Concept explainers
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(a)
Interpretation:
Whether hydration of propene will give one or two products has to be identified based on Markovnikov’s rule.
Concept Introduction:
In this reaction no atoms or group of atoms are removed. Instead the unsaturated bond is reduced to saturated bond. A general scheme for addition reaction of
Addition reactions can be classified broadly into two types. They are asymmetrical addition reaction and symmetrical addition reaction.
Symmetrical addition reactions is the one in which the same atom or same group of atoms are added across the carbon‑carbon multiple bonds.
Unsymmetrical addition reactions is the one in which the different atom or different group of atoms are added across the carbon‑carbon multiple bonds.
Markovnikov’s rule:
When an unsymmetrical molecule of formula HQ to an unsymmeterical alkene, the hydrogen atom from HQ gets attached to the unsaturated carbon atom which has the most hydrogen atoms. In other words, it can be said that the hydrogen atom gets attached to the unsaturated carbon atom that is least substituted.
(b)
Interpretation:
Whether hydration of 3-hexene will give one or two products has to be identified based on Markovnikov’s rule.
Concept Introduction:
Chemical reaction in which an atom or a group of atoms are added to each carbon atom of a carbon‑carbon multiple bond in a hydrocarbon or hydrocarbon derivative is known as addition reaction.
In this reaction no atoms or group of atoms are removed. Instead the unsaturated bond is reduced to saturated bond. A general scheme for addition reaction of alkene can be given as shown below,
Addition reactions can be classified broadly into two types. They are asymmetrical addition reaction and symmetrical addition reaction.
Symmetrical addition reactions is the one in which the same atom or same group of atoms are added across the carbon‑carbon multiple bonds.
Unsymmetrical addition reactions is the one in which the different atom or different group of atoms are added across the carbon‑carbon multiple bonds.
Markovnikov’s rule:
When an unsymmetrical molecule of formula HQ to an unsymmeterical alkene, the hydrogen atom from HQ gets attached to the unsaturated carbon atom which has the most hydrogen atoms. In other words, it can be said that the hydrogen atom gets attached to the unsaturated carbon atom that is least substituted.
(c)
Interpretation:
Whether hydration of cyclopropene will give one or two products has to be identified based on Markovnikov’s rule.
Concept Introduction:
Chemical reaction in which an atom or a group of atoms are added to each carbon atom of a carbon‑carbon multiple bond in a hydrocarbon or hydrocarbon derivative is known as addition reaction.
In this reaction no atoms or group of atoms are removed. Instead the unsaturated bond is reduced to saturated bond. A general scheme for addition reaction of alkene can be given as shown below,
Addition reactions can be classified broadly into two types. They are asymmetrical addition reaction and symmetrical addition reaction.
Symmetrical addition reactions is the one in which the same atom or same group of atoms are added across the carbon‑carbon multiple bonds.
Unsymmetrical addition reactions is the one in which the different atom or different group of atoms are added across the carbon‑carbon multiple bonds.
Markovnikov’s rule:
When an unsymmetrical molecule of formula HQ to an unsymmeterical alkene, the hydrogen atom from HQ gets attached to the unsaturated carbon atom which has the most hydrogen atoms. In other words, it can be said that the hydrogen atom gets attached to the unsaturated carbon atom that is least substituted.
(d)
Interpretation:
Whether hydration of cyclopentene will give one or two products has to be identified based on Markovnikov’s rule.
Concept Introduction:
Chemical reaction in which an atom or a group of atoms are added to each carbon atom of a carbon‑carbon multiple bond in a hydrocarbon or hydrocarbon derivative is known as addition reaction.
In this reaction no atoms or group of atoms are removed. Instead the unsaturated bond is reduced to saturated bond. A general scheme for addition reaction of alkene can be given as shown below,
Addition reactions can be classified broadly into two types. They are asymmetrical addition reaction and symmetrical addition reaction.
Symmetrical addition reactions is the one in which the same atom or same group of atoms are added across the carbon‑carbon multiple bonds.
Unsymmetrical addition reactions is the one in which the different atom or different group of atoms are added across the carbon‑carbon multiple bonds.
Markovnikov’s rule:
When an unsymmetrical molecule of formula HQ to an unsymmeterical alkene, the hydrogen atom from HQ gets attached to the unsaturated carbon atom which has the most hydrogen atoms. In other words, it can be said that the hydrogen atom gets attached to the unsaturated carbon atom that is least substituted.
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Chapter 13 Solutions
Study Guide with Selected Solutions for Stoker's General, Organic, and Biological Chemistry, 7th
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- Predict the products of this organic reaction: OH + NaOH A? Specifically, in the drawing area below draw the skeletal ("line") structure of the product, or products, of this reaction. (If there's more than one product, draw them in any arrangement you like, so long as they aren't touching.) If there aren't any products because this reaction won't happen, check the No reaction box under the drawing area. No reaction Click and drag to start drawing a structure. ✓ Sarrow_forwardPredict the products of this organic reaction: CH3-C-O-CH2-CH2-C-CH3 + H₂O ? A Specifically, in the drawing area below draw the condensed structure of the product, or products, of this reaction. (If there's more than one product, draw them in any arrangement you like, so long as they aren't touching.) If there aren't any products because this reaction won't happen, check the No reaction box under the drawing area. No reaction Click anywhere to draw the first atom of your structure. :☐ darrow_forwardDE d. Draw an arrow pushing mechanism for the following IN O CI N fo 人 P Polle DELL prt sc home end ins F5 F6 F7 F8 F9 F10 F11 F12arrow_forward
- Predict the products of this organic reaction: + H₂O H* ? A Specifically, in the drawing area below draw the skeletal ("line") structure of the product, or products, of this reaction. (If there's more than one product, draw them in any arrangement you like, so long as they aren't touching.) If there aren't any products because this reaction won't happen, check the No reaction box under the drawing area. No Reaction Click and drag to start drawing a structure.arrow_forwardPredict the major organic products of the reaction below and draw them on right side of the arrow. If there will be no significant reaction, check the box below the drawing area instead. C Cl CH, OH There will be no significant reaction. + pyridine G Click and drag to start drawing a structure.arrow_forwardWhat is the missing reactant in this organic reaction? H R+ H2O Δ OH 0= CH3-CH-O-CH3 + CH3-C-OH Specifically, in the drawing area below draw the condensed structure of R. If there is more than one reasonable answer, you can draw any one of them. If there is no reasonable answer, check the No answer box under the drawing area. No Answer Click anywhere to draw the first atom of your structure. dyarrow_forward
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