Using necessary organic or inorganic reagents, the synthesis of given compounds has to be indicated. Concept introduction: Anti-Markovnikov’s rule: Unsymmetrical alkene reacts with hydrogen halide, halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides .

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Answer 1

Question

Chapter 13, Problem 39P

(a)

Interpretation Introduction

Interpretation:

Using necessary organic or inorganic reagents, the synthesis of given compounds has to be indicated.

Concept introduction:

Anti-Markovnikov’s rule: Unsymmetrical alkene reacts with hydrogen halide, halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

(b)

Interpretation Introduction

Using necessary organic or inorganic reagents, the synthesis of given compounds has to be indicated.

Concept introduction:

Anti-Markovnikov’s rule: Unsymmetrical alkene reacts with hydrogen halide, halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

(c)

Interpretation Introduction

Interpretation:

Using necessary organic or inorganic reagents, the synthesis of given compounds has to be indicated.

Concept introduction:

Anti-Markovnikov’s rule: Unsymmetrical alkene reacts with hydrogen halide, halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

Dehydration reaction:

Removal of water molecule from the reaction when the alcohol is treated with strong acid like sulfuric acid and gives alkene.

The stability of carbocation is given below,

Tertiary carbocation is more stable than the secondary and primary.

(d)

Interpretation Introduction

Interpretation:

Using necessary organic or inorganic reagents, the synthesis of given compounds has to be indicated.

Concept introduction:

Alkenes undergoes bromination reaction using bromine which yields the dibromo compound, bromination takes place in the double bond of the alkenes.

Heck reaction:

The Heck reaction is a cross-coupling reaction of an alkyl halide with an alkene to make a substituted alkenes using palladium as a catalyst and a base.

Hydrogenation:

Alkenes undergoes hydrogenation using Pd/C and hydrogen will reduce alkene to alkane

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1 Please provide an efficient synthesis of the product below from the starting material. Use the starting material as the ONLY source of carbon atoms. Show the synthesis of each compound that would be used in the overall synthesis of the product. [This synthesis uses alkyne and alcohol chemistry.]

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d. Draw arrow-pushing mechanism for an enzymatic retro-aldol reaction of the following hexose. Use B: and/or HA as needed. OH OH سية HO OH OH

Answer 2

Question

Chapter 13, Problem 39P

(a)

Interpretation Introduction

Interpretation:

Using necessary organic or inorganic reagents, the synthesis of given compounds has to be indicated.

Concept introduction:

Anti-Markovnikov’s rule: Unsymmetrical alkene reacts with hydrogen halide, halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

(b)

Interpretation Introduction

Using necessary organic or inorganic reagents, the synthesis of given compounds has to be indicated.

Concept introduction:

Anti-Markovnikov’s rule: Unsymmetrical alkene reacts with hydrogen halide, halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

(c)

Interpretation Introduction

Interpretation:

Using necessary organic or inorganic reagents, the synthesis of given compounds has to be indicated.

Concept introduction:

Anti-Markovnikov’s rule: Unsymmetrical alkene reacts with hydrogen halide, halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

Dehydration reaction:

Removal of water molecule from the reaction when the alcohol is treated with strong acid like sulfuric acid and gives alkene.

The stability of carbocation is given below,

Tertiary carbocation is more stable than the secondary and primary.

(d)

Interpretation Introduction

Interpretation:

Using necessary organic or inorganic reagents, the synthesis of given compounds has to be indicated.

Concept introduction:

Alkenes undergoes bromination reaction using bromine which yields the dibromo compound, bromination takes place in the double bond of the alkenes.

Heck reaction:

The Heck reaction is a cross-coupling reaction of an alkyl halide with an alkene to make a substituted alkenes using palladium as a catalyst and a base.

Hydrogenation:

Alkenes undergoes hydrogenation using Pd/C and hydrogen will reduce alkene to alkane

Expert Solution & Answer

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Answer 3

Question

Chapter 13, Problem 39P

(a)

Interpretation Introduction

Interpretation:

Using necessary organic or inorganic reagents, the synthesis of given compounds has to be indicated.

Concept introduction:

Anti-Markovnikov’s rule: Unsymmetrical alkene reacts with hydrogen halide, halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

(b)

Interpretation Introduction

Using necessary organic or inorganic reagents, the synthesis of given compounds has to be indicated.

