Stereochemistry: Three possible answers- diastereomers, enantiomersOHCH₂OHI-c=021108 110141745 HORCH₂OHILНоCH₂OHTILa. Compounds I and III have this relationship with each other: enantiomersb. Compounds II and IV have this relationship with each other:c. Compounds I and II have this relationship with each other:d. *Draw one structure that is a stereoisomer of II, but neither adiastereomer nor an enantiomer. (more than one correct answer)

Enantiomers:Enantiomers are pairs of molecules that are non-superimposable mirror images of each…

Answered: Stereochemistry: Three possible…

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter5: Stereochemistry At Tetrahedral Centers

Section5.SE: Something Extra

Problem 74AP: cis-1,2-Dimethylcyclohexane is optically inactive even though it has two chirality centers. Explain.

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Indicate the relationship between each pair. Choose from: configurational stereoisomers,conformers, constitutional isomers, or different formulas (Each term is used at least twice.)
Ketones react with alcohols to yield products called acetals. Why does the all-cis isomer of 4-tert-butyl-1,3-cyclohexanediol react readily with acetone and an acid catalyst to form an acetal, but other stereoisomers do not react? In formulating your answer, draw the more stable chair conformations of all four stereoisomers and the product acetal for each one.
Classify the folowing pair of molecules as enantimoers or diastereomers
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just problem 5.20 please
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9. Which compound reacts with both NaBH and H/Pt to produce the same product? A) 1 4 2 B) II III CHO ||| D) None of these 10. Reduction of a carbonyl to produce a stereogenic center A) occurs with the formation of both diastereomers. B) occurs with the formation of both enantiomers. (C) occurs stereospecifically yielding a single isomeric product. D) none of these. MgBr 11. Which reagent would you use to produce (S)-1-phenylethanol from phenyl methyl ketone (acetophenone)? 12. A) S-CBS reagent B) R-CBS reagent C) NaBH +S-CBS reagent 4 D) NaBH + R-CBS reagent 4 An aldehyde can be produced by the reaction of the compound shown with which reagent? A) B) || D IV OCH3 I) H₁/Pt III) LiAlH4 II) NaBH4 IV) DIBAL-H 13. LiAlH reacts with which of the following? 4 A) | H .0 CI 0 EtO. 0 B) C) III D) All of these I II III
2. How many units of unsaturations does a compound with the formula C25H40Cl4 have? 3. Give the name of this compound, including stereochemistry if relevant: (CH3)3CCH₂CI
Please solve this orgo question!
4. Isomers and Stereocenters ( (a) Assign each set of molecules as constitutional isomers, conformational isomers, enantiomers, diastereomers, or identical. Please write the full name for the type. Molecules Type (b) H₂Ca HgC.. CH3 OCH₂ CH3 af OCH, SP H₂C**** H₂C H₂C NGOCH, H.C_OCKS OCH₂ CH₂ H₁C HC H*** CI H H CI Br H3C CH₂ Br (d) E) (0) For each of the following molecules, write the number of stereocenters and circle the center of any stereocenters. (i) (ii) H₂C (онт (eg 5) (b) -CH3 Isegna CH3 on mots eno H₂C CH3
Identity if they are , constitutional isomers, stereoisomers, enantiomers, diastereomers, or conformers.
The molecule (I) and (II) are || CH3 **H I Identical Enantiomers Diastereomers Constitutional Isomers Next H3C X II

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