Bundle: Chemistry for Today: General, Organic, and Biochemistry, Loose-Leaf Version, 9th + LMS Integrated OWLv2, 4 terms (24 months) Printed Access Card
9th Edition
ISBN: 9781337598255
Author: Spencer L. Seager
Publisher: Cengage Learning
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Textbook Question
Chapter 13, Problem 13.58E
Thiols have lower boiling points and are less water soluble than the corresponding alcohol (e.g.,
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Which kinds of reactions are common to alcohols? Provide anexample of each.
Molecules with OH bonds tend to be soluble in water and yet octanol (C8H17OH) is not soluble in water. Please explain why octanol is not soluble in water.
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(Select all that apply.)
| Octanal is more hydrophilic than formaldehyde.
O Formaldehyde is a small molecule.
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Chapter 13 Solutions
Bundle: Chemistry for Today: General, Organic, and Biochemistry, Loose-Leaf Version, 9th + LMS Integrated OWLv2, 4 terms (24 months) Printed Access Card
Ch. 13 - Draw general formulas for an alcohol and phenol,...Ch. 13 - Prob. 13.2ECh. 13 - Assign IUPAC names to the following alcohols: a....Ch. 13 - Assign IUPAC names to the following alcohols: a....Ch. 13 - Several important alcohols are well known by...Ch. 13 - Prob. 13.6ECh. 13 - Draw structural formulas for each of the...Ch. 13 - Draw structural formulas for each of the...Ch. 13 - Name each of the following as a derivative of...Ch. 13 - Name each of the following as a derivative of...
Ch. 13 - Prob. 13.11ECh. 13 - Draw structural formulas for each of the...Ch. 13 - Prob. 13.13ECh. 13 - Classify the following alcohols as primary,...Ch. 13 - Classify the following alcohols as primary,...Ch. 13 - Draw structural formulas for the four aliphatic...Ch. 13 - Why are the boiling points of alcohols much higher...Ch. 13 - Arrange the compounds of each group in order of...Ch. 13 - Prob. 13.19ECh. 13 - Draw structural formulas for the following...Ch. 13 - Prob. 13.21ECh. 13 - Draw the structures of the chief product formed...Ch. 13 - Draw the structures of the chief product formed...Ch. 13 - Draw the structures of the ethers that can be...Ch. 13 - Prob. 13.25ECh. 13 - Give the structure of an alcohol that could be...Ch. 13 - Give the structure of an alcohol that could be...Ch. 13 - What products would result from the following...Ch. 13 - What products would result from the following...Ch. 13 - Each of the following conversions requires more...Ch. 13 - Each of the following conversions requires more...Ch. 13 - The three-carbon diol used in antifreeze is It is...Ch. 13 - Methanol is fairly volatile and evaporates quickly...Ch. 13 - Prob. 13.34ECh. 13 - Prob. 13.35ECh. 13 - Name an alcohol used in each of the following...Ch. 13 - Prob. 13.37ECh. 13 - Prob. 13.38ECh. 13 - Assign a common name to each of the following...Ch. 13 - Assign a common name to each of the following...Ch. 13 - Assign the IUPAC name to each of the following...Ch. 13 - Assign the IUPAC name to each of the following...Ch. 13 - Prob. 13.43ECh. 13 - Draw structural formulas for the following: a....Ch. 13 - Prob. 13.45ECh. 13 - Prob. 13.46ECh. 13 - Prob. 13.47ECh. 13 - Arrange the following compounds in order of...Ch. 13 - Arrange the compounds in Exercise 13.48 in order...Ch. 13 - Prob. 13.50ECh. 13 - Complete the following reactions: a. b....Ch. 13 - Prob. 13.52ECh. 13 - Lipoic acid is required by many microorganisms for...Ch. 13 - Alcohols and thiols can both be oxidized in a...Ch. 13 - Prob. 13.55ECh. 13 - Prob. 13.56ECh. 13 - Prob. 13.57ECh. 13 - Thiols have lower boiling points and are less...Ch. 13 - Prob. 13.59ECh. 13 - Prob. 13.60ECh. 13 - Prob. 13.61ECh. 13 - Prob. 13.62ECh. 13 - A mixture of ethanol and 1propanol is heated to...Ch. 13 - Prob. 13.64ECh. 13 - Prob. 13.65ECh. 13 - Prob. 13.66ECh. 13 - Prob. 13.67ECh. 13 - Figure 13.8 points out that methanol is used as a...Ch. 13 - Figure 13.13 focuses on the use of thiol chemistry...Ch. 13 - Prob. 13.70ECh. 13 - Prob. 13.71ECh. 13 - Prob. 13.72ECh. 13 - The compound that has the greatest polarity is: a....Ch. 13 - Alcoholic beverages contain: a. wood alcohol. b....Ch. 13 - Prob. 13.75ECh. 13 - Which of the following compounds is an ether? a....
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- 2. Complete the following reactions for the preparation of alcohols. Draw the structure of the product. Name the reactant and the product. a) CHy CH=CH-CHy + HyO Hydration of alkenes b) Cat. CHy-CHy + H2 drogenation carbonyl pups d)arrow_forwardDraw the structure of the six constitutional isomers of molecular formula C 5H 12O that contain an ether as functional group.arrow_forwardwhy do some ethers with the same molecular formulas as their respective alcohols have a lower boiling point?arrow_forward
- a primary alcohol has one -OH group, a secondary hasarrow_forwardExplain why these compounds (1-propanol, ethylene glycol, and ethanethiol) experience different intermolecular forces based on their molecular structure.arrow_forwardExplain the solubility of alcohols in water and in n-hexane.arrow_forward
- Which would be a secondary alcohol? . a) CH3 – CH2 – CH2OH b) CH3 – CH – CH3 OH c) CH3 – CH – CH2 OH OH d) OH CH3 – C – CH3 CH3 Oarrow_forwardDraw the structure of (R) 3-hydroxy-4-cyclohexenone. Give the IUPAC name of this compound, including stereochemistry. CH₂ HỌ.Harrow_forwardGive the IUPAC name of the following alcohols and phenols.arrow_forward
- 1: Give at least five (5) uses of Alcohol and Phenol Name Functional Group R-OH Alcohols LOH Phenols Based on the illustration above. What is the difference between alcohol and phenol? Can Phenol react with alcohol?arrow_forwardClassify each statement as a property of ethers, alcohols, or both ethers and alcohols. 1. These compounds cannot form hydrogen bonds between themselves, but they can form hydrogen bonds with other compounds containing an O−HO−H , N−HN−H , or F−HF−H bond, such as water.2. These compounds are water soluble if they have fewer than four carbon atoms.3. When comparing ethers and alcohols of similar molecular weights, these compounds have the higher boiling point. alcohols both ethers and alcohols ethersarrow_forwardCompare the families of alcohols, phenols, ethers, thiols and alkyl halides in terms of polarity, acidity, reactivity, hydrogen bond formation, relative boiling points.arrow_forward
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