
Organic Chemistry
7th Edition
ISBN: 9780321803221
Author: Paula Y. Bruice
Publisher: Prentice Hall
expand_more
expand_more
format_list_bulleted
Concept explainers
Question
Chapter 13, Problem 45P
Interpretation Introduction
Interpretation:
The reason should be explained why the reaction does not following the given mechanism.
Concept introduction:
Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.
Bond strength is depends on the formation of the radical, if the radical is involving in resonance which is weakest bond strength.
Propagation: In this stage, two steps are involving hydrogen abstraction and halogen abstraction (no change in the number of free radicals).
Expert Solution & Answer

Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
Draw product B, indicating what type of reaction occurs.
F3C
CF3
NH2
Me O
.N.
+
B
OMe
Benzimidazole E. State its formula. sState the differences in the formula with other benzimidazoles.
Draw product A, indicating what type of reaction occurs.
F3C
CN
CF3
K2CO3, DMSO, H₂O2
A
Chapter 13 Solutions
Organic Chemistry
Ch. 13.2 - Prob. 1PCh. 13.2 - Write the steps for formation of...Ch. 13.3 - Prob. 3PCh. 13.4 - Prob. 4PCh. 13.5 - Prob. 7PCh. 13.5 - a. Would chlorination or bromination produce a...Ch. 13.5 - Prob. 10PCh. 13.6 - Prob. 11PCh. 13.7 - Prob. 12PCh. 13.7 - Prob. 13P
Ch. 13.8 - Prob. 14PCh. 13.8 - Draw the stereoisomers of the major...Ch. 13.9 - a. How many stereoisomers are formed from the...Ch. 13.9 - Prob. 17PCh. 13.9 - Prob. 19PCh. 13.9 - Prob. 20PCh. 13.9 - Prob. 21PCh. 13.10 - Prob. 22PCh. 13.11 - How many atoms share the unpaired electrons in...Ch. 13.11 - Prob. 24PCh. 13 - Prob. 25PCh. 13 - Prob. 26PCh. 13 - Prob. 27PCh. 13 - Prob. 28PCh. 13 - Prob. 29PCh. 13 - Prob. 30PCh. 13 - Prob. 31PCh. 13 - Prob. 32PCh. 13 - Prob. 33PCh. 13 - Prob. 34PCh. 13 - Prob. 35PCh. 13 - Starting with cyclohexane, how could the following...Ch. 13 - a. Propose a mechanism for the following reaction:...Ch. 13 - What stereoisomers are obtained from the following...Ch. 13 - Prob. 39PCh. 13 - Prob. 40PCh. 13 - Prob. 41PCh. 13 - Draw the products of the following reactions,...Ch. 13 - a. What five-carbon alkene forms the same product...Ch. 13 - Prob. 44PCh. 13 - Prob. 45PCh. 13 - Prob. 46PCh. 13 - Explain why the rate of bromination of methane...Ch. 13 - Prob. 48P
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- 19) Which metal is most commonly used in galvanization to protect steel structures from oxidation? Lead a. b. Tin C. Nickel d. Zinc 20) The following molecule is an example of a: R₁ R2- -N-R3 a. Secondary amine b. Secondary amide c. Tertiary amine d. Tertiary amidearrow_forwardpls helparrow_forwardIndicate the product of the reaction OH OH CH3-CC- Ph + H2SO4 a 20°C | CH3 Pharrow_forward
- 35) Complete the following equation by drawing the line the structure of the products that are formed. Please note that in some cases more than one product is possible. You must draw all possible products to recive full marks! a. ethanol + 2-propanol + H2SO4 → b. OH conc. H2SO4 CH2 H3C CH + K2Cr2O7 C. d. H3C A pressure CH3 + H2 CH Pt catalystarrow_forward21) The rate of reaction depends upon: a. the concentration and nature of reactants b. the temperature of the reaction C. whether or not a catalyst was used d. all of the above 22) A Maxwell-Boltzmann curve shows the distribution of molecular energies in a reaction system. When the temperature in this system is increased, the peak is a. higher and further to the right. b. higher and further to the left. c. lower and further to the right. d. lower and further to the left. 23) Which of the following correctly describes the reaction represented by the reaction below? CaCO3 (s) + energy → CaO (s) + CO2 (g) a. It is exothermic and the potential energy is greater in the reactants than the products. b. c. It is exothermic and the potential energy is greater in the products than the reactants. It is endothermic and the potential energy is greater in the products than the reactants. d. It is endothermic and the potential energy is equal for the products and reactants.arrow_forwardpls helparrow_forward
- 27) Draw the energy level diagram and write the full and shorthand electron configuration for a neutral sulfur atom.arrow_forwardIndicate whether these compounds are isomers, enantiomers, or tautomers. OCH OCH محمد ممدarrow_forward30) Substance A to E below are listed with several of their properties. The identities of the substances are identified in random order below: Iron, ethane, ethanol, sodium nitrate, graphite First classify each substance as either a polar covalent compound, non-polar covalent compound, ionic compound, metallic solid, or network solid. Write your predictions in the sixth coloumn of the chart, under "type of substance." Then, identify the identity of the substance in the last coloumn. Substance Melting Point Boiling Point Solubility in H₂O Electrical Conductivity Type of Substance Identity of Substance (°C) (°C) as: Solid, Liquids, Solution A -182 -88 Insoluble No/No/- B 1538 2862 Insoluble Yes/Yes/- C 308 380 Soluble Yes/Yes/Yes Ꭰ 3456 Insoluble No/-/- E -114 78 Soluble No/No/Noarrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill EducationPrinciples of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
- Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill EducationChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningElementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY

Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning

Chemistry
Chemistry
ISBN:9781259911156
Author:Raymond Chang Dr., Jason Overby Professor
Publisher:McGraw-Hill Education

Principles of Instrumental Analysis
Chemistry
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Cengage Learning

Organic Chemistry
Chemistry
ISBN:9780078021558
Author:Janice Gorzynski Smith Dr.
Publisher:McGraw-Hill Education

Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning

Elementary Principles of Chemical Processes, Bind...
Chemistry
ISBN:9781118431221
Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:WILEY
Enzymes - Effect of cofactors on enzyme; Author: Tutorials Point (India) Ltd;https://www.youtube.com/watch?v=AkAbIwxyUs4;License: Standard YouTube License, CC-BY
Enzyme Catalysis Part-I; Author: NPTEL-NOC IITM;https://www.youtube.com/watch?v=aZE740JWZuQ;License: Standard Youtube License