Study Guide with Selected Solutions for Stoker's General, Organic, and Biological Chemistry, 7th
7th Edition
ISBN: 9781305081086
Author: STOKER, H. Stephen
Publisher: Brooks Cole
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Question
Chapter 13, Problem 13.18EP
(a)
Interpretation Introduction
Interpretation:
IUPAC name for the given
Concept Introduction:
- The suffix –ane has to be replaced with the suffix –ene. This is used to indicate the presence of double bond.
- The longest continuous chain of carbon atoms has to be chosen that contains both carbon atoms of the double bond.
- The parent carbon chain has to be numbered in a way so that the numbering begins at the end near to the double bond. In case if the double bond is equidistant from both ends, then numbering has to be done from the end that is closer to substituents.
- The position of the double bond has to be given a single number which is lower‑numbered carbon atom that is present in the double bond.
- Suffixes like –diene, -triene, -tetrene, and so on are used when the compound contains more than one double bond.
- In case of cycloalkenes which do not have any substitution, the numbering is not needed to locate the double bond because the bond is assumed to be between the carbons 1 and 2.
- In case if substituents are present in cycloalkene, then the double‑bonded carbon
atoms are numbered 1 and 2 in a direction where the substituent gets the lower number. - If the cycloalkenes contain more than one double bond, then one double bond is assigned the numbers 1 and 2 followed by the other double bond so that the lowest number possible is given.
(b)
Interpretation Introduction
Interpretation:
IUPAC name for the given unsaturated hydrocarbon has to be assigned.
Concept Introduction:
IUPAC nomenclature for alkene: There are about eight rules to be followed in giving IUPAC name for alkene.
- The suffix –ane has to be replaced with the suffix –ene. This is used to indicate the presence of double bond.
- The longest continuous chain of carbon atoms has to be chosen that contains both carbon atoms of the double bond.
- The parent carbon chain has to be numbered in a way so that the numbering begins at the end near to the double bond. In case if the double bond is equidistant from both ends, then numbering has to be done from the end that is closer to substituents.
- The position of the double bond has to be given a single number which is lower‑numbered carbon atom that is present in the double bond.
- Suffixes like –diene, -triene, -tetrene, and so on are used when the compound contains more than one double bond.
- In case of cycloalkenes which do not have any substitution, the numbering is not needed to locate the double bond because the bond is assumed to be between the carbons 1 and 2.
- In case if substituents are present in cycloalkene, then the double‑bonded carbon atoms are numbered 1 and 2 in a direction where the substituent gets the lower number.
- If the cycloalkenes contain more than one double bond, then one double bond is assigned the numbers 1 and 2 followed by the other double bond so that the lowest number possible is given.
(c)
Interpretation Introduction
Interpretation:
IUPAC name for the given unsaturated hydrocarbon has to be assigned.
Concept Introduction:
IUPAC nomenclature for alkene: There are about eight rules to be followed in giving IUPAC name for alkene.
- The suffix –ane has to be replaced with the suffix –ene. This is used to indicate the presence of double bond.
- The longest continuous chain of carbon atoms has to be chosen that contains both carbon atoms of the double bond.
- The parent carbon chain has to be numbered in a way so that the numbering begins at the end near to the double bond. In case if the double bond is equidistant from both ends, then numbering has to be done from the end that is closer to substituents.
- The position of the double bond has to be given a single number which is lower‑numbered carbon atom that is present in the double bond.
- Suffixes like –diene, -triene, -tetrene, and so on are used when the compound contains more than one double bond.
- In case of cycloalkenes which do not have any substitution, the numbering is not needed to locate the double bond because the bond is assumed to be between the carbons 1 and 2.
- In case if substituents are present in cycloalkene, then the double‑bonded carbon atoms are numbered 1 and 2 in a direction where the substituent gets the lower number.
- If the cycloalkenes contain more than one double bond, then one double bond is assigned the numbers 1 and 2 followed by the other double bond so that the lowest number possible is given.
(d)
Interpretation Introduction
Interpretation:
IUPAC name for the given unsaturated hydrocarbon has to be assigned.
Concept Introduction:
IUPAC nomenclature for alkene: There are about eight rules to be followed in giving IUPAC name for alkenes.
- The suffix –ane has to be replaced with the suffix –ene. This is used to indicate the presence of double bond.
- The longest continuous chain of carbon atoms has to be chosen that contains both carbon atoms of the double bond.
- The parent carbon chain has to be numbered in a way so that the numbering begins at the end near to the double bond. In case if the double bond is equidistant from both ends, then numbering has to be done from the end that is closer to substituents.
