14.47 Addition of HCI to alkene X forms two alkyl halides Y and Z.exocyclic C=CXHCICIY+CI Za. Label Y and Z as a 1,2-addition product or a 1,4-addition product.b.Label Y and Z as the kinetic or thermodynamic product and explainwhy.c. Explain why addition of HCI occurs at the indicated C=C (called anexocyclic double bond), rather than the other C=C (called anendocyclic double bond).

A.1,2-addition product (Y): The addition of HCl at the exocyclic double bond results in the chlorine…

Answered: 14.47 Addition of HCI to alkene X forms…

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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9,49 Draw a stepwise mechanism for the following reaction. OH H20 H,SO following reaction. HO, H,SO, H20 An allylic alcohol contains an OH group on a carbon atom adiacent to a C-C double bond. Treatment of allylic alcohol A with HCI forms a mixture of two allylic chiorides, B and C. Draw a stepwise mechanism that illustrates how both products are formed. 9.51 CI HCI H20 HO, 9.52 Draw a stepwise, detailed mechanism for the following reaction. OH H2SO4 H20
Addition of HCl to alkene X forms two alkyt halides Y and Z. exocyclic C=C HCI CH3 CH2 -CH3 ci z a. Label Y and Z as a 1,2-addition product or a 1,4-addition product. b. Label Y and Z as the kinetic or thermodynamic product and explain why. c. Explain why addition of HCl occurs at the indicated C=C (called an exocyclic double bond), rather than the other C=C (called an endocyclic double bond).
10.52 Draw the products of each reaction, including stereoisomers. a. H₂O H₂SO4 b. C. Cl₂ HI d. e. Cl₂ H₂O [1] BH3 [2] H₂O₂, HO- f. g. h. CH3O CH3O H₂O H₂SO4 Br2 HCI
write the correct product for each reaction. indicate any specific stereochemistry
7.53 Draw the products of each SN2 reaction and indicate the stereochemistry where appropriate. (2) HA a. + "OCH3 C. Br + "CN b. C + -OCH₂CH3
8:49 Question 19 of 32 H H Starting from the structure below (sighting down the indicated bond), rotate the back carbon to provide the structure in the conformation that will be capable of an E2 elimination. R/S stereochemistry is graded. CH3 Br Ph .5G Submit Draw Newman Projection OCH3 Q
9.45 Draw the expected product of each of the following reactions, showing stereochemistry where appropriate: me ? ? 9.46 Compound A is an alkyne that reacts with two equivalents of H₂ in the presence of Pd to give 2,4,6-trimethyloctane. Maho NH3 Draw the structure of compound A. How many chiral centers are present in compound A? Identify the locants for the methyl groups in compound A. Explain why the locants are not 2, 4, and 6 as seen in the product of hydrogenation.
9.44 Draw the products of each reaction and indicate stereochemistry around stereogenic centers. a. b. C. d. e. f. OH HD OH OH OH OH OH HBr HCI ZnCl₂ SOCI₂ pyridine TSCI pyridine HBr HCI KI
G.89.
15. Consider the substitution reaction: The product(s) of the reaction is(are): a. R enantiomer C. d. HO-C (S)-2-bromononane H CH; A equimolar mixture of a and b. A mixture of the major product a with the minor product b. CH₂O CH₂OH b. Senantiomer HO-C CH;
Fill in the product, starting material, or reagent for each reaction. "No reaction" is a possibility. Also, be sure to show stereochemistry and anyrearrangements if they occur. 5. 1) BH; THF 2) H,02. OH H;C
1. Which alkene forms in the greater abundance, and why? CI base

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