(a) Interpretation: The difference between central atom and terminal atom is to be stated. Concept introduction: Molecular geometry is the 3 − D representation of the molecule in a space. The Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Question

1. a) Assuming that an atom of arsenic has hydrogen-like atomic orbitals, sketch the radial probability plots for 4p and 4d orbitals of S atom. Indicate angular and radial nodes in these orbitals. (4 points) b) Calculate Zeff experienced by and electron in 4p AO's in a arsenic atom. Use Slater rules that were discussed in lecture. (3 points)

Answer 1

Question

Chapter 13, Problem 67E

Interpretation Introduction

(a)

Interpretation:

The difference between central atom and terminal atom is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. The Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Interpretation Introduction

(b)

Interpretation:

The difference between molecular geometry and electron pair geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. The Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Interpretation Introduction

(c)

Interpretation:

The difference between angular geometry and trigonal planar geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. The Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Interpretation Introduction

(d)

Interpretation:

The difference between trigonal planar geometry and trigonal pyramidal geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. As the Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Interpretation Introduction

(e)

Interpretation:

The difference between Trigonal planar geometry and tetrahedral geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. As the Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Interpretation Introduction

(f)

Interpretation:

The difference between Polar molecule and nonpolar molecule is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. As the Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

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1. a) Assuming that an atom of arsenic has hydrogen-like atomic orbitals, sketch the radial probability plots for 4p and 4d orbitals of S atom. Indicate angular and radial nodes in these orbitals. (4 points) b) Calculate Zeff experienced by and electron in 4p AO's in a arsenic atom. Use Slater rules that were discussed in lecture. (3 points)

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Answer 2

Question

Chapter 13, Problem 67E

Interpretation Introduction

(a)

Interpretation:

The difference between central atom and terminal atom is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. The Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Interpretation Introduction

(b)

Interpretation:

The difference between molecular geometry and electron pair geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. The Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Interpretation Introduction

(c)

Interpretation:

The difference between angular geometry and trigonal planar geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. The Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Interpretation Introduction

(d)

Interpretation:

The difference between trigonal planar geometry and trigonal pyramidal geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. As the Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Interpretation Introduction

(e)

Interpretation:

The difference between Trigonal planar geometry and tetrahedral geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. As the Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Interpretation Introduction

(f)

Interpretation:

The difference between Polar molecule and nonpolar molecule is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. As the Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

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Answer 3

Question

Chapter 13, Problem 67E

Interpretation Introduction

(a)

Interpretation:

The difference between central atom and terminal atom is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. The Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Interpretation Introduction

(b)

Interpretation:

The difference between molecular geometry and electron pair geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. The Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Interpretation Introduction

(c)

Interpretation:

The difference between angular geometry and trigonal planar geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. The Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Interpretation Introduction

(d)

Interpretation:

The difference between trigonal planar geometry and trigonal pyramidal geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. As the Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Interpretation Introduction

(e)

Interpretation:

The difference between Trigonal planar geometry and tetrahedral geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. As the Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Interpretation Introduction

(f)

Interpretation:

The difference between Polar molecule and nonpolar molecule is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. As the Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

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Answer 4

Question

Chapter 13, Problem 67E

Interpretation Introduction

(a)

Interpretation:

The difference between central atom and terminal atom is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. The Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Interpretation Introduction

(b)

Interpretation:

The difference between molecular geometry and electron pair geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. The Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Interpretation Introduction

(c)

Interpretation:

The difference between angular geometry and trigonal planar geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. The Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Interpretation Introduction

(d)

Interpretation:

The difference between trigonal planar geometry and trigonal pyramidal geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. As the Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Interpretation Introduction

(e)

Interpretation:

The difference between Trigonal planar geometry and tetrahedral geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. As the Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Interpretation Introduction

(f)

Interpretation:

The difference between Polar molecule and nonpolar molecule is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. As the Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

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Answer 5

Chapter 13, Problem 67E

Interpretation Introduction

(a)

Interpretation:

The difference between central atom and terminal atom is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. The Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Interpretation Introduction

(b)

Interpretation:

The difference between molecular geometry and electron pair geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. The Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Interpretation Introduction

(c)

Interpretation:

The difference between angular geometry and trigonal planar geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. The Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Interpretation Introduction

(d)

Interpretation:

The difference between trigonal planar geometry and trigonal pyramidal geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. As the Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Interpretation Introduction

(e)

Interpretation:

The difference between Trigonal planar geometry and tetrahedral geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. As the Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Interpretation Introduction

(f)

Interpretation:

The difference between Polar molecule and nonpolar molecule is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. As the Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Answer 6

Chapter 13, Problem 67E

Interpretation Introduction

(a)

Interpretation:

The difference between central atom and terminal atom is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. The Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Answer 7

Chapter 13, Problem 67E

Interpretation Introduction

(a)

Interpretation:

The difference between central atom and terminal atom is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. The Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The difference between molecular geometry and electron pair geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. The Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The difference between molecular geometry and electron pair geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. The Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The difference between angular geometry and trigonal planar geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. The Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The difference between angular geometry and trigonal planar geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. The Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Answer 12

Interpretation Introduction

(d)

Interpretation:

The difference between trigonal planar geometry and trigonal pyramidal geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. As the Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Answer 13

Interpretation Introduction

(d)

Interpretation:

The difference between trigonal planar geometry and trigonal pyramidal geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. As the Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Answer 14

Interpretation Introduction

(e)

Interpretation:

The difference between Trigonal planar geometry and tetrahedral geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. As the Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Answer 15

Interpretation Introduction

(e)

Interpretation:

The difference between Trigonal planar geometry and tetrahedral geometry is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. As the Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Answer 16

Interpretation Introduction

(f)

Interpretation:

The difference between Polar molecule and nonpolar molecule is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. As the Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Answer 17

Interpretation Introduction

(f)

Interpretation:

The difference between Polar molecule and nonpolar molecule is to be stated.

Concept introduction:

Molecular geometry is the 3−D representation of the molecule in a space. As the Lewis model is not able to explain the shape of the molecules. In terms of electron density, the bonding electrons as well as lone pair of electrons holds the shape of the molecule.

Answer 18

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Answer 29

Ch. 13 - Draw the Lewis diagrams for each of the following...Ch. 13 - Prob. 2E Ch. 13 - Prob. 3E Ch. 13 - Prob. 4E Ch. 13 - Draw the Lewis diagrams for each of the following...Ch. 13 - Prob. 6E Ch. 13 - Draw the Lewis diagrams for each of the following...Ch. 13 - Prob. 8E Ch. 13 - Prob. 9E Ch. 13 - Prob. 10E

Chapter 13 Solutions