- The position of the double bond has to be given a single number which is lower‑numbered carbon atom that is present in the double bond.
- Suffixes like –diene, -triene, -tetrene, and so on are used when the compound contains more than one double bond.
- In case of cycloalkenes which do not have any substitution, the numbering is not needed to locate the double bond because the bond is assumed to be between the carbons 1 and 2.
- In case if substituents are present in cycloalkene, then the double‑bonded carbon atoms are numbered 1 and 2 in a direction where the substituent gets the lower number.
- If the cycloalkenes contain more than one double bond, then one double bond is assigned the numbers 1 and 2 followed by the other double bond so that the lowest number possible is given.
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Chapter 13 Solutions
Study Guide with Selected Solutions for Stoker's General, Organic, and Biological Chemistry, 7th
Ch. 13.1 - Prob. 1QQCh. 13.1 - Prob. 2QQCh. 13.1 - Prob. 3QQCh. 13.2 - Prob. 1QQCh. 13.2 - Prob. 2QQCh. 13.2 - Prob. 3QQCh. 13.2 - Prob. 4QQCh. 13.3 - Prob. 1QQCh. 13.3 - Prob. 2QQCh. 13.3 - Prob. 3QQ
Ch. 13.3 - Prob. 4QQCh. 13.4 - Prob. 1QQCh. 13.4 - Prob. 2QQCh. 13.5 - Prob. 1QQCh. 13.5 - Prob. 2QQCh. 13.5 - Prob. 3QQCh. 13.6 - Prob. 1QQCh. 13.6 - Prob. 2QQCh. 13.6 - Prob. 3QQCh. 13.7 - Prob. 1QQCh. 13.7 - Prob. 2QQCh. 13.7 - Prob. 3QQCh. 13.8 - Prob. 1QQCh. 13.8 - Prob. 2QQCh. 13.9 - Prob. 1QQCh. 13.9 - Prob. 2QQCh. 13.10 - Prob. 1QQCh. 13.10 - Prob. 2QQCh. 13.10 - Prob. 3QQCh. 13.10 - Prob. 4QQCh. 13.10 - Prob. 5QQCh. 13.11 - Prob. 1QQCh. 13.11 - Prob. 2QQCh. 13.11 - Prob. 3QQCh. 13.11 - Prob. 4QQCh. 13.11 - Prob. 5QQCh. 13.12 - Prob. 1QQCh. 13.12 - Prob. 2QQCh. 13.12 - Prob. 3QQCh. 13.12 - Prob. 4QQCh. 13.12 - Prob. 5QQCh. 13.13 - Prob. 1QQCh. 13.13 - Prob. 2QQCh. 13.13 - Prob. 3QQCh. 13.14 - Prob. 1QQCh. 13.14 - Prob. 2QQCh. 13.14 - Prob. 3QQCh. 13.14 - Prob. 4QQCh. 13.15 - Prob. 1QQCh. 13.15 - Prob. 2QQCh. 13.15 - Prob. 3QQCh. 13.15 - Prob. 4QQCh. 13.16 - Prob. 1QQCh. 13.16 - Prob. 2QQCh. 13 - Classify each of the following hydrocarbons as...Ch. 13 - Classify each of the following hydrocarbons as...Ch. 13 - Prob. 13.3EPCh. 13 - Prob. 13.4EPCh. 13 - Prob. 13.5EPCh. 13 - Prob. 13.6EPCh. 13 - Prob. 13.7EPCh. 13 - Prob. 13.8EPCh. 13 - Prob. 13.9EPCh. 13 - What is the molecular formula for each of the...Ch. 13 - Prob. 13.11EPCh. 13 - Prob. 13.12EPCh. 13 - What is wrong, if anything, with the following...Ch. 13 - Prob. 13.14EPCh. 13 - Prob. 13.15EPCh. 13 - Prob. 13.16EPCh. 13 - Prob. 13.17EPCh. 13 - Prob. 13.18EPCh. 13 - Draw a condensed structural formula for each of...Ch. 13 - Draw a condensed structural formula for each of...Ch. 13 - The following names are incorrect by IUPAC rules....Ch. 13 - The following names are incorrect by IUPAC rules....Ch. 13 - Prob. 13.23EPCh. 13 - Prob. 13.24EPCh. 13 - Prob. 13.25EPCh. 13 - Classify each of the following compounds as...Ch. 13 - Prob. 13.27EPCh. 13 - How many