9. Which compound reacts with both NaBH and H/Pt to produce the same product? 4 2

Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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9.
Which compound reacts with both NaBH and H/Pt to produce the same
product?
A) 1
4
2
B)
II
III
CHO
|||
D)
None of these
10.
Reduction of a carbonyl to produce a stereogenic center
A)
occurs with the formation of both diastereomers.
B)
occurs with the formation of both enantiomers.
(C)
occurs stereospecifically yielding a single isomeric product.
D) none of these.
MgBr
11. Which reagent would you use to produce (S)-1-phenylethanol from phenyl methyl
ketone (acetophenone)?
12.
A)
S-CBS reagent
B) R-CBS reagent
C)
NaBH +S-CBS reagent
4
D)
NaBH + R-CBS reagent
4
An aldehyde can be produced by the reaction of the compound shown with which
reagent?
A)
B) ||
D
IV
OCH3
I) H₁/Pt
III) LiAlH4
II) NaBH4
IV) DIBAL-H
13. LiAlH reacts with which of the following?
4
A)
|
H
.0
CI
0 EtO.
0
B)
C)
III
D)
All of these
I
II
III
Transcribed Image Text:9. Which compound reacts with both NaBH and H/Pt to produce the same product? A) 1 4 2 B) II III CHO ||| D) None of these 10. Reduction of a carbonyl to produce a stereogenic center A) occurs with the formation of both diastereomers. B) occurs with the formation of both enantiomers. (C) occurs stereospecifically yielding a single isomeric product. D) none of these. MgBr 11. Which reagent would you use to produce (S)-1-phenylethanol from phenyl methyl ketone (acetophenone)? 12. A) S-CBS reagent B) R-CBS reagent C) NaBH +S-CBS reagent 4 D) NaBH + R-CBS reagent 4 An aldehyde can be produced by the reaction of the compound shown with which reagent? A) B) || D IV OCH3 I) H₁/Pt III) LiAlH4 II) NaBH4 IV) DIBAL-H 13. LiAlH reacts with which of the following? 4 A) | H .0 CI 0 EtO. 0 B) C) III D) All of these I II III
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