Chemistry In Context
9th Edition
ISBN: 9781259638145
Author: Fahlman, Bradley D., Purvis-roberts, Kathleen, Kirk, John S., Bentley, Anne K., Daubenmire, Patrick L., ELLIS, Jamie P., Mury, Michael T., American Chemical Society
Publisher: Mcgraw-hill Education,
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Chapter 13, Problem 23Q
Interpretation Introduction
Interpretation: Using Figure 13.7, why adenine-thymine base pairs are less stable than cytosine-guanine base pairs should be explained.
Concept Introduction:
The four major nitrogen-containing bases are:
Adenine:
It is represented with the letter “A”
Guanine:
It is represented with the letter “G”.
Thymine:
It is represented with the letter “T”.
Cytosine:
It is represented with the letter “C”.
Complementary bases:
- • Adenine is the complementary base of Thymine.
- • Cytosine is the complementary base of Guanine.
- • In DNA, Adenine always makes a double bond with thymine (
Hydrogen bonding between complementary bases:
The bases of
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b.
CH3
H3C
CH3
CH3
H3C
an unexpected product,
containing a single 9-
membered ring
the expected product,
containing two fused rings
H3C-I
(H3C)2CuLi
an enolate
b.
H3C
CH3
1.
2. H3O+
H3C
MgBr
H3C
Predict the major products of this reaction:
excess
H+
NaOH
?
A
Note that the first reactant is used in excess, that is, there is much more of the first reactant than the second.
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structure.
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Chapter 13 Solutions
Chemistry In Context
Ch. 13.2 - Skill Building Small, but Important Differences...Ch. 13.2 - Prob. 13.2YTCh. 13.2 - Prob. 13.3YTCh. 13.2 - Prob. 13.4YTCh. 13.3 - Skill Building Complementary Base Sequences...Ch. 13.3 - Prob. 13.6YTCh. 13.3 - Prob. 13.7YTCh. 13.3 - Prob. 13.8YTCh. 13.4 - Prob. 13.9YTCh. 13.4 - Prob. 13.10YT
Ch. 13.5 - Scientific Practices How Is Hamburger Like Nylon?...Ch. 13.5 - Prob. 13.12YTCh. 13.5 - Scientific Practices Function Follows Form In...Ch. 13.6 - Prob. 13.14YTCh. 13 - The theme of this chapter is that DNA guides the...Ch. 13 - Prob. 2QCh. 13 - Prob. 3QCh. 13 - Consider the structural formulas in Figure 13.1....Ch. 13 - Prob. 5QCh. 13 - Prob. 6QCh. 13 - Prob. 7QCh. 13 - Prob. 8QCh. 13 - Prob. 9QCh. 13 - a. What does each letter in DNA stand for? b....Ch. 13 - Here is the structural formula for the base...Ch. 13 - Prob. 12QCh. 13 - Prob. 13QCh. 13 - Prob. 14QCh. 13 - Prob. 15QCh. 13 - Polar amino acids can be classified as acidic,...Ch. 13 - Prob. 17QCh. 13 - Prob. 18QCh. 13 - Explain one similarity and one difference between...Ch. 13 - Prob. 20QCh. 13 - Diagram the steps to produce insulin from a cow or...Ch. 13 - Prob. 22QCh. 13 - Prob. 23QCh. 13 - Prob. 24QCh. 13 - Prob. 25QCh. 13 - Prob. 26QCh. 13 - Prob. 27QCh. 13 - Prob. 28QCh. 13 - Almost all organisms use the same four bases and...Ch. 13 - Prob. 30QCh. 13 - Consider the idea of mixing genes as an...Ch. 13 - Prob. 32QCh. 13 - Prob. 33QCh. 13 - Prob. 34QCh. 13 - List two advantages and two disadvantages of...Ch. 13 - Prob. 37QCh. 13 - Prob. 38QCh. 13 - Prob. 39QCh. 13 - Recently developed techniques have dramatically...Ch. 13 - Find a transgenic organism not discussed in the...Ch. 13 - You are the head of a government facing another...
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