - Draw Lewis diagrams for water and dihydrogen...Ch. 13 - Prob. 2PECh. 13 - Prob. 3PECh. 13 - Prob. 4PECh. 13 - Prob. 5PECh. 13 - What is the Lewis diagram of butane, C4H10?Ch. 13 - Prob. 7PECh. 13 - Prob. 8PECh. 13 - Prob. 9PECh. 13 - Prob. 10PECh. 13 - In the gas phase, tin (II) chloride is a...Ch. 13 - Prob. 12PECh. 13 - Determine the molecular geometry around each...Ch. 13 - Describe the molecular geometry around each carbon...Ch. 13 - Is the difluoromethane molecule polar or nonpolar?...Ch. 13 - Prob. 1LDRECh. 13 - Prob. 2LDRECh. 13 - Prob. 3LDRECh. 13 - Prob. 4LDRECh. 13 - Prob. 5LDRECh. 13 - Prob. 6LDRECh. 13 - Prob. 7LDRECh. 13 - Prob. 8LDRECh. 13 - Prob. 9LDRECh. 13 - Prob. 10LDRE
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