Alkanes are more susceptible for addition reaction or substitution reaction has to be indicated. Concept Introduction: Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula. Alkanes are hydrocarbons that contain only single bonds between the carbon atoms. Therefore, there is no possibility of addition reaction. Alkanes undergo only substitution reactions. Alkenes and cycloalkenes are hydrocarbons that contain at least one double bond in its structure. Addition reaction can take place across the double bond. Aromatic compounds undergo substitution reactions rather than addition reactions even though they contain double bonds. This is because the double bonds are involved in delocalization.

Question

Name the molecules & Identify any chiral center CH3CH2CH2CHCH₂CH₂CH₂CH₂ OH CH₂CHCH2CH3 Br CH3 CH3CHCH2CHCH2CH3 CH3

Answer 1

Question

Definition Definition Molecules that have multiple bonds between their carbon atoms. Alkenes are hydrocarbons with a double bond between two adjacent carbon atoms (R 2 C=CR 2 ), whereas alkynes are hydrocarbons with a triple bond between two adjacent carbon atoms R-C=C-R . These two groups are known as unsaturated hydrocarbons. They have fewer hydrogen atoms when compared with alkanes with same number of carbon atoms. The general molecular formula for an unsaturated hydrocarbon can be represented as C n H 2n +2 .

Chapter 13, Problem 13.125EP

(a)

Interpretation Introduction

Interpretation:

Alkanes are more susceptible for addition reaction or substitution reaction has to be indicated.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Alkanes are hydrocarbons that contain only single bonds between the carbon atoms. Therefore, there is no possibility of addition reaction. Alkanes undergo only substitution reactions. Alkenes and cycloalkenes are hydrocarbons that contain at least one double bond in its structure. Addition reaction can take place across the double bond. Aromatic compounds undergo substitution reactions rather than addition reactions even though they contain double bonds. This is because the double bonds are involved in delocalization.

(b)

Interpretation Introduction

Interpretation:

Dienes are more susceptible for addition reaction or substitution reaction has to be indicated.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Alkanes are hydrocarbons that contain only single bonds between the carbon atoms. Therefore, there is no possibility of addition reaction. Alkanes undergo only substitution reactions. Alkenes and cycloalkenes are hydrocarbons that contain at least one double bond in its structure. Addition reaction can take place across the double bond. Aromatic compounds undergo substitution reactions rather than addition reactions even though they contain double bonds. This is because the double bonds are involved in delocalization.

(c)

Interpretation Introduction

Interpretation:

Alkylbenzenes are more susceptible for addition reaction or substitution reaction has to be indicated.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Alkanes are hydrocarbons that contain only single bonds between the carbon atoms. Therefore, there is no possibility of addition reaction. Alkanes undergo only substitution reactions. Alkenes and cycloalkenes are hydrocarbons that contain at least one double bond in its structure. Addition reaction can take place across the double bond. Aromatic compounds undergo substitution reactions rather than addition reactions even though they contain double bonds. This is because the double bonds are involved in delocalization.

(d)

Interpretation Introduction

Interpretation:

Cycloalkenes are more susceptible for addition reaction or substitution reaction has to be indicated.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Alkanes are hydrocarbons that contain only single bonds between the carbon atoms. Therefore, there is no possibility of addition reaction. Alkanes undergo only substitution reactions. Alkenes and cycloalkenes are hydrocarbons that contain at least one double bond in its structure. Addition reaction can take place across the double bond. Aromatic compounds undergo substitution reactions rather than addition reactions even though they contain double bonds. This is because the double bonds are involved in delocalization.

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Name the molecules & Identify any chiral center CH3CH2CH2CHCH₂CH₂CH₂CH₂ OH CH₂CHCH2CH3 Br CH3 CH3CHCH2CHCH2CH3 CH3

Curved arrows are used to illustrate the flow of electrons. Using the provided starting and product structures, draw the curved electrons-pushing arrows for the following reaction or mechanistic step(s).

