Chemistry In Context
9th Edition
ISBN: 9781259638145
Author: Fahlman, Bradley D., Purvis-roberts, Kathleen, Kirk, John S., Bentley, Anne K., Daubenmire, Patrick L., ELLIS, Jamie P., Mury, Michael T., American Chemical Society
Publisher: Mcgraw-hill Education,
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Chapter 13, Problem 26Q
Interpretation Introduction
Interpretation:
The reason for why a double-strand break in a DNA double helix cannot be repaired by a cell has to be explained.
Concept Introduction:
DNA and its nitrogen bases:
- • DNA is the abbreviation term of “Deoxyribonucleic Acid”. It is a complex molecule found in all living things.
- • The primary function of DNA is to store and transmit genetic information.
- • A base is nitrogen containing heterocyclic compound which is found in DNA
- • There are mainly four nitrogen bases in DNA which are listed as follows:
- 1. Adenine
- 2. Guanine
- 3. Cytosine
- 4. Thymine
Complementary bases:
- • Adenine is the complementary base of Thymine
- • Cytosine is the complementary base of Guanine.
- • In DNA, Adenine always makes a double bond with thymine (
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Part V. Label ad match the carbons in compounds Jane and Diane
w/ the corresponding peak no.
in the
Spectra (Note: use the given peak no. To label the carbons, other peak
no are intentionally
omitted)
7 4 2
-0.13
-0.12
-0.11
-0.10
-0.08
8
CI
Jane
1
-0.09
5
210
200
190
180
170
160
150
140
130
120
110
100
-8
90
f1 (ppm)
11
8
172.4
172.0
f1 (ppr
HO
CI
NH
Diane
7
3
11
80
80
-80
-R
70
60
60
2
5
-8
50
40
8.
170
160
150
140
130
120
110
100
90
-0
80
70
20
f1 (ppm)
15
30
-20
20
-60
60
-0.07
-0.06
-0.05
-0.04
-0.03
-0.02
-0.01
-0.00
-0.01
10
-0.17
16
15
56
16
-0.16
-0.15
-0.14
-0.13
-0.12
-0.11
-0.10
-0.09
-0.08
-0.07
-0.06
-0.05
-0.04
17.8 17.6 17.4 17.2 17.0
f1 (ppm)
-0.03
-0.02
550
106
40
30
20
20
-0.01
-0.00
F-0.01
10
0
Chapter 13 Solutions
Chemistry In Context
Ch. 13.2 - Skill Building Small, but Important Differences...Ch. 13.2 - Prob. 13.2YTCh. 13.2 - Prob. 13.3YTCh. 13.2 - Prob. 13.4YTCh. 13.3 - Skill Building Complementary Base Sequences...Ch. 13.3 - Prob. 13.6YTCh. 13.3 - Prob. 13.7YTCh. 13.3 - Prob. 13.8YTCh. 13.4 - Prob. 13.9YTCh. 13.4 - Prob. 13.10YT
Ch. 13.5 - Scientific Practices How Is Hamburger Like Nylon?...Ch. 13.5 - Prob. 13.12YTCh. 13.5 - Scientific Practices Function Follows Form In...Ch. 13.6 - Prob. 13.14YTCh. 13 - The theme of this chapter is that DNA guides the...Ch. 13 - Prob. 2QCh. 13 - Prob. 3QCh. 13 - Consider the structural formulas in Figure 13.1....Ch. 13 - Prob. 5QCh. 13 - Prob. 6QCh. 13 - Prob. 7QCh. 13 - Prob. 8QCh. 13 - Prob. 9QCh. 13 - a. What does each letter in DNA stand for? b....Ch. 13 - Here is the structural formula for the base...Ch. 13 - Prob. 12QCh. 13 - Prob. 13QCh. 13 - Prob. 14QCh. 13 - Prob. 15QCh. 13 - Polar amino acids can be classified as acidic,...Ch. 13 - Prob. 17QCh. 13 - Prob. 18QCh. 13 - Explain one similarity and one difference between...Ch. 13 - Prob. 20QCh. 13 - Diagram the steps to produce insulin from a cow or...Ch. 13 - Prob. 22QCh. 13 - Prob. 23QCh. 13 - Prob. 24QCh. 13 - Prob. 25QCh. 13 - Prob. 26QCh. 13 - Prob. 27QCh. 13 - Prob. 28QCh. 13 - Almost all organisms use the same four bases and...Ch. 13 - Prob. 30QCh. 13 - Consider the idea of mixing genes as an...Ch. 13 - Prob. 32QCh. 13 - Prob. 33QCh. 13 - Prob. 34QCh. 13 - List two advantages and two disadvantages of...Ch. 13 - Prob. 37QCh. 13 - Prob. 38QCh. 13 - Prob. 39QCh. 13 - Recently developed techniques have dramatically...Ch. 13 - Find a transgenic organism not discussed in the...Ch. 13 - You are the head of a government facing another...
