14.41 Label each pair of compounds as stereoisomers, conformations, or constitutional isomers: (a) A and B; (b) A and C; (c) A and D; (d) C and D. A B C D
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- Drawn are four isomeric dimethylcyclopropanes. A B C D a. How are the compounds in each pair related (enantiomers, diastereomers, constitutional isomers): A and B; A and C; B and C; C and D? b. Label each compound as chiral or achiral. c. Which compounds, alone, would be optically active? d. Which compounds have a plane of symmetry? e. f. g. How do the boiling points of the compounds in each pair compare: A and B; B and C; C and D? Which of the compounds are meso compounds? Would an equal mixture of compounds C and D be optically active? What about an equal mixture of B and C?Drawn are four isomeric dimethylcyclopropane. a. How are the compounds in each pair related (enantiomers, diastereomers,constitutional isomers): A and B; A and C; B and C; C and D?b. Label each compound as chiral or achiral.c. Which compounds, alone, would be optically active?d. Which compounds have a plane of symmetry?e. Which of the compounds are meso compounds?f. Would an equal mixture of compounds C and D be optically active? Whatabout an equal mixture of B and C?g. How many stereogenic centers are there for each compound?Ans.
- Problem 5.30 Page 204 State how each pair of compounds is related. Are they enantiomers, diastereomers, constitutional isomers, or identical? Br а. HO, and Br но b. and С. HO- and OH HO d. Он and OH но HODrawn are four isomeric dimethylcyclopropanes. a.How are the compounds in each pair related (enantiomers, diastereomers, constitutional isomers): A and B; A and C; B and C; C and D? b.Label each compound as chiral or achiral. c.Which compounds alone would be optically active? d.Which compounds have a plane of symmetry? e.How do the boiling points of the compounds in each pair compare: A and B; B and C; C and D? f.Which of the compounds are meso compounds? g.Would an equal mixture of compounds C and D be optically active? What about an equal mixture of B and C?None
- Chondrocole A is a marine natural product isolated from red seaweed that grows in regions of heavy surf in the Pacific Ocean. (a) Predict the solubility of chondrocole A in water and CH2Cl2. (b) Locate the stereogenic centers and label each as R or S. (c) Draw a stereoisomer and a constitutional isomer of chondrocole A.Q2: Drawn are four isomeric dimethylcyclopropanes. a. How are the compounds in each pair related (enantiomers, diastereomers, constitutional isomers): A and 8; A and C; B and C, Cand D? b. Label each compound as chiral or achiral. c. Which compounds, alone, would be optically active? d. Which compounds have a plane of symmetry? e. Which of the compounds are meso compounds? f. Would an equal mixture of compounds C and D be optically active? What about an equal mixture of B and C?Problem 4.30 (a) Draw C in its more stable chair conformation. (b) Convert D to a hexagon with substituents on wedges and dashed wedges. Н | CH3 CH3 CH2CH2CH3 н
- 5.60 How are the compounds in each pair related to each other? Are they identical, enantiomers, diastereomers, constitutional isomers, or not isomers of each other? J a. b. C. d. L e. H f. HO Br HO. H Br H CI H 'OH -H H Br H and and and and and OH H and H" HO Y H H CI CBr Br Br но. C/ H OH OH3. Which conformation is lower in energy? Explain. (3 pts)5.71 Identify the specific type of relationship between each of the following pairs of molecules (i.e., either same, constitutional isomers, enantiomers, diastereomers, conformers, or unrelated). Savitos vilsbitqo (a) (d) (b) Siamating elinton sidege or phool stutxim Sru lliw moitoshib roirlw al jert (f) no H omognene 2 H₂C CI trig beshslo en moinsne (-) OA bre tomblihene (or txim s tebieno 03 a Tequixim erit to eaeoxe phemoinsne ant ei fedW Strigil bashslog-ensia osnebsicherebenaPhosurda (e) bloqque es+to noitsion alege is earl enstudomond-S-(2) 182 H dW 269 isetermine the compou No ni enstudomord S-(2) Vino bregut Brge of H CH3 H H₂C CI ei jew not is Br H3C 84.2 e moldog ni weib uoy estupelom srif (c) toolstoy oftios 8 B 2A 2 maldo19 992) loxet CI 6 al #Choltsmmation d lebigoloid on alldirixe temolinone A en evitastig ei,º0.2stal agitator oliqa CH3 Uher(g) meH 2Br20x Briem Hiene Н CH3 H3C, Erilmoitr Н ...H H H NO H antholica ish buat agensm obseu gunb s ai netorqudi S22 CH3 himsm85…