Answer 2

Question

Definition Definition Molecules that have multiple bonds between their carbon atoms. Alkenes are hydrocarbons with a double bond between two adjacent carbon atoms (R 2 C=CR 2 ), whereas alkynes are hydrocarbons with a triple bond between two adjacent carbon atoms R-C=C-R . These two groups are known as unsaturated hydrocarbons. They have fewer hydrogen atoms when compared with alkanes with same number of carbon atoms. The general molecular formula for an unsaturated hydrocarbon can be represented as C n H 2n +2 .

Chapter 13, Problem 13.125EP

(a)

Interpretation Introduction

Interpretation:

Alkanes are more susceptible for addition reaction or substitution reaction has to be indicated.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Alkanes are hydrocarbons that contain only single bonds between the carbon atoms. Therefore, there is no possibility of addition reaction. Alkanes undergo only substitution reactions. Alkenes and cycloalkenes are hydrocarbons that contain at least one double bond in its structure. Addition reaction can take place across the double bond. Aromatic compounds undergo substitution reactions rather than addition reactions even though they contain double bonds. This is because the double bonds are involved in delocalization.

(b)

Interpretation Introduction

Interpretation:

Dienes are more susceptible for addition reaction or substitution reaction has to be indicated.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Alkanes are hydrocarbons that contain only single bonds between the carbon atoms. Therefore, there is no possibility of addition reaction. Alkanes undergo only substitution reactions. Alkenes and cycloalkenes are hydrocarbons that contain at least one double bond in its structure. Addition reaction can take place across the double bond. Aromatic compounds undergo substitution reactions rather than addition reactions even though they contain double bonds. This is because the double bonds are involved in delocalization.

(c)

Interpretation Introduction

Interpretation:

Alkylbenzenes are more susceptible for addition reaction or substitution reaction has to be indicated.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Alkanes are hydrocarbons that contain only single bonds between the carbon atoms. Therefore, there is no possibility of addition reaction. Alkanes undergo only substitution reactions. Alkenes and cycloalkenes are hydrocarbons that contain at least one double bond in its structure. Addition reaction can take place across the double bond. Aromatic compounds undergo substitution reactions rather than addition reactions even though they contain double bonds. This is because the double bonds are involved in delocalization.

(d)

Interpretation Introduction

Interpretation:

Cycloalkenes are more susceptible for addition reaction or substitution reaction has to be indicated.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Alkanes are hydrocarbons that contain only single bonds between the carbon atoms. Therefore, there is no possibility of addition reaction. Alkanes undergo only substitution reactions. Alkenes and cycloalkenes are hydrocarbons that contain at least one double bond in its structure. Addition reaction can take place across the double bond. Aromatic compounds undergo substitution reactions rather than addition reactions even though they contain double bonds. This is because the double bonds are involved in delocalization.

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Answer 3

Question

Definition Definition Molecules that have multiple bonds between their carbon atoms. Alkenes are hydrocarbons with a double bond between two adjacent carbon atoms (R 2 C=CR 2 ), whereas alkynes are hydrocarbons with a triple bond between two adjacent carbon atoms R-C=C-R . These two groups are known as unsaturated hydrocarbons. They have fewer hydrogen atoms when compared with alkanes with same number of carbon atoms. The general molecular formula for an unsaturated hydrocarbon can be represented as C n H 2n +2 .

Chapter 13, Problem 13.125EP

(a)

Interpretation Introduction

Interpretation:

Alkanes are more susceptible for addition reaction or substitution reaction has to be indicated.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Alkanes are hydrocarbons that contain only single bonds between the carbon atoms. Therefore, there is no possibility of addition reaction. Alkanes undergo only substitution reactions. Alkenes and cycloalkenes are hydrocarbons that contain at least one double bond in its structure. Addition reaction can take place across the double bond. Aromatic compounds undergo substitution reactions rather than addition reactions even though they contain double bonds. This is because the double bonds are involved in delocalization.

