Organic Chemistry
Organic Chemistry
7th Edition
ISBN: 9780321803221
Author: Paula Y. Bruice
Publisher: Prentice Hall
Question
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Chapter 13, Problem 27P

(a)

Interpretation Introduction

Interpretation:

The major product obtained by the reaction of excess of given compound with Cl2 in presence of ultraviolet light should be identified.

Concept introduction:

Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.

Bond strength is depends on the formation of the radical, if the radical is involving in resonance which is weakest bond strength.

Chlorination:

Organic Chemistry, Chapter 13, Problem 27P , additional homework tip  1

2-methylpropane undergoes radical chlorination and yields the 2-chloro-2-methylpropane and 1-chloro-2-methyl propane.

(b)

Interpretation Introduction

Interpretation:

The major product obtained by the reaction of excess of given compound with Cl2 in presence of ultraviolet light should be identified.

Concept introduction:

Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.

Bond strength is depends on the formation of the radical, if the radical is involving in resonance which is weakest bond strength.

Chlorination:

Organic Chemistry, Chapter 13, Problem 27P , additional homework tip  2

2-methylpropane undergoes radical chlorination and yields the 2-chloro-2-methylpropane and 1-chloro-2-methylpropane.

(c)

Interpretation Introduction

Interpretation:

The major product obtained by the reaction of excess of given compound with Cl2 in presence of ultraviolet light should be identified.

Concept introduction:

Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.

Bond strength is depends on the formation of the radical, if the radical is involving in resonance which is weakest bond strength.

Chlorination:

Organic Chemistry, Chapter 13, Problem 27P , additional homework tip  3

2-methylpropane undergoes radical chlorination and yields the 2-chloro-2-methylpropane and 1-chloro-2-methylpropane.

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