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- n Feb 3 A T + 4. (2 pts) Draw the structure of the major component of the Limonene isolated. Explain how you confirmed the structure. 5. (2 pts) Draw the fragment corresponding to the base peak in the Mass spectrum of Limonene. 6. (1 pts) Predict the 1H NMR spectral data of R-Limonene. Proton NMR: 5.3 pon multiplet (H Ringarrow_forwardPart VI. Ca H 10 O is the molecular formula of compound Tom and gives the in the table below. Give a possible structure for compound Tom. 13C Signals summarized C1 C2 C3 C4 C5 C6 C7 13C shift (ppm) 23.5 27.0 33.0 35.8 127 162 205 DEPT-90 + DEPT-135 + +arrow_forward2. Using the following data to calculate the value of AvapH o of water at 298K. AvapH o of water at 373K is 40.7 kJ/mol; molar heat capacity of liquid water at constant pressure is 75.2J mol-1 K-1 and molar heat capacity of water vapor at constant pressure is 33.6 J mol-1 K-1.arrow_forward
- Part VII. Below are the 'HNMR 13 3 C-NMR, COSY 2D- NMR, and HSQC 20-NMR (Similar with HETCOR but axes are reversed) spectra of an organic compound with molecular formula C6H13 O. Assign chemical shift values to the H and c atoms of the compound. Find the structure. Show complete solutions. Predicted 1H NMR Spectrum ли 4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1 1.0 0.9 0.8 f1 (ppm)arrow_forward3. Draw the expanded structural formula, the condensed structural formula, and the skeletal structural formula for 2-pentene. expanded structure: Condensed structure: Skeletal formula: 4. Draw the expanded structural formula, the condensed structural formula, and the skeletal structural formula for 2-methyl-3-heptene. expanded structure: Condensed structure: Skeletal formula: following structurearrow_forwardPart IV. Propose a plausible Structure w/ the following descriptions: a) A 5-carbon hydrocarbon w/ a single peak in its proton decoupled the DEPT-135 Spectrum shows a negative peak C-NMR spectrum where b) what cyclohexane dione isomer gives the largest no. Of 13C NMR signals? c) C5H120 (5-carbon alcohol) w/ most deshielded carbon absent in any of its DEPT Spectivaarrow_forward
- 13C NMR is good for: a) determining the molecular weight of the compound b) identifying certain functional groups. c) determining the carbon skeleton, for example methyl vs ethyl vs propyl groups d) determining how many different kinds of carbon are in the moleculearrow_forward6 D 2. (1 pt) Limonene can be isolated by performing steam distillation of orange peel. Could you have performed this experiment using hexane instead of water? Explain. 3. (2 pts) Using GCMS results, analyze and discuss the purity of the Limonene obtained from the steam distillation of orange peel.arrow_forwardPart III. Arrange the following carbons (in blue) in order of increasing chemical shift. HO B NH 2 A CIarrow_forward
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