(b)

Interpretation Introduction

Interpretation:

Dienes are more susceptible for addition reaction or substitution reaction has to be indicated.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Alkanes are hydrocarbons that contain only single bonds between the carbon atoms. Therefore, there is no possibility of addition reaction. Alkanes undergo only substitution reactions. Alkenes and cycloalkenes are hydrocarbons that contain at least one double bond in its structure. Addition reaction can take place across the double bond. Aromatic compounds undergo substitution reactions rather than addition reactions even though they contain double bonds. This is because the double bonds are involved in delocalization.

(c)

Interpretation Introduction

Interpretation:

Alkylbenzenes are more susceptible for addition reaction or substitution reaction has to be indicated.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Alkanes are hydrocarbons that contain only single bonds between the carbon atoms. Therefore, there is no possibility of addition reaction. Alkanes undergo only substitution reactions. Alkenes and cycloalkenes are hydrocarbons that contain at least one double bond in its structure. Addition reaction can take place across the double bond. Aromatic compounds undergo substitution reactions rather than addition reactions even though they contain double bonds. This is because the double bonds are involved in delocalization.

(d)

Interpretation Introduction

Interpretation:

Cycloalkenes are more susceptible for addition reaction or substitution reaction has to be indicated.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Alkanes are hydrocarbons that contain only single bonds between the carbon atoms. Therefore, there is no possibility of addition reaction. Alkanes undergo only substitution reactions. Alkenes and cycloalkenes are hydrocarbons that contain at least one double bond in its structure. Addition reaction can take place across the double bond. Aromatic compounds undergo substitution reactions rather than addition reactions even though they contain double bonds. This is because the double bonds are involved in delocalization.

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Answer 4

Question

Definition Definition Molecules that have multiple bonds between their carbon atoms. Alkenes are hydrocarbons with a double bond between two adjacent carbon atoms (R 2 C=CR 2 ), whereas alkynes are hydrocarbons with a triple bond between two adjacent carbon atoms R-C=C-R . These two groups are known as unsaturated hydrocarbons. They have fewer hydrogen atoms when compared with alkanes with same number of carbon atoms. The general molecular formula for an unsaturated hydrocarbon can be represented as C n H 2n +2 .

Chapter 13, Problem 13.125EP

(a)

Interpretation Introduction

Interpretation:

Alkanes are more susceptible for addition reaction or substitution reaction has to be indicated.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Alkanes are hydrocarbons that contain only single bonds between the carbon atoms. Therefore, there is no possibility of addition reaction. Alkanes undergo only substitution reactions. Alkenes and cycloalkenes are hydrocarbons that contain at least one double bond in its structure. Addition reaction can take place across the double bond. Aromatic compounds undergo substitution reactions rather than addition reactions even though they contain double bonds. This is because the double bonds are involved in delocalization.

(b)

Interpretation Introduction

Interpretation:

Dienes are more susceptible for addition reaction or substitution reaction has to be indicated.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Alkanes are hydrocarbons that contain only single bonds between the carbon atoms. Therefore, there is no possibility of addition reaction. Alkanes undergo only substitution reactions. Alkenes and cycloalkenes are hydrocarbons that contain at least one double bond in its structure. Addition reaction can take place across the double bond. Aromatic compounds undergo substitution reactions rather than addition reactions even though they contain double bonds. This is because the double bonds are involved in delocalization.

(c)

Interpretation Introduction

Interpretation:

Alkylbenzenes are more susceptible for addition reaction or substitution reaction has to be indicated.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Alkanes are hydrocarbons that contain only single bonds between the carbon atoms. Therefore, there is no possibility of addition reaction. Alkanes undergo only substitution reactions. Alkenes and cycloalkenes are hydrocarbons that contain at least one double bond in its structure. Addition reaction can take place across the double bond. Aromatic compounds undergo substitution reactions rather than addition reactions even though they contain double bonds. This is because the double bonds are involved in delocalization.

