Organic Chemistry
Organic Chemistry
12th Edition
ISBN: 9781118875766
Author: T. W. Graham Solomons, Craig B. Fryhle, Scott A. Snyder
Publisher: WILEY
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Chapter 13, Problem 18P
Interpretation Introduction

Interpretation:

The reagents required for the given reactants to produce 1,3-butadiene are to be determined.

Concept introduction:

Alkyl halides undergo E2 elimination when reacted with a strong base and a strong nucleophile, like tertiary alkoxides.

Alcohols heated in the presence of mineral acids undergo elimination reaction and form alkanes.

Primary alcohols undergo E2 elimination with concentrated sulfuric acid H2SO4 to form alkenes.

H2SO4 is a dehydrating agent.

Nickel boride Ni2B (P-2) is an effective reducing catalyst sensitive to steric factors and also, a mild reducing agent which converts alkynes to alkenes.

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Write structural formulas for the products that form when 1-butene reacts with each of the following reagents: (a) HI (b) H2, Pt (c) Dilute H2SO4, warm (d) Cold concentrated H2SO4 (e) Cold concentrated H2SO4, then H2O and heat (f) HBr (g) Br2 in CCl4 (h) Br2 in H2O (i) HCl (j) O3, then Me2S (k) OsO4, then NaHSO3/H2O (l) KMnO4, OH-, heat, then H3O+ (m) Hg(OAc)2 in THF and H2O, then NaBH4, OH- (n) BH3:THF, then H2O2, OH-
6) Which is the organic product for the following reaction? (a) (b) (c) (d) LOH OH COOH OH OH COOH COOH KMnO4 H₂O (e) None of the above products will be formed
Starting from bromoethane, the formation of which of the following compound requires more than one step of reaction? 2 (a) Methoxyethane (b) Ethanol (c) Ethanoic acid (d) Ethene

Chapter 13 Solutions

Organic Chemistry

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