hydrogen atoms are present in a molecule...Ch. 13 - Prob. 13.29EPCh. 13 - Draw a line-angle structural formula for each of...Ch. 13 - Prob. 13.31EPCh. 13 - Prob. 13.32EPCh. 13 - Prob. 13.33EPCh. 13 - Prob. 13.34EPCh. 13 - Prob. 13.35EPCh. 13 - Prob. 13.36EPCh. 13 - Prob. 13.37EPCh. 13 - Prob. 13.38EPCh. 13 - For each of the following pairs of alkenes,...Ch. 13 - Prob. 13.40EPCh. 13 - Prob. 13.41EPCh. 13 - Prob. 13.42EPCh. 13 - Prob. 13.43EPCh. 13 - Prob. 13.44EPCh. 13 - Prob. 13.45EPCh. 13 - Prob. 13.46EPCh. 13 - For each molecule, indicate whether cistrans...Ch. 13 - For each molecule, indicate whether cistrans...Ch. 13 - Prob. 13.49EPCh. 13 - Prob. 13.50EPCh. 13 - Prob. 13.51EPCh. 13 - Draw a structural formula for each of the...Ch. 13 - Prob. 13.53EPCh. 13 - Prob. 13.54EPCh. 13 - Prob. 13.55EPCh. 13 - Prob. 13.56EPCh. 13 - Prob. 13.57EPCh. 13 - Prob. 13.58EPCh. 13 - Why is the number of carbon atoms in a terpene...Ch. 13 - How many isoprene units are present in a....Ch. 13 - Prob. 13.61EPCh. 13 - Indicate whether each of the following statements...Ch. 13 - Prob. 13.63EPCh. 13 - With the help of Figure 13-7, indicate whether...Ch. 13 - Prob. 13.65EPCh. 13 - Prob. 13.66EPCh. 13 - Prob. 13.67EPCh. 13 - Prob. 13.68EPCh. 13 - Prob. 13.69EPCh. 13 - Prob. 13.70EPCh. 13 - Prob. 13.71EPCh. 13 - Prob. 13.72EPCh. 13 - Prob. 13.73EPCh. 13 - Prob. 13.74EPCh. 13 - Prob. 13.75EPCh. 13 - Write a chemical equation showing reactants,...Ch. 13 - Supply the structural formula of the product in...Ch. 13 - Prob. 13.78EPCh. 13 - What reactant would you use to prepare each of the...Ch. 13 - Prob. 13.80EPCh. 13 - Prob. 13.81EPCh. 13 - Prob. 13.82EPCh. 13 - Prob. 13.83EPCh. 13 - Prob. 13.84EPCh. 13 - Prob. 13.85EPCh. 13 - Prob. 13.86EPCh. 13 - Prob. 13.87EPCh. 13 - Prob. 13.88EPCh. 13 - Prob. 13.89EPCh. 13 - Prob. 13.90EPCh. 13 - Prob. 13.91EPCh. 13 - Prob. 13.92EPCh. 13 - Prob. 13.93EPCh. 13 - What are the bond angles about the triple bond in...Ch. 13 - Prob. 13.95EPCh. 13 - Prob. 13.96EPCh. 13 - Prob. 13.97EPCh. 13 - Prob. 13.98EPCh. 13 - Prob. 13.99EPCh. 13 - Prob. 13.100EPCh. 13 - Prob. 13.101EPCh. 13 - Prob. 13.102EPCh. 13 - Prob. 13.103EPCh. 13 - Prob. 13.104EPCh. 13 - Prob. 13.105EPCh. 13 - Prob. 13.106EPCh. 13 - Prob. 13.107EPCh. 13 - Prob. 13.108EPCh. 13 - Assign each of the compounds in Problem 13-107 an...Ch. 13 - Assign each of the compounds in Problem 13-108 an...Ch. 13 - Prob. 13.111EPCh. 13 - Prob. 13.112EPCh. 13 - Prob. 13.113EPCh. 13 - Prob. 13.114EPCh. 13 - Prob. 13.115EPCh. 13 - Write a structural formula for each of the...Ch. 13 - Eight isomeric substituted benzenes have the...Ch. 13 - Prob. 13.118EPCh. 13 - Prob. 13.119EPCh. 13 - Prob. 13.120EPCh. 13 - Prob. 13.121EPCh. 13 - Prob. 13.122EPCh. 13 - Prob. 13.123EPCh. 13 - Prob. 13.124EPCh. 13 - Prob. 13.125EPCh. 13 - For each of the following classes of compounds,...Ch. 13 - Prob. 13.127EPCh. 13 - Prob. 13.128EPCh. 13 - Prob. 13.129EPCh. 13 - Prob. 13.130EP
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