(d)

Interpretation Introduction

Interpretation:

Cycloalkenes are more susceptible for addition reaction or substitution reaction has to be indicated.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Alkanes are hydrocarbons that contain only single bonds between the carbon atoms. Therefore, there is no possibility of addition reaction. Alkanes undergo only substitution reactions. Alkenes and cycloalkenes are hydrocarbons that contain at least one double bond in its structure. Addition reaction can take place across the double bond. Aromatic compounds undergo substitution reactions rather than addition reactions even though they contain double bonds. This is because the double bonds are involved in delocalization.

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Answer 5

Chapter 13, Problem 13.125EP

(a)

Interpretation Introduction

Interpretation:

Alkanes are more susceptible for addition reaction or substitution reaction has to be indicated.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Alkanes are hydrocarbons that contain only single bonds between the carbon atoms. Therefore, there is no possibility of addition reaction. Alkanes undergo only substitution reactions. Alkenes and cycloalkenes are hydrocarbons that contain at least one double bond in its structure. Addition reaction can take place across the double bond. Aromatic compounds undergo substitution reactions rather than addition reactions even though they contain double bonds. This is because the double bonds are involved in delocalization.

(b)

Interpretation Introduction

Interpretation:

Dienes are more susceptible for addition reaction or substitution reaction has to be indicated.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Alkanes are hydrocarbons that contain only single bonds between the carbon atoms. Therefore, there is no possibility of addition reaction. Alkanes undergo only substitution reactions. Alkenes and cycloalkenes are hydrocarbons that contain at least one double bond in its structure. Addition reaction can take place across the double bond. Aromatic compounds undergo substitution reactions rather than addition reactions even though they contain double bonds. This is because the double bonds are involved in delocalization.

(c)

Interpretation Introduction

Interpretation:

Alkylbenzenes are more susceptible for addition reaction or substitution reaction has to be indicated.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Alkanes are hydrocarbons that contain only single bonds between the carbon atoms. Therefore, there is no possibility of addition reaction. Alkanes undergo only substitution reactions. Alkenes and cycloalkenes are hydrocarbons that contain at least one double bond in its structure. Addition reaction can take place across the double bond. Aromatic compounds undergo substitution reactions rather than addition reactions even though they contain double bonds. This is because the double bonds are involved in delocalization.

(d)

Interpretation Introduction

Interpretation:

Cycloalkenes are more susceptible for addition reaction or substitution reaction has to be indicated.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Alkanes are hydrocarbons that contain only single bonds between the carbon atoms. Therefore, there is no possibility of addition reaction. Alkanes undergo only substitution reactions. Alkenes and cycloalkenes are hydrocarbons that contain at least one double bond in its structure. Addition reaction can take place across the double bond. Aromatic compounds undergo substitution reactions rather than addition reactions even though they contain double bonds. This is because the double bonds are involved in delocalization.

Answer 6

Chapter 13, Problem 13.125EP

(a)

Interpretation Introduction

Interpretation:

Alkanes are more susceptible for addition reaction or substitution reaction has to be indicated.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Alkanes are hydrocarbons that contain only single bonds between the carbon atoms. Therefore, there is no possibility of addition reaction. Alkanes undergo only substitution reactions. Alkenes and cycloalkenes are hydrocarbons that contain at least one double bond in its structure. Addition reaction can take place across the double bond. Aromatic compounds undergo substitution reactions rather than addition reactions even though they contain double bonds. This is because the double bonds are involved in delocalization.

Answer 7

Chapter 13, Problem 13.125EP

(a)

Interpretation Introduction

Interpretation:

Alkanes are more susceptible for addition reaction or substitution reaction has to be indicated.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Alkanes are hydrocarbons that contain only single bonds between the carbon atoms. Therefore, there is no possibility of addition reaction. Alkanes undergo only substitution reactions. Alkenes and cycloalkenes are hydrocarbons that contain at least one double bond in its structure. Addition reaction can take place across the double bond. Aromatic compounds undergo substitution reactions rather than addition reactions even though they contain double bonds. This is because the double bonds are involved in delocalization.

