Chemical Principles
8th Edition
ISBN: 9781305581982
Author: Steven S. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Chapter 13, Problem 14E
Interpretation Introduction
Interpretation: The given electrostatic potential diagrams needs to be matched with correct molecules.
Concept Introduction: The given molecule is said to be polar if the bond between the two atoms has unequal electron distribution. If the two atoms bonded together have difference in their electronegativity, the more electronegative atom attracts the shared pair of electron/s towards itself and become negatively charged while the comparatively less electronegative or electropositive atom becomes positively charged.
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Experiment:
Each team will be provided with 5g of a mixture of acetanilide and salicylic acid. You will divide it into three 1.5 g portions in separate 125 mL Erlenmeyer flasks savıng some for melting point analysis. Dissolve the mixture in each flask in ~60mL of DI water by heating to boiling on a hotplate. Take the flasks off the hotplate once you have a clear solution and let them stand on the bench top for 5 mins and then allow them to cool as described below.
Sample A-Let the first sample cool slowly to room temperature by letting it stand on your lab bench, with occasional stirring to promote crystallization.
Sample B-Cool the second sample 1n a tap-water bath to 10-15 °C
Sample C-Cool the third sample in an ice-bath to 0-2 °C
Results:
weight after recrystalization and melting point temp.
A=0.624g,102-115°
B=0.765g, 80-105°
C=1.135g, 77-108
What is the percent yield of A,B, and C.
Chapter 13 Solutions
Chemical Principles
Ch. 13 - Explain the electronegativity trends across a row...Ch. 13 - Prob. 2DQCh. 13 - Prob. 3DQCh. 13 - Prob. 4DQCh. 13 - Prob. 5DQCh. 13 - Prob. 6DQCh. 13 - Prob. 7DQCh. 13 - Prob. 8DQCh. 13 - Prob. 9DQCh. 13 - Arrange the following molecules from most to least...
Ch. 13 - Prob. 11DQCh. 13 - Prob. 12DQCh. 13 - Prob. 13ECh. 13 - Prob. 14ECh. 13 - An alternative definition of electronegativity...Ch. 13 - Prob. 16ECh. 13 - Without using Fig. 13.3, predict the order of...Ch. 13 - Without using Fig. 13.3, predict which bond in...Ch. 13 - Prob. 19ECh. 13 - Prob. 20ECh. 13 - Indicate the bond polarity (show the partial...Ch. 13 - Prob. 22ECh. 13 - Prob. 23ECh. 13 - Prob. 24ECh. 13 - Prob. 25ECh. 13 - Prob. 26ECh. 13 - Prob. 27ECh. 13 - Prob. 28ECh. 13 - Prob. 29ECh. 13 - Prob. 30ECh. 13 - Prob. 31ECh. 13 - Give an example of an ionic compound where both...Ch. 13 - What noble gas has the same electron configuration...Ch. 13 - Which of the following ions have noble gas...Ch. 13 - Give three ions that are isoelectronic with...Ch. 13 - Prob. 36ECh. 13 - Predict the empirical formulas of the ionic...Ch. 13 - Which compound in each of the following pairs of...Ch. 13 - Use the following data to estimate Hf for...Ch. 13 - Use the following data to estimate Hf for...Ch. 13 - Consider the following:...Ch. 13 - In general, the higher the charge on the ions in...Ch. 13 - Consider the following energy changes: a....Ch. 13 - Prob. 44ECh. 13 - Prob. 45ECh. 13 - The lattice energies of FeCl3,FeCl2,andFe2O3 are...Ch. 13 - Prob. 47ECh. 13 - Prob. 48ECh. 13 - Prob. 49ECh. 13 - Prob. 50ECh. 13 - Prob. 51ECh. 13 - Prob. 52ECh. 13 - Prob. 53ECh. 13 - Prob. 54ECh. 13 - Prob. 55ECh. 13 - Prob. 56ECh. 13 - Prob. 57ECh. 13 - Prob. 58ECh. 13 - Prob. 59ECh. 13 - Prob. 60ECh. 13 - Prob. 61ECh. 13 - Prob. 62ECh. 13 - Prob. 63ECh. 13 - Prob. 64ECh. 13 - Prob. 65ECh. 13 - Prob. 66ECh. 13 - Prob. 67ECh. 13 - Prob. 68ECh. 13 - Prob. 69ECh. 13 - Prob. 70ECh. 13 - Prob. 71ECh. 13 - Prob. 72ECh. 13 - Prob. 73ECh. 13 - Prob. 74ECh. 13 - Prob. 75ECh. 13 - Prob. 76ECh. 13 - Prob. 77ECh. 13 - Prob. 78ECh. 13 - Prob. 79ECh. 13 - Prob. 80ECh. 13 - Prob. 81ECh. 13 - Prob. 82ECh. 13 - Prob. 83ECh. 13 - Prob. 84ECh. 13 - Prob. 85ECh. 13 - Prob. 86ECh. 13 - Prob. 87ECh. 13 - Prob. 88ECh. 13 - Prob. 89ECh. 13 - Prob. 90ECh. 13 - Prob. 91ECh. 13 - Prob. 92ECh. 13 - Prob. 93ECh. 13 - Prob. 94ECh. 13 - Prob. 95ECh. 13 - Predict the molecular structure and the bond...Ch. 13 - Prob. 97ECh. 13 - Two variations of the octahedral geometry are...Ch. 13 - Prob. 99ECh. 13 - Predict the molecular structure and the bond...Ch. 13 - Which of the molecules in Exercise 96 have net...Ch. 13 - Prob. 102ECh. 13 - Give two requirements that should be satisfied for...Ch. 13 - What do each of the following sets of...Ch. 13 - Prob. 105ECh. 13 - Consider the following Lewis structure, where E is...Ch. 13 - Consider the following Lewis structure, where E is...Ch. 13 - Prob. 108ECh. 13 - Prob. 109ECh. 13 - Which of the following molecules have net dipole...Ch. 13 - Prob. 111AECh. 13 - Prob. 112AECh. 13 - Prob. 113AECh. 13 - Prob. 114AECh. 13 - Prob. 115AECh. 13 - There are two possible structures of XeF2Cl2 ,...Ch. 13 - Prob. 117AECh. 13 - Prob. 118AECh. 13 - Prob. 119AECh. 13 - Prob. 120AECh. 13 - Prob. 121AECh. 13 - Prob. 122AECh. 13 - Prob. 123AECh. 13 - Prob. 124AECh. 13 - Prob. 125AECh. 13 - Prob. 126AECh. 13 - Prob. 127AECh. 13 - Prob. 128AECh. 13 - Prob. 129AECh. 13 - Prob. 130AECh. 13 - Prob. 131AECh. 13 - Prob. 132AECh. 13 - Prob. 133CPCh. 13 - Prob. 134CPCh. 13 - Given the following information: Heat of...Ch. 13 - Prob. 136CPCh. 13 - A promising new material with great potential as...Ch. 13 - Think of forming an ionic compound as three steps...Ch. 13 - Prob. 139CPCh. 13 - Prob. 140CPCh. 13 - Calculate the standard heat of formation of the...Ch. 13 - Prob. 142CPCh. 13 - Prob. 143MP
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