Chemistry: Structure and Properties Custom Edition for Rutgers University General Chemistry
15th Edition
ISBN: 9781269935678
Author: Nivaldo J. Tro
Publisher: Pearson Education
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Chapter 13, Problem 47E
The unit cells for cesium chloride and barium(ll) chloride are shown here Show the ratio of cations to anions in each unit cell corresponds to the ratio of cations to anions in the formula of each compound
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Chapter 13 Solutions
Chemistry: Structure and Properties Custom Edition for Rutgers University General Chemistry
Ch. 13 - Determine what state this substance is in at 1 atm...Ch. 13 - Prob. 2SAQCh. 13 - Prob. 3SAQCh. 13 - Prob. 4SAQCh. 13 - Prob. 5SAQCh. 13 - Prob. 6SAQCh. 13 - Prob. 7SAQCh. 13 - Prob. 8SAQCh. 13 - Prob. 9SAQCh. 13 - Prob. 10SAQ
Ch. 13 - What is a phase diagram?Ch. 13 - Draw a generic phase diagram and label its...Ch. 13 - What is the significance of crossing a line in a...Ch. 13 - What is graphene? Why is graphene unique?Ch. 13 - Prob. 5ECh. 13 - What is a crystalline lattice? How is the lattice...Ch. 13 - Prob. 7ECh. 13 - Prob. 8ECh. 13 - What is the difference between hexagonal closest...Ch. 13 - What are the three basic types of solids and the...Ch. 13 - Prob. 11ECh. 13 - What kinds of forces hold each of the three basic...Ch. 13 - Prob. 13ECh. 13 - Prob. 14ECh. 13 - Prob. 15ECh. 13 - Prob. 16ECh. 13 - Prob. 17ECh. 13 - Prob. 18ECh. 13 - Prob. 19ECh. 13 - Consider the phase diagram for iodine shown here....Ch. 13 - Prob. 21ECh. 13 - Prob. 22ECh. 13 - Prob. 23ECh. 13 - Prob. 24ECh. 13 - Prob. 25ECh. 13 - An X-ray beam of unknown wavelength is diffracted...Ch. 13 - Prob. 27ECh. 13 - Determine the coordination number for each...Ch. 13 - Prob. 29ECh. 13 - Molybdenum crystallizes with the body-centred unit...Ch. 13 - Prob. 31ECh. 13 - An atom has a radius of 142 pm and crystallizes in...Ch. 13 - Rhodium has a density of 12.41 g / cm3 and...Ch. 13 - Barium has a density of 3.59 g/cm3 and...Ch. 13 - Prob. 35ECh. 13 - Palladium crystallizes with a face-centered cubic...Ch. 13 - Prob. 37ECh. 13 - Identify each solid as molecular, ionic, or...Ch. 13 - Which solid has the highest melting point? Why?...Ch. 13 - Which solid has the highest melting point? Why?...Ch. 13 - Which solid in each pair has the higher melting...Ch. 13 - Which solid in each pair has the higher melting...Ch. 13 - Prob. 43ECh. 13 - Prob. 44ECh. 13 - Prob. 45ECh. 13 - Prob. 46ECh. 13 - The unit cells for cesium chloride and barium(ll)...Ch. 13 - Prob. 48ECh. 13 - Prob. 49ECh. 13 - Prob. 50ECh. 13 - Prob. 51ECh. 13 - Prob. 52ECh. 13 - Prob. 53ECh. 13 - Prob. 54ECh. 13 - Prob. 55ECh. 13 - Prob. 56ECh. 13 - Prob. 57ECh. 13 - The density of an unknown metal is 12.3 g/cm3 and...Ch. 13 - Prob. 59ECh. 13 - Consider a planet where the pressure of the...Ch. 13 - An unknown metal is found to have a density of...Ch. 13 - Prob. 62ECh. 13 - Potassium chloride crystallizes in the rock salt...Ch. 13 - Calculate the fraction of empty space in cubic...Ch. 13 - Prob. 65ECh. 13 - Prob. 66ECh. 13 - Prob. 67E
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- If one edge of the silicon carbide unit cell is 436.0 pm, what is the calculated density of this compound? (a) 0.803 g/cm3 (b) 0311g/cm3 (c) 321 g/cm3arrow_forwardDescribe the unit cell of lithium (see Figure).arrow_forward• describe the arrangement of atoms in the common cubic crystal lattices and calculate the packing efficiency for a lattice.arrow_forward
- The unit cell of silicon carbide, SiC, is illustrated below. (a) In what type of unit cell are the (dark gray) C atoms arranged? (b) If one edge of the silicon carbide unit cell is 436.0 pm, what is the calculated density of this compound? A portion of the solid-state structure of silicon carbide.arrow_forwardThe density of polonium metal is 9.2 g/cm3. If the extended lattice of polonium exhibits a simple cubic unit cell, estimate the atomic radius of polonium.arrow_forwardThe coordination number of uniformly sized spheres in a cubic closest-packing (FCC) array is 12. Give the coordination number of each atom in (a) a simple cubic lattice. (b) a body-centered cubic lattice.arrow_forward
- The CsCl structure is a simple cubic array of chloride ions with a cesium ion at the center of each cubic array (see Exercise 69). Given that the density of cesium chloride is 3.97 g/cm3, and assuming that the chloride and cesium ions touch along the body diagonal of the cubic unit cell, calculate the distance between the centers of adjacent Cs+ and Cl ions in the solid. Compare this value with the expected distance based on the sizes of the ions. The ionic radius of Cs+ is 169 pm, and the ionic radius of Cl is 181 pm.arrow_forward(a) Determining an Atom Radius from Lattice Dimensions: Gold has a face-centered unit cell, and its density is 19.32 g/cm3. Calculate the radius of a gold atom. (b) The Structure of Solid Iron: Iron has a density of 7.8740 g/cm3, and the radius of an iron atom is 126 pm. Verify that solid iron has a body-centered cubic unit cell. (Be sure to note that the atoms in a body-centered cubic unit cell touch along the diagonal across the cell. They do not touch along the edges of the cell.) (Hint: The diagonal distance across the unit cell = edge 3.)arrow_forwardLithium hydride (LiH) has the sodium chloride structure, and the length of the edge of the unit cell is 4.086 108 cm. Calculate the density of this solid.arrow_forward
- The structures of some common crystalline substances are shown below. Show that the net composition of each unit cell corresponds to the correct formula of each substance.arrow_forwardCalculate the unit cell edge length of copper metal, which has an fcc arrangement. The radius of a copper atom is 126 pm.arrow_forwardCrystalline polonium has a primitive cubic unit cell, lithium has a body-centered cubic unit cell, and calcium has a face-centered cubic unit cell. How many Po atoms belong to one unit cell? How many Li atoms belong to one unit cell? How many Ca atoms belong to one unit cell? Draw each unit cell. Indicate on your drawing what fraction of each atom lies within the unit cell.arrow_forward
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