Answer 8

(b)

Interpretation Introduction

Interpretation:

Dienes are more susceptible for addition reaction or substitution reaction has to be indicated.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Alkanes are hydrocarbons that contain only single bonds between the carbon atoms. Therefore, there is no possibility of addition reaction. Alkanes undergo only substitution reactions. Alkenes and cycloalkenes are hydrocarbons that contain at least one double bond in its structure. Addition reaction can take place across the double bond. Aromatic compounds undergo substitution reactions rather than addition reactions even though they contain double bonds. This is because the double bonds are involved in delocalization.

Answer 9

(b)

Interpretation Introduction

Interpretation:

Dienes are more susceptible for addition reaction or substitution reaction has to be indicated.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Alkanes are hydrocarbons that contain only single bonds between the carbon atoms. Therefore, there is no possibility of addition reaction. Alkanes undergo only substitution reactions. Alkenes and cycloalkenes are hydrocarbons that contain at least one double bond in its structure. Addition reaction can take place across the double bond. Aromatic compounds undergo substitution reactions rather than addition reactions even though they contain double bonds. This is because the double bonds are involved in delocalization.

Answer 10

(c)

Interpretation Introduction

Interpretation:

Alkylbenzenes are more susceptible for addition reaction or substitution reaction has to be indicated.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Alkanes are hydrocarbons that contain only single bonds between the carbon atoms. Therefore, there is no possibility of addition reaction. Alkanes undergo only substitution reactions. Alkenes and cycloalkenes are hydrocarbons that contain at least one double bond in its structure. Addition reaction can take place across the double bond. Aromatic compounds undergo substitution reactions rather than addition reactions even though they contain double bonds. This is because the double bonds are involved in delocalization.

Answer 11

(c)

Interpretation Introduction

Interpretation:

Alkylbenzenes are more susceptible for addition reaction or substitution reaction has to be indicated.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Alkanes are hydrocarbons that contain only single bonds between the carbon atoms. Therefore, there is no possibility of addition reaction. Alkanes undergo only substitution reactions. Alkenes and cycloalkenes are hydrocarbons that contain at least one double bond in its structure. Addition reaction can take place across the double bond. Aromatic compounds undergo substitution reactions rather than addition reactions even though they contain double bonds. This is because the double bonds are involved in delocalization.

Answer 12

(d)

Interpretation Introduction

Interpretation:

Cycloalkenes are more susceptible for addition reaction or substitution reaction has to be indicated.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Alkanes are hydrocarbons that contain only single bonds between the carbon atoms. Therefore, there is no possibility of addition reaction. Alkanes undergo only substitution reactions. Alkenes and cycloalkenes are hydrocarbons that contain at least one double bond in its structure. Addition reaction can take place across the double bond. Aromatic compounds undergo substitution reactions rather than addition reactions even though they contain double bonds. This is because the double bonds are involved in delocalization.

Answer 13

(d)

Interpretation Introduction

Interpretation:

Cycloalkenes are more susceptible for addition reaction or substitution reaction has to be indicated.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Alkanes are hydrocarbons that contain only single bonds between the carbon atoms. Therefore, there is no possibility of addition reaction. Alkanes undergo only substitution reactions. Alkenes and cycloalkenes are hydrocarbons that contain at least one double bond in its structure. Addition reaction can take place across the double bond. Aromatic compounds undergo substitution reactions rather than addition reactions even though they contain double bonds. This is because the double bonds are involved in delocalization.

Answer 14

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Answer 25

Ch. 13.1 - Prob. 1QQ Ch. 13.1 - Prob. 2QQ Ch. 13.1 - Prob. 3QQ Ch. 13.2 - Prob. 1QQ Ch. 13.2 - Prob. 2QQ Ch. 13.2 - Prob. 3QQ Ch. 13.2 - Prob. 4QQ Ch. 13.3 - Prob. 1QQ Ch. 13.3 - Prob. 2QQ Ch. 13.3 - Prob. 3QQ

Solution Summary: The author explains that alkanes are more susceptible for addition reaction or substitution reaction.

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