Concept introduction:

Anti-Markovnikov’s rule: Unsymmetrical alkene reacts with hydrogen halide, halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

(c)

Interpretation Introduction

Interpretation:

Using necessary organic or inorganic reagents, the synthesis of given compounds has to be indicated.

Concept introduction:

Anti-Markovnikov’s rule: Unsymmetrical alkene reacts with hydrogen halide, halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

Dehydration reaction:

Removal of water molecule from the reaction when the alcohol is treated with strong acid like sulfuric acid and gives alkene.

The stability of carbocation is given below,

Tertiary carbocation is more stable than the secondary and primary.

(d)

Interpretation Introduction

Interpretation:

Using necessary organic or inorganic reagents, the synthesis of given compounds has to be indicated.

Concept introduction:

Alkenes undergoes bromination reaction using bromine which yields the dibromo compound, bromination takes place in the double bond of the alkenes.

Heck reaction:

The Heck reaction is a cross-coupling reaction of an alkyl halide with an alkene to make a substituted alkenes using palladium as a catalyst and a base.

Hydrogenation:

Alkenes undergoes hydrogenation using Pd/C and hydrogen will reduce alkene to alkane

Expert Solution & Answer

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Answer 4

Question

Chapter 13, Problem 39P

(a)

Interpretation Introduction

Interpretation:

Using necessary organic or inorganic reagents, the synthesis of given compounds has to be indicated.

Concept introduction:

Anti-Markovnikov’s rule: Unsymmetrical alkene reacts with hydrogen halide, halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

(b)

Interpretation Introduction

Using necessary organic or inorganic reagents, the synthesis of given compounds has to be indicated.

Concept introduction:

Anti-Markovnikov’s rule: Unsymmetrical alkene reacts with hydrogen halide, halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

(c)

Interpretation Introduction

Interpretation:

Using necessary organic or inorganic reagents, the synthesis of given compounds has to be indicated.

Concept introduction:

Anti-Markovnikov’s rule: Unsymmetrical alkene reacts with hydrogen halide, halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

Dehydration reaction:

Removal of water molecule from the reaction when the alcohol is treated with strong acid like sulfuric acid and gives alkene.

The stability of carbocation is given below,

Tertiary carbocation is more stable than the secondary and primary.

(d)

Interpretation Introduction

Interpretation:

Using necessary organic or inorganic reagents, the synthesis of given compounds has to be indicated.

Concept introduction:

Alkenes undergoes bromination reaction using bromine which yields the dibromo compound, bromination takes place in the double bond of the alkenes.

Heck reaction:

The Heck reaction is a cross-coupling reaction of an alkyl halide with an alkene to make a substituted alkenes using palladium as a catalyst and a base.

Hydrogenation:

Alkenes undergoes hydrogenation using Pd/C and hydrogen will reduce alkene to alkane

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Answer 5

Chapter 13, Problem 39P

(a)

Interpretation Introduction

Interpretation:

Using necessary organic or inorganic reagents, the synthesis of given compounds has to be indicated.

Concept introduction:

Anti-Markovnikov’s rule: Unsymmetrical alkene reacts with hydrogen halide, halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

(b)

Interpretation Introduction

Using necessary organic or inorganic reagents, the synthesis of given compounds has to be indicated.

Concept introduction:

Anti-Markovnikov’s rule: Unsymmetrical alkene reacts with hydrogen halide, halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

(c)

Interpretation Introduction

Interpretation:

Using necessary organic or inorganic reagents, the synthesis of given compounds has to be indicated.

Concept introduction:

Anti-Markovnikov’s rule: Unsymmetrical alkene reacts with hydrogen halide, halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

Dehydration reaction:

Removal of water molecule from the reaction when the alcohol is treated with strong acid like sulfuric acid and gives alkene.

The stability of carbocation is given below,

Tertiary carbocation is more stable than the secondary and primary.

(d)

Interpretation Introduction

Interpretation:

Using necessary organic or inorganic reagents, the synthesis of given compounds has to be indicated.

Concept introduction:

Alkenes undergoes bromination reaction using bromine which yields the dibromo compound, bromination takes place in the double bond of the alkenes.

Heck reaction:

The Heck reaction is a cross-coupling reaction of an alkyl halide with an alkene to make a substituted alkenes using palladium as a catalyst and a base.

Hydrogenation:

Alkenes undergoes hydrogenation using Pd/C and hydrogen will reduce alkene to alkane

Answer 6

Chapter 13, Problem 39P

(a)

Interpretation Introduction

Interpretation:

Using necessary organic or inorganic reagents, the synthesis of given compounds has to be indicated.

Concept introduction:

Anti-Markovnikov’s rule: Unsymmetrical alkene reacts with hydrogen halide, halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

Answer 7

Chapter 13, Problem 39P

(a)

Interpretation Introduction

Interpretation:

Using necessary organic or inorganic reagents, the synthesis of given compounds has to be indicated.

Concept introduction:

Anti-Markovnikov’s rule: Unsymmetrical alkene reacts with hydrogen halide, halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

Answer 8

(b)

Interpretation Introduction

Using necessary organic or inorganic reagents, the synthesis of given compounds has to be indicated.

Concept introduction:

Anti-Markovnikov’s rule: Unsymmetrical alkene reacts with hydrogen halide, halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

Answer 9

(b)

Interpretation Introduction

Using necessary organic or inorganic reagents, the synthesis of given compounds has to be indicated.

Concept introduction:

Anti-Markovnikov’s rule: Unsymmetrical alkene reacts with hydrogen halide, halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

Answer 10

(c)

Interpretation Introduction

Interpretation:

Using necessary organic or inorganic reagents, the synthesis of given compounds has to be indicated.

Concept introduction:

Anti-Markovnikov’s rule: Unsymmetrical alkene reacts with hydrogen halide, halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

Dehydration reaction:

Removal of water molecule from the reaction when the alcohol is treated with strong acid like sulfuric acid and gives alkene.

The stability of carbocation is given below,

Tertiary carbocation is more stable than the secondary and primary.

Answer 11

(c)

Interpretation Introduction

Interpretation:

Using necessary organic or inorganic reagents, the synthesis of given compounds has to be indicated.

Concept introduction:

Anti-Markovnikov’s rule: Unsymmetrical alkene reacts with hydrogen halide, halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

Dehydration reaction:

Removal of water molecule from the reaction when the alcohol is treated with strong acid like sulfuric acid and gives alkene.

The stability of carbocation is given below,

Tertiary carbocation is more stable than the secondary and primary.

Answer 12

(d)

Interpretation Introduction

Interpretation:

Using necessary organic or inorganic reagents, the synthesis of given compounds has to be indicated.

Concept introduction:

Alkenes undergoes bromination reaction using bromine which yields the dibromo compound, bromination takes place in the double bond of the alkenes.

Heck reaction:

The Heck reaction is a cross-coupling reaction of an alkyl halide with an alkene to make a substituted alkenes using palladium as a catalyst and a base.

Hydrogenation:

Alkenes undergoes hydrogenation using Pd/C and hydrogen will reduce alkene to alkane

Answer 13

(d)

Interpretation Introduction

Interpretation:

Using necessary organic or inorganic reagents, the synthesis of given compounds has to be indicated.

Concept introduction:

Alkenes undergoes bromination reaction using bromine which yields the dibromo compound, bromination takes place in the double bond of the alkenes.

Heck reaction:

The Heck reaction is a cross-coupling reaction of an alkyl halide with an alkene to make a substituted alkenes using palladium as a catalyst and a base.

Hydrogenation:

Alkenes undergoes hydrogenation using Pd/C and hydrogen will reduce alkene to alkane

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 13.2 - Prob. 1P Ch. 13.2 - Write the steps for formation of...Ch. 13.3 - Prob. 3P Ch. 13.4 - Prob. 4P Ch. 13.5 - Prob. 7P Ch. 13.5 - a. Would chlorination or bromination produce a...Ch. 13.5 - Prob. 10P Ch. 13.6 - Prob. 11P Ch. 13.7 - Prob. 12P Ch. 13.7 - Prob. 13P

Solution Summary: The author explains Anti-Markovnikov's rule: Unsymmetrical alkene reacts with hydrogen halide, h2 ions go to the less substitution position of carbon-carbon double bond which provides al

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